Oxidative Hair Dye Stabilization with Rooibos Extract

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Solution Overview

Problem

Oxidative hair dye compositions are highly unstable, leading to ineffective results when stored for extended periods or reused, as they rapidly oxidize due to exposure to air, and existing antioxidants like ascorbic acid and sodium dithionate have limitations such as rapid degradation and undesirable reactions.

Innovation Solution

Incorporating antioxidant botanical extracts rich in flavanoid and phenolic acid components, such as Rooibos tea extract, into oxidative hair dye compositions to inhibit oxidative degradation, thereby stabilizing the dyes and allowing for multiple uses and extended storage.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If oxidative dye compositions are stored under regular atmospheric conditions, then they are easily stored and accessed, but they rapidly oxidize and lose effectiveness

Engineering Contradiction:
Improvestability of oxidative dyeVSAvoidcomplexity of antioxidant system
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent combines multiple antioxidants (ascorbic acid, sodium dithionate, and erythorbic acid) to create a composite antioxidant system that provides synergistic protection against oxidative degradation. This composite approach allows the dye composition to maintain stability without requiring complex packaging or storage conditions

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The antioxidants act as intermediary substances that intervene between the oxidative dye and atmospheric oxygen. These intermediary compounds preferentially react with oxygen or donate electrons to prevent oxidation of the dye molecules, thereby protecting the dye's effectiveness during storage

Inventive Principle:
Principle #24Intermediary (Mediator)

2Reliability

If ascorbic acid is used as antioxidant, then it provides initial protection, but it rapidly loses activity when exposed to air

Engineering Contradiction:
Improveantioxidant effectivenessVSAvoidduration of antioxidant activity
Core Design Contradiction:
ReliabilityVSDuration of action of stationary object

Solution Approach 1:

The patent changes the chemical parameters of the antioxidant system by combining three different antioxidants with complementary properties. Erythorbic acid, in particular, provides long-lasting activity as it is more stable in air than ascorbic acid alone, thereby extending the duration of antioxidant protection

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates a sequential antioxidant system where ascorbic acid acts first but is gradually consumed, then erythorbic acid and sodium dithionate provide continued protection. As one antioxidant is depleted, others take over, ensuring continuous protection throughout the storage period

Inventive Principle:
Principle #34Discarding and recovering

3Reliability

If sodium dithionate is used as antioxidant, then it provides stabilization, but it is malodorous and undergoes undesirable secondary reactions with nitro-based dyes

Engineering Contradiction:
Improvestability of oxidative dyeVSAvoidmalodor and secondary reactions
Core Design Contradiction:
ReliabilityVSObject-generated harmful factors

Solution Approach 1:

The patent applies the sodium dithionate antioxidant in a controlled, localized manner within the multi-component system. By combining it with other antioxidants that have different reaction profiles, the harmful effects are localized to specific interactions while the overall stabilizing effect is maintained

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The patent uses erythorbic acid as a substitute or complementary antioxidant that provides similar stabilization benefits without the malodor and secondary reaction problems of sodium dithionate. Erythorbic acid copies the stabilizing function while avoiding the harmful side effects

Inventive Principle:
Principle #26Copying

4Productivity

If oxidative dye composition is used multiple times, then it reduces waste and cost, but the dye becomes ineffective after storage due to air oxidation

Engineering Contradiction:
Improvenumber of uses per containerVSAvoideffectiveness of oxidative dye
Core Design Contradiction:
ProductivityVSReliability

Solution Approach 1:

The patent incorporates a pre-formulated mixture of antioxidants into the oxidative dye composition before storage. This beforehand cushioning against oxidation allows the dye to maintain its effectiveness throughout multiple storage periods and uses, preventing degradation before it occurs

Inventive Principle:
Principle #11Beforehand cushioning (Prior cushioning)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The use of flavanoid and phenolic acid antioxidants significantly enhances the stability of oxidative hair dyes, enabling multiple applications and prolonged storage without significant loss of effectiveness, as demonstrated by maintaining color deposition and stability comparable to traditional antioxidants like erythorbic acid.

Implementation Method 1

at least one antioxidant comprising at least one flavanoid component and/or at least one phenolic acid component, present in an amount sufficient to inhibit the oxidative degradation of one or more oxidative dyes

Methodology Applied
Scientific EffectAntioxidant activity: Oxidation

Data Source

PatentEP2291172B1Oxidative hair dye compositions, methods and products
Publication Date: 2017.10.25 A VEDA CORPORATION
  • EP2291172B1 patent drawing
  • EP2291172B1 patent drawing
  • EP2291172B1 patent drawing

AI summary

Oxidative hair dye compositions containing at least one antioxidant botanical extract operable to inhibit the oxidative degradation of one or more oxidative dyes present in the oxidative dye composition, methods for coloring hair, and methods and products that enable multiple use oxidative dye containers.