Orientation-Patterned Templates via Far-From-Equilibrium Deposition

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Solution Overview

Problem

Current methods for preparing orientation-patterned templates for heteroepitaxial growth face challenges such as high etch-pit density, rough surface morphology, lack of an etch-stop material, and complex polishing processes, particularly for GaP templates, which hinder the growth of nonlinear optical materials like GaP and GaN.

Innovation Solution

A technique involving the deposition of a first layer on a common substrate using a far-from-equilibrium process, followed by a second layer using a close-to-equilibrium process, allowing for the creation of orientation-patterned templates with opposite polarities, which can be bonded to achieve high-quality thick growth without the need for expensive equipment or precise polishing.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If traditional polishing processes are used to prepare GaP templates, then surface smoothness is improved, but manufacturing complexity and time consumption increase significantly

Engineering Contradiction:
Improvesurface smoothnessVSAvoidprocess complexity
Core Design Contradiction:
Manufacturing precisionVSDevice complexity

Solution Approach 1:

The patent extracts and removes the complex polishing step from the template preparation process by using chemical etching to create the orientation pattern directly. The etch-stop material layer is selectively removed through chemical etching, which automatically produces the desired orientation pattern without requiring mechanical polishing, thereby simplifying the manufacturing process while maintaining surface quality.

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The patent replaces the mechanical polishing system with a chemical etching system. Instead of using mechanical abrasion to achieve surface smoothness and orientation patterning, the process uses chemical etchants that selectively remove material based on crystallographic orientation, substituting mechanical action with chemical action to achieve the same functional result with reduced complexity.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

2Manufacturing precision

If wafer fusion bonding is used to create orientation-patterned templates, then template quality is improved, but the requirement for precise alignment and matching increases manufacturing difficulty

Engineering Contradiction:
Improvetemplate qualityVSAvoidmanufacturing difficulty
Core Design Contradiction:
Manufacturing precisionVSEase of manufacture

Solution Approach 1:

The patent applies preliminary action by pre-depositing the etch-stop material layer (such as AlGaAs or InGaAs) on the substrate before creating the orientation pattern. This pre-deposited layer serves as a built-in alignment reference and etching stop, eliminating the need for precise post-bonding alignment adjustments and simplifying the overall manufacturing process while maintaining high template quality.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The etch-stop material layer acts as an intermediary between the substrate and the orientation-patterned layer. This intermediate layer facilitates the bonding process by providing a chemically active surface for bonding while simultaneously serving as a protective layer during etching, thus mediating between the conflicting requirements of bond strength and etching selectivity without requiring precise mechanical alignment.

Inventive Principle:
Principle #24Intermediary (Mediator)

3Manufacturing precision

If high-quality native substrates are used for heteroepitaxial growth, then growth quality is improved, but substrate cost increases significantly

Engineering Contradiction:
Improvegrowth qualityVSAvoidsubstrate cost
Core Design Contradiction:
Manufacturing precisionVSQuantity of substance

Solution Approach 1:

The patent employs cheap, readily available common substrates (such as Si, Ge, GaAs, or GaP) instead of expensive native substrates. The etch-stop material layer is designed to be selectively removed during processing, allowing the use of low-cost substrates that would normally be unsuitable for high-quality heteroepitaxial growth. This approach treats the substrate as a disposable sacrificial element, replacing it with a permanent template structure that provides the necessary crystallographic orientation.

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

Solution Approach 2:

The patent creates a composite structure consisting of the common substrate, etch-stop material layer, and orientation-patterned epitaxial layer. This composite material system combines the advantages of low-cost substrates with the functional properties of high-quality epitaxial layers, achieving both cost reduction and growth quality improvement through the synergistic combination of different materials with complementary properties.

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This method enables the preparation of high-quality orientation-patterned templates on common substrates like Si or Ge, overcoming the limitations of traditional techniques and facilitating subsequent thick growth for applications in frequency conversion devices, while reducing costs and simplifying the process.

Implementation Method 1

depositing a first layer of a first material on a common substrate by a far-from-equilibrium process

Methodology Applied
Scientific EffectEpitaxy: Epitaxy

Implementation Method 2

depositing a first layer of a second material on the first layer of the first material by a close-to-equilibrium process

Methodology Applied
Scientific EffectEpitaxy: Epitaxy

Implementation Method 3

bonded to achieve high-quality thick growth

Methodology Applied
Scientific EffectWafer bonding: Welding

Data Source

PatentUS11646201B1Method for fabrication of orientation-patterned templates on common substrates
Publication Date: 2023.05.09 THE GOVERNMENT OF THE UNITED STATES AS REPRESENTED BY THE SECRETARY OF THE AIR FORCE
  • US11646201B1 patent drawing
  • US11646201B1 patent drawing
  • US11646201B1 patent drawing

AI summary

A method for preparation of orientation-patterned (OP) templates comprising the steps of: depositing a first layer of a first material on a common substrate by a far-from-equilibrium process; and depositing a first layer of a second material on the first layer of the first material by a close-to-equilibrium process, wherein a first assembly is formed. The first material and the second material may be the same material or different materials. The substrate material may be Al2O3 (sapphire), silicon (Si), germanium (Ge), GaAs, GaP, GaSb, InAs, InP, CdTe, CdS, CdSe, or GaSe. The first material deposited on the common substrate may be one or more electronic or optical binary materials from the group consisting of AlN, GaN, GaP, InP, GaAs, InAs, AlAs, ZnSe, GaSe, ZnTe, CdTe, HgTe, GaSb, SiC, CdS, CdSe, or their ternaries or quaternaries. The far-from-equilibrium process is one of MOCVD and MBE, and the close-to-equilibrium process is HVPE.