Oxidation-Resistant Metal Particles for Semiconductor Substrates

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Solution Overview

Problem

The oxidation of copper layers on semiconductor chips impedes subsequent manufacturing processes such as die bonding, wire bonding, and molding, increasing the cost and complexity of semiconductor device packaging.

Innovation Solution

Depositing metal particles with a core of copper or aluminum and a highly oxidation-resistant shell, such as silver or gold, onto semiconductor substrates to form metal layers that protect against corrosion and enable electrical contact while allowing for wire bonding and molding.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If copper layers are deposited on semiconductor chips to allow electrical access, then electrical conductivity is improved, but oxidation occurs which impedes subsequent manufacturing processes

Engineering Contradiction:
Improveelectrical conductivityVSAvoidsubsequent manufacturing processes
Core Design Contradiction:
ReliabilityVSEase of manufacture

Solution Approach 1:

The patent applies composite materials by creating a multi-layer metal structure consisting of a copper core layer providing electrical conductivity and an outer shell layer of oxidation-resistant material (such as nickel, palladium, or platinum) protecting against oxidation. This composite structure simultaneously achieves reliable electrical conductivity while preventing oxidation that would impede subsequent manufacturing processes like die bonding, wire bonding, and molding.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The oxidation-resistant shell layer acts as an intermediary between the copper core and the external environment. This intermediate layer protects the copper from direct contact with oxidizing agents while allowing the electrical function to pass through, thereby enabling subsequent manufacturing processes without interference from oxidation.

Inventive Principle:
Principle #24Intermediary (Mediator)

2Ease of operation

If copper layers are deposited to enable electrical contact, then electrical access is improved, but oxidation increases manufacturing cost and complexity

Engineering Contradiction:
Improveelectrical accessVSAvoidpackaging complexity
Core Design Contradiction:
Ease of operationVSDevice complexity

Solution Approach 1:

By using composite metal layers with an oxidation-resistant outer shell, the patent eliminates the need for additional protective measures or process modifications that would otherwise be required to prevent copper oxidation. This reduces packaging complexity while maintaining ease of electrical access.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The oxidation-resistant shell provides self-protection for the copper layer, automatically preventing oxidation without requiring external protective measures or complex packaging processes. This self-service approach simplifies the overall manufacturing process and reduces complexity.

Inventive Principle:
Principle #25Self-service

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The oxidation-resistant metal layers prevent corrosion of the underlying copper or aluminum, ensuring reliable electrical and thermal conductivity, reducing contact resistance, and facilitating efficient packaging of semiconductor chips.

Implementation Method 1

Depositing metal particles with a core of copper or aluminum and a highly oxidation-resistant shell, such as silver or gold, onto semiconductor substrates to form metal layers

Methodology Applied
Scientific EffectPhysical Vapour Deposition: Physical Vapour Deposition

Implementation Method 2

The shells are made of a second metal material that is highly resistant to oxidation

Methodology Applied
Scientific EffectOxidation resistance: Oxidation

Implementation Method 3

ensuring reliable electrical and thermal conductivity, reducing contact resistance

Methodology Applied
Scientific EffectElectrical conduction: Conduction (electrical)

Implementation Method 4

ensuring reliable electrical and thermal conductivity

Methodology Applied
Scientific EffectThermal conduction: Conduction (thermal)

Data Source

PatentUS8912047B2Method for producing a metal layer on a substrate and device
Publication Date: 2014.12.16 INFINEON TECHNOLOGIES AG
  • US8912047B2 patent drawing
  • US8912047B2 patent drawing
  • US8912047B2 patent drawing

AI summary

A method produces a metal layer on a semiconductor substrate. A metal layer is produced on the semiconductor substrate by depositing metal particles. The metal particles include cores made of a first metal material and shells surrounding the cores. The shells are made of a second metal material that is resistant to oxidation.