Organometallic Compound for OLEDs with Low Driving Voltage

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Solution Overview

Problem

Organic light-emitting devices (OLEDs) face challenges in achieving low driving voltage, high efficiency, high brightness, and long lifespan.

Innovation Solution

An organometallic compound represented by Formula 1 is used in the organic layer of OLEDs, acting as a dopant, which includes specific metal elements and ligand structures that enhance electrical characteristics and reduce structural changes in excited states, improving lifespan and color purity.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Power

If conventional organic light-emitting devices are used, then basic light emission is achieved, but driving voltage is high and efficiency is low

Engineering Contradiction:
Improvedriving voltageVSAvoiddevice efficiency
Core Design Contradiction:
PowerVSReliability

Solution Approach 1:

The patent modifies the chemical structure of the organometallic compound by changing ligand types, metal centers, and molecular geometry to optimize electronic properties. Specifically, the invention uses compounds with C2v or C2h symmetry and specific HOMO-LUMO energy levels to reduce driving voltage while maintaining high efficiency, directly addressing the contradiction between power consumption and device reliability

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent employs composite organometallic compounds combining specific metal centers (Ir, Pt, Os) with tailored organic ligands to create materials that simultaneously achieve low driving voltage and high efficiency. The composite structure allows optimization of both electrical characteristics and optical properties, resolving the contradiction between power requirements and operational reliability

Inventive Principle:
Principle #40Composite materials

2Illumination intensity

If conventional emission layers are used, then light emission is achieved, but color purity is insufficient

Engineering Contradiction:
Improvecolor purityVSAvoidemission layer structure
Core Design Contradiction:
Illumination intensityVSDevice complexity

Solution Approach 1:

The patent applies local quality by designing emission layers with specific spatial arrangements of organometallic compounds having defined molecular geometries (C2v or C2h symmetry). This localized structural optimization enables precise control over emission characteristics, achieving high color purity without requiring complex multi-layer structures

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The patent utilizes the inherent color emission properties of specific organometallic compounds and optimizes their molecular structures to achieve desired color purity. By selecting metals (Ir, Pt, Os) and ligands that emit in specific wavelength ranges, the invention achieves excellent color purity while maintaining relatively simple emission layer architecture

Inventive Principle:
Principle #32Color changes

3Duration of action of stationary object

If OLEDs operate for extended periods, then continuous light emission is maintained, but lifespan is limited due to structural changes in excited states

Engineering Contradiction:
Improvedevice lifespanVSAvoidmolecular structure stability
Core Design Contradiction:
Duration of action of stationary objectVSStability of the object's composition

Solution Approach 1:

The patent employs organometallic compounds with inherently stable molecular structures (C2v or C2h symmetry) that resist degradation during operation. The specific molecular geometry and bonding configuration provide built-in structural stability that cushions against excited-state induced degradation, extending device lifespan while maintaining composition stability

Inventive Principle:
Principle #11Beforehand cushioning (Prior cushioning)

Solution Approach 2:

The patent uses organometallic compounds that can be synthesized through cost-effective methods and provide sufficient operational stability. The compounds are designed to maintain their structural integrity throughout the device's operational life, providing a balance between material stability and device lifespan without requiring overly complex or expensive materials

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The use of the organometallic compound in OLEDs results in devices with low driving voltage, high efficiency, long lifespan, and excellent color purity, with improved electronic characteristics suitable for emission layers.

Implementation Method 1

The holes and the electrons recombine in the emission layer to produce excitons. These excitons transition from an excited state to a ground state, thereby generating light.

Methodology Applied
Scientific EffectElectroluminescence: Electroluminescence

Implementation Method 2

luminescent compounds, for example, phosphorescent compounds, may be used for monitoring, sensing, and detecting biological materials such as various cells and proteins.

Methodology Applied
Scientific EffectPhosphorescence: Phosphorescence

Data Source

PatentUS11352384B2Organometallic compound, organic light-emitting device including the same, and diagnostic composition including the same
Publication Date: 2022.06.07 SAMSUNG ELECTRONICS CO LTD
  • US11352384B2 patent drawing
  • US11352384B2 patent drawing
  • US11352384B2 patent drawing

AI summary

An organometallic compound represented by Formula 1:wherein, in Formula 1, groups and variables are the same as described in the specification.