Oxidation Reactor Inlet Geometry for Refractory Stress Reduction

Resolve Bottlenecks,
Find Innovative Solutions
Generate Solutions

Solution Overview

Problem

Existing oxidation reactors for partial oxidation of hydrocarbonaceous feed streams face challenges such as mechanical stress on refractory protective layers, limited reactor diameter, and reduced flexibility in construction, which affect their integrity and efficiency.

Innovation Solution

The oxidation reactor is designed with a combination of a dome-shaped first section and a frustoconical second section, merging into a cylindrical third section, all with refractory protective layers. This configuration allows for improved mixing of product gases, increased reactor volume, and reduced mechanical stress on the refractory lining.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Length of stationary object

If a dome-shaped inlet region is used, then the transition from small to large diameter is achieved over a shorter length, but the mechanical stresses from thermal expansion become more complex and the refractory protective layer integrity is compromised

Engineering Contradiction:
Improvelength of inlet regionVSAvoidintegrity of refractory protective layer
Core Design Contradiction:
Length of stationary objectVSStrength

Solution Approach 1:

The inlet region is divided into two separate sections: a dome-shaped first section for achieving diameter transition, and a frustoconical second section for stress distribution. This segmentation allows each section to perform its specific function optimally without compromising the other.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

Different geometric configurations are applied to different sections of the inlet region. The dome-shaped first section provides compact diameter transition, while the frustoconical second section with its gradual slope provides mechanical stress relief, creating local optimization of properties.

Inventive Principle:
Principle #3Local quality

2Volume of stationary object

If the reactor diameter is increased, then the reactor volume is increased, but the mechanical stresses on the refractory protective layer increase and affect integrity

Engineering Contradiction:
Improvereactor volumeVSAvoidmechanical stress on refractory protective layer
Core Design Contradiction:
Volume of stationary objectVSStress or pressure

Solution Approach 1:

The dome-shaped first section uses a curved spherical geometry to achieve the diameter transition, which distributes thermal expansion stresses more evenly compared to sharp angular transitions, reducing stress concentration points.

Inventive Principle:
Principle #14Spheroidality (Curvature)

Solution Approach 2:

By separating the diameter transition function (dome section) from the stress distribution function (frustoconical section), the design allows the reactor to achieve large volume while the frustoconical section specifically addresses stress management.

Inventive Principle:
Principle #1Segmentation

3Length of stationary object

If a frustoconical inlet region with large angle is used, then the diameter transition is achieved, but the flame geometry is impaired due to recirculation zones and turbulence

Engineering Contradiction:
Improvediameter transition lengthVSAvoidflame geometry
Core Design Contradiction:
Length of stationary objectVSShape

Solution Approach 1:

The dome-shaped first section provides a smooth curved transition that avoids sharp angles, reducing turbulence and recirculation zones while achieving the necessary diameter change, thereby preserving flame geometry.

Inventive Principle:
Principle #14Spheroidality (Curvature)

Solution Approach 2:

The frustoconical second section uses a gentle slope specifically optimized to balance diameter transition with minimal disturbance to the flame, creating local conditions that protect flame geometry while achieving the overall diameter change.

Inventive Principle:
Principle #3Local quality

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The innovative reactor design enhances the mechanical stability and thermal control of the oxidation process, increasing the reactor's volume while minimizing forces and stresses on the refractory protective layer, thus improving the overall efficiency and longevity of the reactor.

Implementation Method 1

lined on its inside with one or more layers of refractory material, for example refractory bricks, which thus form protective layers against the heat released in the reactor interior

Methodology Applied
Scientific EffectThermal insulation: Thermal Insulation

Implementation Method 2

The partial oxidation of hydrocarbonaceous feed material for production of synthesis gas is typically performed at high reactor temperatures in the range from 1000° C. to 1500° C.

Methodology Applied
Scientific EffectPartial oxidation: Oxidation

Implementation Method 3

The hydrocarbonaceous feed material and the oxidant are generally mixed in a reactor in close proximity to the injection nozzles

Methodology Applied
Scientific EffectCombustion: Combustion

Data Source

PatentUS20250128944A1Oxidation reactor for partial oxidation of a feed stream with specific geometry
Publication Date: 2025.04.24 LAIR LIQUIDE SA POUR LETUDE & LEXPLOITATION DES PROCEDES GEORGES CLAUDE
  • US20250128944A1 patent drawing
  • US20250128944A1 patent drawing
  • US20250128944A1 patent drawing

AI summary

The invention relates to an oxidation reactor for partial oxidation of a feed stream with an oxygen-containing oxidant stream to give a hydrogen-containing product stream. This partial oxidation may be conducted as a noncatalytic partial oxidation (POX) or as an autothermal reforming (ATR). Useful feed streams here include hydrocarbonaceous streams, but also ammonia-containing streams. According to the invention, the inlet region of the oxidation reactor is configured as a combination of a dome-shaped region with a (frusto) conical region, where the (frusto) conical inlet region merges into the cylindrical section of the oxidation reactor.