Oxidation Layer Treatment for SiGe Trench Surface Uniformity

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Solution Overview

Problem

Conventional semiconductor processes face challenges in achieving surface uniformity and reducing dislocation defects, particularly in silicon-germanium (SiGe) based CMOS manufacturing, which affects the performance and reliability of integrated circuits due to lattice mismatch and uneven surface formation during plasma etching.

Innovation Solution

The implementation of an oxidation-deoxidation layer treatment process, where an oxidation layer is formed and then removed, selectively binding and eliminating surface defects, resulting in a substantially flat and uniform substrate surface, allowing for regular growth of the silicon-germanium layer along the lattice direction.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Volume of moving object

If plasma etching is used to define trench regions, then high aspect ratio trenches can be formed, but surface defects and non-uniformity are introduced

Engineering Contradiction:
Improvetrench depthVSAvoidsurface uniformity
Core Design Contradiction:
Volume of moving objectVSManufacturing precision

Solution Approach 1:

An oxidation layer is formed on the trench surface before subsequent processing steps. This preliminary oxidation action prepares the surface by creating a uniform oxide layer that will be selectively removed later, thereby eliminating surface defects introduced during plasma etching and ensuring uniformity for subsequent SiGe layer deposition.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The oxidation layer acts as an intermediary between the plasma-etched trench surface and the SiGe layer. By forming and subsequently removing this intermediate oxidation layer, surface defects are eliminated without affecting the underlying trench structure, enabling uniform SiGe growth on the pre-defined deep trench geometry.

Inventive Principle:
Principle #24Intermediary (Mediator)

2Productivity

If silicon-germanium layer is formed directly on plasma etched surface, then manufacturing steps are reduced, but dislocation defects occur due to lattice mismatch

Engineering Contradiction:
Improvemanufacturing efficiencyVSAvoiddevice performance
Core Design Contradiction:
ProductivityVSReliability

Solution Approach 1:

The oxidation layer is formed as a preliminary step before SiGe deposition. Although this adds a process step, it prepares the surface by eliminating defects that would cause dislocations, thereby ensuring reliable device performance while maintaining manufacturing efficiency through a straightforward process sequence.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The oxidation layer serves as a temporary intermediary that mediates between the plasma-etched surface and the SiGe layer. It provides a clean, defect-free interface for SiGe growth, preventing dislocation defects caused by lattice mismatch while allowing the process to remain efficient with a single oxidation step.

Inventive Principle:
Principle #24Intermediary (Mediator)

3Manufacturing precision

If oxidation layer is formed and removed, then surface uniformity is improved, but additional process steps are required

Engineering Contradiction:
Improvesurface uniformityVSAvoidprocess complexity
Core Design Contradiction:
Manufacturing precisionVSDevice complexity

Solution Approach 1:

The oxidation step is performed as a preliminary action that creates a uniform surface layer. Although it adds a process step, the oxidation conditions are optimized to form the layer quickly, and the subsequent removal is straightforward, thereby improving surface uniformity without significantly increasing overall process complexity.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The oxidation process parameters (temperature, oxygen flow, time) are optimized to form the oxidation layer efficiently. By controlling these parameters, the oxidation and removal steps are streamlined, improving surface uniformity while minimizing the increase in process complexity through precise parameter management.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This process improves the surface quality of the substrate, reducing dislocation defects and enhancing the performance of CMOS devices by ensuring a uniform interface for filling materials and increasing charge carrier mobility, thereby boosting the operational speed and reliability of integrated circuits.

Implementation Method 1

an oxidation layer is formed and then removed, selectively binding and eliminating surface defects

Methodology Applied
Scientific EffectOxidation: Oxidation

Data Source

PatentUS9449866B2Methods and systems for using oxidation layers to improve device surface uniformity
Publication Date: 2016.09.20 SHANGHAI HUALI MICROELECTRONICS CORP
  • US9449866B2 patent drawing
  • US9449866B2 patent drawing
  • US9449866B2 patent drawing

AI summary

The invention discloses a treatment process for a semiconductor, comprising providing a substrate, the substrate comprises silicon material; defining a trench region; removing the trench region using a plasma etching process and exposing a trench surface, the trench surface comprising surface defects; forming an oxidation layer overlaying the trench surface; removing the oxidation layer and at least a portion of the surface defects; expositing a treated trench surface, the treated trench surface being substantially free from surface defects; and forming a layer of silicon germanium material overlaying the treated trench surface. The invention further provides a semiconductor processing technique used to eliminate or reduce dislocation defect on the semiconductor device and improve device performance. In the treatment process, a substrate is subjected to at least one oxidation-deoxidation processes, where an oxidation layer is formed and then removed.