Organic Solid Crystal Optical Modulator for Tunable Refractive Index

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Solution Overview

Problem

Current technologies for virtual and augmented reality devices lack materials with improved optical properties such as controllable refractive index, birefringence, and optical clarity, which are essential for high-performance display systems and optical modulation.

Innovation Solution

The development of organic solid crystal (OSC) materials with tunable refractive index and birefringence, achieved through various manufacturing methods including epitaxial and non-epitaxial growth processes, which can be integrated into thin films and optical systems for enhanced optical performance.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Ease of manufacture

If organic materials are used in VR/AR devices, then processability and electrical response are improved, but optical properties such as refractive index control and birefringence are insufficient

Engineering Contradiction:
ImproveprocessabilityVSAvoidoptical properties
Core Design Contradiction:
Ease of manufactureVSReliability

Solution Approach 1:

The patent applies parameter changes by systematically modifying molecular structures through electron withdrawing groups (EWGs) to tune optical properties. Specific parameters including refractive index, birefringence, and HOMO-LUMO gaps are adjusted by changing molecular composition and structure, achieving controllable optical characteristics while maintaining organic material processability

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent employs composite materials by combining organic molecules with specific electron withdrawing groups (such as fluorine, chlorine, nitro, cyano groups) to create composite molecular structures. These composite structures integrate the processability of organic materials with enhanced and tunable optical properties, effectively resolving the contradiction between ease of manufacture and optical performance

Inventive Principle:
Principle #40Composite materials

2Reliability

If inorganic crystals are used, then optical properties are superior, but device complexity and integration difficulty increase

Engineering Contradiction:
Improveoptical propertiesVSAvoidintegration difficulty
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent substitutes inorganic crystal materials with organic solid crystal materials that can be processed using solution-based methods rather than complex mechanical or high-energy processing required for inorganic crystals. This substitution maintains superior optical properties while dramatically simplifying device integration and manufacturing processes

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Solution Approach 2:

By changing the material phase from amorphous to solid crystal through controlled crystallization processes, the patent achieves inorganic-crystal-level optical properties in organic materials, enabling refractive index control and birefringence without the integration complexity of traditional inorganic crystals

Inventive Principle:
Principle #35Parameter changes

3Speed

If liquid crystals are used, then electrical response is good, but optical clarity and broadband efficiency are limited

Engineering Contradiction:
Improveelectrical responseVSAvoidoptical clarity
Core Design Contradiction:
SpeedVSReliability

Solution Approach 1:

The patent utilizes phase transitions by transitioning from liquid crystal phase to solid crystal phase. This phase transition enables the material to maintain fast electrical response characteristics while achieving superior optical clarity, broadband efficiency, and controllable refractive index properties that are limited in liquid crystal phase

Inventive Principle:
Principle #36Phase transitions

Solution Approach 2:

By creating composite molecular structures with specific electron withdrawing groups within the solid crystal lattice, the patent achieves a material that combines the electrical responsiveness characteristic of liquid crystals with the optical clarity and stability of solid crystals, effectively resolving the contradiction between electrical response speed and optical quality

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

These OSC materials provide high broadband efficiency, off-axis contrast, and active tunability, enabling improved performance in display systems and optical modulation, rivaling inorganic crystals while offering the processability and electrical response of liquid crystals.

Implementation Method 1

organic solid crystal (OSC) materials with tunable refractive index and birefringence

Methodology Applied
Scientific EffectBirefringence: Birefringence

Implementation Method 2

epitaxial and non-epitaxial growth processes

Methodology Applied
Scientific EffectEpitaxy: Epitaxy

Data Source

PatentUS20240151993A1Electron withdrawing group (EWG)-containing organic molecules for improved optical properties in ar/VR components
Publication Date: 2024.05.09 META PLATFORMS TECHNOLOGIES LLC
  • US20240151993A1 patent drawing
  • US20240151993A1 patent drawing
  • US20240151993A1 patent drawing

AI summary

An optical modulator includes an organic solid crystal thin film having an organic molecule and an electron withdrawing group (EWG) bonded to the organic molecule, a primary electrode disposed over a first region of the organic solid crystal thin film, and a secondary electrode disposed over a second region of the organic solid crystal thin film, wherein an optical property of the organic solid crystal thin film is configured to change in response to a changing voltage between the primary electrode and the secondary electrode.