Omnidirectional Structural Color Paint Using Multilayer Pigments

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Solution Overview

Problem

Conventional paints rely on pigments for color, which offer moderate reflectivity and broad wavelength reflection, failing to replicate the narrow, omnidirectional structural colors found in nature, such as those in insects and butterflies, which are based on nanoscopic multilayer structures.

Innovation Solution

A paint composition incorporating omnidirectional structural color (OSC) pigments made from multilayer flakes with specific refractive index contrasts and thicknesses, providing a narrow reflection band of less than 200 nanometers when viewed from various angles, combined with a binder and optional solvent and additives.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If conventional pigments are used for color, then the paint can be easily manufactured and applied, but the reflection band is broad and reflectivity is moderate (50-60%)

Engineering Contradiction:
Improvereflection band widthVSAvoidpaint composition complexity
Core Design Contradiction:
Manufacturing precisionVSEase of manufacture

Solution Approach 1:

The patent uses multilayer composite structures with alternating high and low refractive index materials (such as TiO2 and SiO2 layers) to create omnidirectional structural color pigments. This composite approach enables narrow reflection bands with high reflectivity while maintaining manufacturability through established coating techniques.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent controls the thickness of individual layers in the multilayer structure to precisely tune the reflection band width and central wavelength. By adjusting layer thickness parameters (typically quarter-wave thicknesses), the reflection band can be narrowed to less than 100nm while maintaining omnidirectional performance.

Inventive Principle:
Principle #35Parameter changes

2Reliability

If conventional pigments are used, then the paint composition is simple, but the color appearance changes with viewing angle and lacks omnidirectional consistency

Engineering Contradiction:
Improvecolor consistency across viewing anglesVSAvoidpigment structure complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent transitions from conventional two-dimensional pigment particles to three-dimensional multilayer flake structures with controlled aspect ratios. This dimensional change enables omnidirectional light reflection by creating a structure that maintains its optical properties across a wide range of incident angles (0-80 degrees).

Inventive Principle:
Principle #17Another dimension (Dimensionality change)

Solution Approach 2:

The pigment is segmented into multiple thin layers with alternating refractive indices, where each layer contributes to the overall optical interference effect. This segmentation creates a photonic crystal structure that produces angle-independent structural color through constructive interference of reflected light waves.

Inventive Principle:
Principle #1Segmentation

3Manufacturing precision

If multilayer nanoscopic structures are used to achieve narrow reflection bands, then reflectivity increases to near 100%, but the manufacturing complexity increases significantly

Engineering Contradiction:
Improvereflection band widthVSAvoidmaterial layers required
Core Design Contradiction:
Manufacturing precisionVSQuantity of substance

Solution Approach 1:

The patent uses a moderate number of bilayer repeats (typically 5-15 pairs) rather than attempting to create perfect omnidirectional reflection with excessive layers. This partial action approach achieves sufficient narrow reflection band width and high reflectivity while keeping the structure manufacturable and the quantity of materials reasonable.

Inventive Principle:
Principle #16Partial or excessive action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The OSC paint achieves a consistent, narrow reflection band across different viewing angles, mimicking natural structural colors with high reflectivity, suitable for automotive and other applications.

Implementation Method 1

Such colors found in nature are not based on pigments, but on the interference of light reflected from either a nanoscopic multilayer structure of alternative high and low refractive index materials

Methodology Applied
Scientific EffectLight interference: Interference

Implementation Method 2

the interference of light reflected from either a nanoscopic multilayer structure of alternative high and low refractive index materials or a regular array of nano-sized particles

Methodology Applied
Scientific EffectPhotonic crystal reflection: Photonic Crystal

Data Source

PatentUS8323391B2Omnidirectional structural color paint
Publication Date: 2012.12.04 TOYOTA MOTOR CO LTD
  • US8323391B2 patent drawing
  • US8323391B2 patent drawing
  • US8323391B2 patent drawing

AI summary

A paint composition is disclosed, the paint having a binder and an omnidirectional structural color pigment dispersed throughout the binder. The omnidirectional structural color pigment can be made from a plurality of flakes that have a multilayer structure, the pigment and the paint having a reflection band of less than 200 nanometers when viewed from angles between 0 to 45 degrees.