Oxidation Catalyst NOx Differential Monitoring

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Solution Overview

Problem

Ensuring effective NOx reduction in exhaust gas treatment systems, particularly in diesel engines, across various operating conditions remains a challenge due to the decline in catalytic activity of oxidation catalysts over time and cross-sensitivity issues with NOx sensors.

Innovation Solution

A method for diagnosing the performance of oxidation catalysts in exhaust gas treatment systems by measuring NOx differentials and ammonia production using upstream and downstream NOx sensors, correlating NOx reduction performance to oxidizing capabilities, and utilizing a catalytic composition capable of oxidizing NOx species and reducing them to ammonia, even under rich conditions.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If oxidation catalyst activity is maintained over time, then NOx reduction efficiency is improved, but catalyst cost and system complexity increase

Engineering Contradiction:
Improvecatalyst performance stabilityVSAvoiddiagnosis system complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent implements a feedback mechanism by continuously monitoring NOx concentrations upstream and downstream of the oxidation catalyst and comparing the differential to threshold values. This feedback loop enables real-time assessment of catalyst performance and triggers diagnostic routines when degradation is detected, allowing maintenance or replacement decisions based on actual performance rather than fixed schedules.

Inventive Principle:
Principle #23Feedback

Solution Approach 2:

The system performs self-diagnosis by using the existing NOx sensors and control module to automatically assess catalyst health. The control module executes diagnostic routines that interpret sensor data and determine catalyst performance status without requiring external inspection equipment or complex additional diagnostic systems.

Inventive Principle:
Principle #25Self-service

2Measurement precision

If NOx sensor cross-sensitivity is addressed, then measurement precision is improved, but system complexity and calibration requirements increase

Engineering Contradiction:
ImproveNOx concentration measurement accuracyVSAvoidsensor calibration complexity
Core Design Contradiction:
Measurement precisionVSDevice complexity

Solution Approach 1:

The patent applies partial correction by adjusting sensor readings only when specific conditions indicate cross-sensitivity interference. Rather than implementing continuous complex calibration, the system uses conditional logic to apply corrections only when necessary, based on detected patterns such as ammonia presence or specific operating conditions that trigger cross-sensitivity issues.

Inventive Principle:
Principle #16Partial or excessive action

Solution Approach 2:

The system changes measurement parameters dynamically by switching between different measurement modes or correction algorithms based on operating conditions. When cross-sensitivity is detected, the system adjusts how sensor readings are interpreted or corrected, rather than relying on fixed calibration parameters throughout all operating ranges.

Inventive Principle:
Principle #35Parameter changes

3Productivity

If catalyst diagnostic capability is enhanced, then exhaust gas treatment efficiency is improved, but measurement and detection difficulty increases

Engineering Contradiction:
Improveexhaust treatment efficiencyVSAvoidcatalyst performance measurement difficulty
Core Design Contradiction:
ProductivityVSDifficulty of detecting and measuring

Solution Approach 1:

The patent uses the NOx sensor differential as an intermediary indicator of catalyst performance. Rather than directly measuring complex catalyst properties such as surface area, pore structure, or active site concentration, the system measures the easily obtainable NOx concentration differential upstream and downstream of the catalyst, which serves as a proxy indicator of catalyst health and performance.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The system replaces complex physical or chemical diagnostic methods with electronic sensor-based measurement. Instead of using sophisticated techniques such as temperature-programmed desorption, chemisorption measurements, or microscopy to assess catalyst condition, the patent substitutes these with simple electronic NOx concentration measurements and differential calculations performed by the control module.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This method effectively monitors and maintains the catalytic performance of oxidation catalysts, ensuring efficient NOx reduction and oxidation capabilities, thereby improving the overall efficiency of exhaust gas treatment systems across different engine operating conditions.

Implementation Method 1

an oxidation catalyst device (OC) having a catalytic composition (CC) and being capable of receiving exhaust gas and oxidizing one or more of combustable hydrocarbons (HC) and one or more nitrogen oxide (NOx) species

Methodology Applied
Scientific EffectCatalysis: Catalysis

Implementation Method 2

a selective catalytic reduction device (SCR) disposed downstream from and in fluid communication with the OC and configured to store NOx species and reduce NOx species in the presence of a reductant

Methodology Applied
Scientific EffectCatalysis: Catalysis

Implementation Method 3

The ammonia then reduces the NOx to nitrogen and water in the presence of the SCR catalyst

Methodology Applied
Scientific EffectReduction: Reduction

Implementation Method 4

OCs can convert NO into NO2 to alter the NO:NOx ratio of exhaust gas in order to increase the NOx reduction efficiency of the downstream SCR

Methodology Applied
Scientific EffectOxidation: Oxidation

Data Source

PatentUS10337377B2Methods for controlling and monitoring oxidation catalyst devices
Publication Date: 2019.07.02 GM GLOBAL TECHNOLOGY OPERATIONS LLC
  • US10337377B2 patent drawing
  • US10337377B2 patent drawing

AI summary

Exhaust gas systems includes an oxidation catalyst (OC) capable of receiving exhaust gas and oxidizing one or more of combustable hydrocarbons (HC) and one or more nitrogen oxide (NOx) species, a selective catalytic reduction device (SCR) disposed downstream from and in fluid communication with the OC, an upstream NOx sensor disposed upstream from the SCR, and a downstream NOx sensor disposed downstream from the SCR. Methods for controlling systems include providing exhaust gas to the OC and subsequently the SCR, measuring an upstream exhaust gas NOx concentration, measuring a downstream exhaust gas NOx concentration, determining a NOx differential by subtracting the downstream exhaust gas NOx concentration from the upstream exhaust gas NOx concentration; and comparing the NOx differential to a differential threshold to determine OC catalytic performance. The method is conducted under while OC is above a NOx to NH3 conversion yield threshold, and/or under rich conditions.