Organometallic OLED Host Compounds for Saturated Color Emission

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Solution Overview

Problem

Current organic light-emitting diode (OLED) technologies face challenges in achieving saturated colors, particularly in red, green, and blue emissions, which are essential for full-color displays, and existing materials may not efficiently utilize the potential of organic materials for flexible and cost-effective opto-electronic devices.

Innovation Solution

A novel organometallic compound of Formula I is introduced, which can be used in OLEDs as a host or emitter, featuring a specific structure that allows for enhanced light emission properties, including the ability to form rings and incorporate various substituents, thereby improving color saturation and efficiency.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Ease of manufacture

If conventional organic materials are used in OLEDs, then cost and flexibility are improved, but color saturation and emission performance deteriorate

Engineering Contradiction:
ImprovecostVSAvoidcolor saturation
Core Design Contradiction:
Ease of manufactureVSManufacturing precision

Solution Approach 1:

The patent modifies the molecular structure parameters of organic emitters by introducing specific heteroatoms (B, Si, Ge) and substituent groups at defined positions, which changes the electronic properties and emission characteristics to achieve saturated colors while maintaining organic material benefits

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates composite organometallic structures by combining organic ligands with metal centers (B, Si, Ge) to form hybrid materials that exhibit enhanced emission properties not achievable with purely organic or inorganic materials alone

Inventive Principle:
Principle #40Composite materials

2Adaptability or versatility

If conventional organic materials are used in OLEDs, then flexibility is improved, but emission efficiency and performance deteriorate

Engineering Contradiction:
ImproveflexibilityVSAvoidemission efficiency
Core Design Contradiction:
Adaptability or versatilityVSReliability

Solution Approach 1:

The patent optimizes molecular parameters including HOMO-LUMO energy gaps, triplet energy levels, and steric bulk of substituents to achieve high emission efficiency while maintaining the flexibility characteristic of organic materials

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent introduces specific functional groups and heteroatoms at particular positions in the molecular structure to locally enhance emission properties without compromising the overall flexibility of the organic material

Inventive Principle:
Principle #3Local quality

3Manufacturing precision

If saturated color emission is achieved using conventional methods, then color performance is improved, but material cost and device complexity increase

Engineering Contradiction:
Improvecolor saturationVSAvoiddevice structure
Core Design Contradiction:
Manufacturing precisionVSDevice complexity

Solution Approach 1:

The patent extracts and eliminates the need for complex color filtering layers and additional optical components by achieving saturated color emission directly from the organic emitter molecules themselves, simplifying the overall device structure

Inventive Principle:
Principle #2Taking out (Extraction)

4Device complexity

If white light emission is used in OLEDs, then device simplicity is improved, but color saturation and display quality deteriorate

Engineering Contradiction:
Improvedevice structureVSAvoidcolor saturation
Core Design Contradiction:
Device complexityVSManufacturing precision

Solution Approach 1:

Instead of using white light emission followed by color filtering (the conventional approach), the patent inverts the strategy by designing emitters that directly emit saturated colors, eliminating the need for filters and achieving both simplicity and color quality

Inventive Principle:
Principle #13The other way round (Inversion)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The compound enhances the emission properties of OLEDs, enabling the production of saturated colors and improving the performance and cost-effectiveness of organic opto-electronic devices, particularly in flexible substrate applications.

Implementation Method 1

OLEDs make use of thin organic films that emit light when voltage is applied across the device

Methodology Applied
Scientific EffectElectroluminescence: Electroluminescence

Data Source

PatentUS20220119418A1Organic electroluminescent materials and devices
Publication Date: 2022.04.21 UNIVERSAL DISPLAY CORP
  • US20220119418A1 patent drawing
  • US20220119418A1 patent drawing
  • US20220119418A1 patent drawing

AI summary

Provided are high triplet host compounds based on a multiphenylene macrocycle which comprises at least one group L1 selected from the group consisting of O, S, Se, BR, BRR′, CRR′, SiRR′, and GeRR′ which links two phenylene groups. Also provided are formulations comprising these compounds. Further provided are OLEDs and related consumer products that utilize these compounds.