Organometallic Compound Emission Layer for OLED Driving Voltage Reduction

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Solution Overview

Problem

Organic light-emitting devices (OLEDs) face challenges in achieving low driving voltage, high efficiency, and long lifespan while maintaining high brightness and efficiency.

Innovation Solution

An organometallic compound represented by Formula 1, where M is selected from Ir, Pt, Os, Ti, Zr, Hf, Eu, Tb, Tm, and Rh, and L1 and L2 are specific ligands, is incorporated into the emission layer of an OLED, serving as a dopant with a host material to enhance performance.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional organic light-emitting devices are used, then they can produce multicolored images with wide viewing angles, but they suffer from high driving voltage, low efficiency, and short lifespan

Engineering Contradiction:
ImprovelifespanVSAvoiddriving voltage
Core Design Contradiction:
ReliabilityVSUse of energy by moving object

Solution Approach 1:

The patent changes the chemical composition parameters of the emission layer by introducing specific organometallic compounds with particular ligand structures (Formula 2A and 2B), thereby optimizing the electronic properties to achieve lower driving voltage and improved device reliability

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates a composite emission layer by combining the host material with the newly synthesized organometallic compound (Formula 1), where the synergistic interaction between host and dopant improves efficiency and lifespan while reducing driving voltage

Inventive Principle:
Principle #40Composite materials

2Reliability

If conventional organic light-emitting devices are used, then they can produce multicolored images with wide viewing angles, but they suffer from high driving voltage, low efficiency, and short lifespan

Engineering Contradiction:
ImprovelifespanVSAvoidefficiency
Core Design Contradiction:
ReliabilityVSProductivity

Solution Approach 1:

The patent optimizes the chemical structure parameters of the organometallic compound, specifically the ligand configurations in Formulae 2A and 2B, to enhance the radiative recombination efficiency and extend device operational lifetime

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The emission layer is designed as a composite system combining host material and organometallic dopant (Formula 1), where the specific composition ratio and molecular interactions improve both efficiency and reliability simultaneously

Inventive Principle:
Principle #40Composite materials

3Productivity

If conventional organic light-emitting devices are used, then they can produce multicolored images with wide viewing angles, but they suffer from high driving voltage, low efficiency, and short lifespan

Engineering Contradiction:
ImproveefficiencyVSAvoiddriving voltage
Core Design Contradiction:
ProductivityVSUse of energy by moving object

Solution Approach 1:

The patent modifies the electronic structure parameters of the emission layer by incorporating organometallic compounds with specific ligand field configurations, thereby reducing the energy barrier for charge recombination and improving efficiency while lowering driving voltage

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent replaces conventional organic emitters with organometallic compounds that utilize metal-centered or ligand-centered emission mechanisms, fundamentally changing the emission physics to achieve superior efficiency and lower voltage requirements

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The organometallic compound improves the OLED's efficiency and lifespan by optimizing the recombination of holes and electrons, leading to enhanced brightness and reduced driving voltage.

Implementation Method 1

Holes provided from the anode may move toward the emission layer through the hole transport region, and electrons provided from the cathode may move toward the emission layer through the electron transport region. Such holes and electrons may be recombined in the emission layer to produce excitons. These excitons may change from an excited state to a ground state, thereby generating light.

Methodology Applied
Scientific EffectElectroluminescence: Electroluminescence

Data Source

PatentUS10370588B2Organometallic compound and organic light-emitting device including the same
Publication Date: 2019.08.06 SAMSUNG ELECTRONICS CO LTD
  • US10370588B2 patent drawing
  • US10370588B2 patent drawing
  • US10370588B2 patent drawing

AI summary

An organometallic compound represented by Formula 1:M(L1)n1(L2)n2  Formula 1wherein in Formula 1, M, L1, L2, n1, and n2 are the same as described in the specification.