2-Oxazoline Aqueous Dispersion for Stable High-Pressure Coating

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Solution Overview

Problem

Conventional resin emulsions with 2-oxazoline groups exhibit insufficient mechanical stability when sprayed at high pressure, leading to aggregate formation and nozzle clogging, which affects productivity in coating processes.

Innovation Solution

An aqueous dispersion containing a polymer with 2-oxazoline groups and a surfactant comprising a sulfuric acid ester compound, with specific chemical structures, is used to enhance mechanical stability.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If the aqueous resin composition is sprayed at higher pressure to perform coating in a shorter period of time, then the coating speed is improved, but the resin emulsion produces aggregates leading to nozzle clogging

Engineering Contradiction:
Improvecoating speedVSAvoidmechanical stability
Core Design Contradiction:
ProductivityVSReliability

Solution Approach 1:

The patent changes the chemical composition parameters of the surfactant system by incorporating a specific sulfuric acid ester compound with defined molecular structure (R1—O—(R2O)nSO3X where R1 is C8-C20 aliphatic hydrocarbon, R2 is C2-C4 alkylene, and n is 2-15). This parameter change in surfactant composition improves mechanical stability and prevents aggregate formation during high-pressure spraying, enabling both high coating speed and reliable performance

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates a composite surfactant system combining the sulfuric acid ester compound with other surfactants in a specific ratio (50-100% by mass of the sulfuric acid ester compound relative to total surfactant). This composite approach synergistically enhances the mechanical stability of the resin emulsion, preventing aggregation under high-shear conditions while maintaining coating efficiency

Inventive Principle:
Principle #40Composite materials

Data Source

PatentUS12473456B2Aqueous dispersion, production method therefor, coating composition, and coating film
Publication Date: 2025.11.18 NIPPON SHOKUBAI CO LTD
  • US12473456B2 patent drawing
  • US12473456B2 patent drawing
  • US12473456B2 patent drawing

AI summary

An aqueous dispersion including a polymer having a 2-oxazoline group; and a surfactant, the surfactant containing a sulfuric acid ester compound represented by the following Chemical Formula (S):R1—O—(R2O)nSO3X  (S)wherein R1 represents an aliphatic hydrocarbon group having 8 to 20 carbon atoms; R2 represents an alkylene group having 2 to 4 carbon atoms; n represents 2 to 15; and X represents a monovalent cation.