Organometallic Compound for OLED Emission Layer

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Solution Overview

Problem

Organic light-emitting devices (OLEDs) face challenges in achieving low driving voltage, high efficiency, high brightness, and long lifespan while maintaining excellent luminance and response speed characteristics.

Innovation Solution

An organometallic compound represented by specific Formulae 1A and 1B is used in the emission layer of OLEDs, serving as a dopant and improving thermal stability, emission color purity, and reducing deposition temperature to minimize impurity formation.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Power

If conventional organic light-emitting devices are used, then basic light emission is achieved, but driving voltage is high and efficiency is low

Engineering Contradiction:
Improvedriving voltageVSAvoidenergy efficiency
Core Design Contradiction:
PowerVSLoss of energy

Solution Approach 1:

The patent modifies the chemical structure of organometallic compounds by introducing specific ligand combinations (Formulae 1A and 1B with particular R groups and coordination modes) to optimize electronic properties, thereby reducing driving voltage and improving energy efficiency simultaneously

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention uses composite organometallic compounds combining multiple ligand types (Formulae 1A and 1B with different R1-R20 substituents) to achieve synergistic effects that improve both electrical conductivity for lower voltage and energy conversion efficiency

Inventive Principle:
Principle #40Composite materials

2Manufacturing precision

If deposition temperature is high, then complete material deposition is achieved, but impurity formation increases

Engineering Contradiction:
Improvedeposition completenessVSAvoidimpurity formation
Core Design Contradiction:
Manufacturing precisionVSObject-generated harmful factors

Solution Approach 1:

The patent develops organometallic compounds with specific thermal stability characteristics (Formulae 1A and 1B) that enable complete deposition at lower temperatures, preventing thermal decomposition and impurity formation while ensuring full material transfer

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention creates organometallic compounds designed for single-use deposition processes that decompose cleanly at controlled temperatures, allowing complete material transfer without generating persistent impurities

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

3Manufacturing precision

If thermal stability is improved, then emission color purity increases, but device complexity increases

Engineering Contradiction:
Improveemission color purityVSAvoidcompound structure complexity
Core Design Contradiction:
Manufacturing precisionVSDevice complexity

Solution Approach 1:

The patent introduces specific functional groups and substituent patterns (R1-R20 in Formulae 1A and 1B) at localized positions within the organometallic compound structure to enhance thermal stability and color purity without requiring complete structural redesign

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The invention systematically varies ligand parameters (R groups, coordination numbers, chelate ring sizes) in Formulae 1A and 1B to optimize the balance between thermal stability, emission color purity, and structural complexity

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The organometallic compound enhances the efficiency, lifespan, and color purity of OLEDs by improving thermal stability and reducing impurity formation, leading to improved performance in brightness and response speed.

Implementation Method 1

Carriers, such as holes and electrons, recombine in the emission layer to produce excitons. These excitons transit from an excited state to a ground state, thereby generating light.

Methodology Applied
Scientific EffectElectroluminescence: Electroluminescence

Data Source

PatentUS11075345B2Organometallic compound and organic light-emitting device including the same
Publication Date: 2021.07.27 SAMSUNG ELECTRONICS CO LTD
  • US11075345B2 patent drawing
  • US11075345B2 patent drawing
  • US11075345B2 patent drawing

AI summary

An organometallic compound represented by one of Formulae 1A and 1B:wherein, in Formulae 1A and 1B, A11, b20, L11, M, m, n, and R15 to R20 are the same as described in the specification.