Organometallic Compound for OLED Driving Voltage and Efficiency

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Solution Overview

Problem

Organic light-emitting devices (OLEDs) face challenges in achieving low driving voltage, high efficiency, and long lifespan while maintaining high brightness.

Innovation Solution

An organometallic compound represented by Formula 1, which includes a C3-C20 heteropolycyclic group with specific metal and ligand configurations, is used in the organic layer of OLEDs to enhance charge mobility and efficiency.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Power

If conventional organic light-emitting devices are used, then basic light emission function is achieved, but driving voltage is high and efficiency is low

Engineering Contradiction:
Improvedriving voltageVSAvoidluminous efficiency
Core Design Contradiction:
PowerVSProductivity

Solution Approach 1:

The patent applies parameter changes by modifying the molecular structure of organometallic compounds through specific ligand configurations (A11 heteropolycyclic group with C3-C20 carbon atoms and specific atomic arrangements at X11-X17 positions). These structural parameter changes optimize charge mobility and reduce driving voltage while improving luminous efficiency. The patent also optimizes device layer structure parameters including thickness and material composition of emission layer, hole transport region, and electron transport region.

Inventive Principle:
Principle #35Parameter changes

2Duration of action of stationary object

If conventional organometallic compounds are used, then device operation is achieved, but lifespan is limited

Engineering Contradiction:
Improvedevice lifespanVSAvoidoperational stability
Core Design Contradiction:
Duration of action of stationary objectVSReliability

Solution Approach 1:

The patent employs composite materials by combining the organometallic compound (Formula 1) with specific host materials in the emission layer, and coordinating with particular materials in hole transport and electron transport regions. This composite approach creates synergistic effects that enhance device reliability and extend operational lifespan. The specific composite structure includes the organometallic compound doped in emission layer with host material at controlled ratios.

Inventive Principle:
Principle #40Composite materials

3Temperature

If conventional organic layers are used, then basic emission function is achieved, but thermal stability is insufficient

Engineering Contradiction:
Improvethermal stabilityVSAvoidmaterial composition stability
Core Design Contradiction:
TemperatureVSStability of the object's composition

Solution Approach 1:

The patent applies local quality by designing specific regions with tailored thermal properties: the emission layer contains the thermally stable organometallic compound (Formula 1) with specific ligand structure, hole transport region uses materials optimized for hole injection and transport, and electron transport region uses materials optimized for electron injection and transport. Each region's material composition is locally optimized for its specific function while contributing to overall thermal stability.

Inventive Principle:
Principle #3Local quality

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The use of the organometallic compound improves the electric characteristics and thermal stability of OLEDs, resulting in reduced driving voltage, increased efficiency, and extended lifetime.

Implementation Method 1

Holes provided from the anode may move toward the emission layer through the hole transport region, and electrons provided from the cathode may move toward the emission layer through the electron transport region. The holes and the electrons are recombined in the emission layer to produce excitons. These excitons change from an excited state to a ground state to thereby generate light.

Methodology Applied
Scientific EffectElectroluminescence: Electroluminescence

Data Source

PatentUS10651402B2Organometallic compound and organic light-emitting device including the same
Publication Date: 2020.05.12 SAMSUNG ELECTRONICS CO LTD
  • US10651402B2 patent drawing
  • US10651402B2 patent drawing
  • US10651402B2 patent drawing

AI summary

An organometallic compound represented by Formula 1:wherein, in Formula 1, b18, A11, L11, M, m, R18, and X11 to X17 are the same as described in the specification.