Oxidation-Responsive Polymer Indicator for Sterilization Degree Measurement

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Solution Overview

Problem

Current medical device sterilization processes lack a reliable method to determine the degree of oxidative treatment, particularly in ensuring the complete removal of bioburden, which is crucial for preventing cross-contamination and ensuring device readiness for reuse.

Innovation Solution

A system and method utilizing an oxidation-responsive polymer indicator that discolors based on exposure to oxidative chemicals, allowing for measurement of discoloration against a threshold color value to determine the degree of oxidative treatment, comprising a polymer with amine, methylene, or methine groups that form quinones upon oxidation, and a color value device to assess this discoloration.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If an oxidative treatment is applied to sterilize a medical device, then the sterilization effectiveness is improved, but the ability to measure the degree of treatment is insufficient

Engineering Contradiction:
Improvesterilization effectivenessVSAvoiddegree of oxidative treatment measurement
Core Design Contradiction:
ReliabilityVSMeasurement precision

Solution Approach 1:

The patent employs a polymer indicator containing amine, methylene, or methine groups that undergo oxidation-induced color changes when exposed to oxidative chemicals during sterilization treatment. The colorimetric transformation provides a visual and measurable indicator of the treatment degree, directly resolving the measurement precision deficiency while maintaining sterilization effectiveness.

Inventive Principle:
Principle #32Color changes

Solution Approach 2:

The polymer indicator acts as an intermediary substance between the oxidative treatment and the measurement system. It chemically interacts with the oxidative chemicals through oxidation reactions, transforming the invisible chemical process into a visible color change that can be quantified, thereby enabling precise measurement of the treatment degree.

Inventive Principle:
Principle #24Intermediary (Mediator)

2Measurement precision

If a polymer indicator with oxidation-responsive groups is used, then the measurement capability is improved, but the device complexity increases

Engineering Contradiction:
Improveoxidative treatment degree determinationVSAvoidindicator system complexity
Core Design Contradiction:
Measurement precisionVSDevice complexity

Solution Approach 1:

The patent applies the indicator polymer locally to the medical device surface rather than requiring a complete system overhaul. The polymer contains specific oxidation-responsive functional groups (amine, methylene, or methine) that are strategically positioned to interact with oxidative chemicals, providing localized measurement capability without complicating the overall device structure.

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The indicator polymer is designed as a disposable or single-use component that can be applied, used, and discarded after one sterilization cycle. This approach avoids the need for complex reusable measurement systems with calibration and maintenance requirements, reducing overall device complexity while maintaining measurement precision.

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

Enables precise determination of the oxidative treatment's effectiveness, ensuring the medical device is adequately sterilized by correlating the indicator's discoloration with the exposure concentration and time of oxidative chemicals, thereby ensuring the device's sterility and readiness for reuse.

Implementation Method 1

an indicator comprising a polymer, said indicator being suitable to discoloration based on an oxidation of the polymer by a process condition of the oxidative treatment oxidizing the polymer

Methodology Applied
Scientific EffectOxidation: Oxidation

Data Source

PatentEP3814769B1Apparatus, method, and system for indication of an oxidative treatment
Publication Date: 2024.09.04 ASP GLOBAL MFG GMBH
  • EP3814769B1 patent drawingFigure 1
  • EP3814769B1 patent drawingFigure 2
  • EP3814769B1 patent drawing

AI summary

An indicator and method of use thereof, and indicator system and method of use thereof are provided to determine the degree of an oxidative treatment. An indicator is incorporated into the oxidative treatment. The object and the indicator are subjected to the oxidative treatment. A discoloration of the indicator occurs based on an oxidation of the polymer by a process condition of the oxidative treatment oxidizing the polymer. The discoloration of the indicator is measured against a threshold color value to determine the degree of the oxidative treatment.