Organometallic Compound for OLED Driving Voltage and Efficiency

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Solution Overview

Problem

Organic light-emitting devices (OLEDs) face challenges in achieving low driving voltage, high efficiency, high brightness, and long lifespan.

Innovation Solution

An organometallic compound represented by Formula 1, which includes platinum (Pt) or palladium (Pd) as M, is used in the emission layer of OLEDs, acting as a dopant to enhance luminescent efficiency and lifespan, with specific bonding configurations and substituents that optimize electrical characteristics.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Power

If conventional organic light-emitting devices are used, then basic light emission is achieved, but driving voltage is high and efficiency is low

Engineering Contradiction:
Improvedriving voltageVSAvoidefficiency
Core Design Contradiction:
PowerVSProductivity

Solution Approach 1:

The patent modifies the chemical structure of the organometallic compound by changing parameters such as the metal center (Pt or Pd), ligand types (X1-X4 being C or N), and substituent groups (R1-R6, Cy1-Cy4) to optimize the emission characteristics, driving voltage, and efficiency of the OLED simultaneously

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention uses composite organometallic compounds combining organic ligands with metal centers (Pt or Pd) to create materials that exhibit both low driving voltage and high efficiency characteristics, resolving the contradiction between these two parameters

Inventive Principle:
Principle #40Composite materials

2Reliability

If conventional luminescent compounds are used, then light emission is achieved, but quantum efficiency is low and lifespan is short

Engineering Contradiction:
ImprovelifespanVSAvoidquantum efficiency
Core Design Contradiction:
ReliabilityVSUse of energy by moving object

Solution Approach 1:

The patent optimizes the organometallic compound structure by adjusting parameters including the metal center selection (Pt or Pd), coordination geometry (X1-X4 configurations), and substituent groups to simultaneously improve quantum efficiency and device lifespan

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention develops organometallic compounds that replace conventional short-lived luminescent materials, providing both high quantum efficiency and extended operational lifespan through improved molecular stability and emission characteristics

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

3Illumination intensity

If standard organometallic compounds are used, then emission is achieved, but color purity is insufficient

Engineering Contradiction:
Improvecolor purityVSAvoidcompound structure complexity
Core Design Contradiction:
Illumination intensityVSDevice complexity

Solution Approach 1:

The patent introduces specific substituent groups (R1-R6, Cy1-Cy4) at particular positions on the ligand framework to locally modify the emission properties, achieving high color purity through targeted structural modifications rather than overall complexity

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The invention adjusts structural parameters such as the types of cyclic groups (Cy1-Cy4 being C5-C30 carbocyclic or C1-C30 heterocyclic groups), linkage types (T1-T3), and substituent positions to precisely control the emission wavelength and color purity while managing structural complexity

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The use of the organometallic compound in OLEDs results in devices with low driving voltage, high efficiency, high quantum efficiency, long lifespan, low roll-off ratio, and excellent color purity.

Implementation Method 1

Examples of such luminescent compounds include a phosphorescent luminescent compound

Methodology Applied
Scientific EffectPhosphorescence: Phosphorescence

Data Source

PatentUS11800789B2Organometallic compound, organic light-emitting device including the same, and diagnostic composition including the organometallic compound
Publication Date: 2023.10.24 SAMSUNG ELECTRONICS CO LTD
  • US11800789B2 patent drawing
  • US11800789B2 patent drawing
  • US11800789B2 patent drawing

AI summary

An organometallic compound represented by Formula 1:wherein, in Formula 1, groups and variables are the same as described in the specification.