Oxazoline Copolymer Antimicrobial Durability

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Solution Overview

Problem

Existing antimicrobial and antifouling technologies for electronic products face issues such as leaching of antimicrobial additives, insufficient durability, and high costs associated with fluorine coatings, making it challenging to provide long-term protection without compromising material compatibility and economic viability.

Innovation Solution

Development of an oxazoline-based copolymer with specific structural units that can be processed through extrusion and injection molding, providing durable antimicrobial and antifouling functionality without leaching, and ensuring compatibility with polymer resins, thereby enhancing the durability and effectiveness of antimicrobial/antifouling properties.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If metal compounds (Zn) are added to provide antimicrobial functionality, then antimicrobial property is improved, but the additive may leach into the human body and has insufficient durability

Engineering Contradiction:
Improveantimicrobial propertyVSAvoidleaching of additive
Core Design Contradiction:
ReliabilityVSLoss of substance

Solution Approach 1:

The patent combines the antimicrobial metal compound with a polymer matrix to create an integrated composite material. The metal compound is not merely added as a separate additive but is merged with the polymer through coordination bonding, forming a stable complex that prevents leaching while maintaining antimicrobial activity.

Inventive Principle:
Principle #5Merging (Combining)

Solution Approach 2:

The invention creates a composite material system consisting of metal compound-polymer complexes. This composite structure integrates the antimicrobial properties of metal compounds with the structural integrity and durability of polymers, solving both the antimicrobial effectiveness and durability issues simultaneously.

Inventive Principle:
Principle #40Composite materials

2Reliability

If N-halamine polymer is added to provide antimicrobial functionality, then antimicrobial property is improved, but regeneration process and repeated halogen material addition are required

Engineering Contradiction:
Improveantimicrobial propertyVSAvoidregeneration process
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent extracts the halogen-containing polymer system and replaces it with a metal compound-polymer complex system. This extraction eliminates the need for regeneration processes and repeated halogen addition, as the metal compound provides sustained antimicrobial activity through its stable coordination with the polymer matrix.

Inventive Principle:
Principle #2Taking out (Extraction)

3Reliability

If fluorine coating is applied for antifouling, then antifouling property is improved, but the technique is expensive, involves complicated synthesis process, and has insufficient durability

Engineering Contradiction:
Improveantifouling propertyVSAvoidsynthesis process complexity
Core Design Contradiction:
ReliabilityVSEase of manufacture

Solution Approach 1:

The patent changes the chemical composition parameters by replacing fluorine-based coatings with metal compound-polymer complexes. This parameter change simplifies the synthesis process, reduces manufacturing costs, and improves durability while maintaining antifouling properties through the stable coordination structure of the metal-polymer complex.

Inventive Principle:
Principle #35Parameter changes

4Reliability

If fluorine coating is applied for antifouling, then antifouling property is improved, but the technique is expensive and has insufficient durability

Engineering Contradiction:
Improveantifouling propertyVSAvoiddurability
Core Design Contradiction:
ReliabilityVSDuration of action of stationary object

Solution Approach 1:

The invention employs composite material structure where metal compounds are coordinated with polymer matrices to form durable antifouling layers. This composite approach enhances durability compared to fluorine coatings by creating a more stable and integrated structure that resists degradation over time.

Inventive Principle:
Principle #40Composite materials

Data Source

PatentUS9969830B2Oxazoline modified copolymer, composition including oxazoline modified copolymer, and article manufactured from the composition
Publication Date: 2018.05.15 SAMSUNG ELECTRONICS CO LTD
  • US9969830B2 patent drawing
  • US9969830B2 patent drawing
  • US9969830B2 patent drawing

AI summary

A copolymer includes a first structural unit selected from Chemical Formula 1, Chemical Formula 2, and a combination thereof and a second structural unit selected from Chemical Formula 3, Chemical Formula 4, and a combination thereof; and a composition including the copolymer and an article manufactured from the composition are provided.Definitions of Chemical Formulae 1 to 4 are the same as described in the detailed description.