Oxidative Hair Dye Composition for Persistent White Hair Coverage

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Solution Overview

Problem

Existing hair dye compositions using oxidation dye precursors fail to achieve intense, persistent, and non-selective coloration with good build-up and resistance to external factors such as washing, light, and perspiration, particularly affecting white hair coverage and color intensity.

Innovation Solution

A cosmetic composition comprising 6-hydroxybenzomorpholine, hydroxyethyl-3,4-methylenedioxyaniline, and N,N-dicarboxymethylglutamic acid, or their salts, combined with optional additional couplers and oxidizing agents, to enhance dyeing performance on keratin fibers.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional oxidation dye precursors are used, then hair dyeing can be achieved, but the coloration lacks intensity and persistence especially on white hair

Engineering Contradiction:
Improvecoloration intensity and persistenceVSAvoiddyeing efficiency
Core Design Contradiction:
ReliabilityVSProductivity

Solution Approach 1:

The patent combines multiple oxidation dye precursors (6-hydroxybenzomorpholine, hydroxyethyl-3,4-methylenedioxyaniline) with specific couplers (meta-diaminobenzenes, meta-aminophenols, meta-diphenols) and heterocyclic compounds to create a composite dyeing system. This composite approach synergistically enhances both color intensity and persistence, particularly on white hair, while maintaining acceptable dyeing efficiency.

Inventive Principle:
Principle #40Composite materials

2Reliability

If conventional dye compositions are used, then hair can be colored, but selectivity varies significantly between end and root of the same lock

Engineering Contradiction:
Improvecolor uniformityVSAvoiddye composition complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent employs different oxidation dye precursors and couplers with varying molecular weights, solubilities, and reactivity profiles to achieve localized optimization. Lighter components penetrate the hair shaft uniformly from root to end, while heavier components provide persistent coloration at the root, creating a balanced color distribution that reduces selectivity differences.

Inventive Principle:
Principle #3Local quality

3Adaptability or versatility

If conventional oxidation bases and couplers are combined, then a wide range of colors can be obtained, but color build-up is insufficient and coverage of white hair is poor

Engineering Contradiction:
Improvecolor varietyVSAvoidcolor build-up and white hair coverage
Core Design Contradiction:
Adaptability or versatilityVSReliability

Solution Approach 1:

The patent merges oxidation dye precursors with direct dyes and basic dyes in a single composition. The oxidation components provide color variety through coupling reactions, while the direct and basic dyes contribute to rapid color build-up and excellent white hair coverage. This merging of different dyeing mechanisms achieves both color versatility and reliable performance.

Inventive Principle:
Principle #5Merging (Combining)

4Reliability

If conventional dye compositions are used, then hair can be colored, but resistance to external factors such as washing, light, and perspiration is insufficient

Engineering Contradiction:
Improvecolor fastnessVSAvoiddegradation from external agents
Core Design Contradiction:
ReliabilityVSObject-affected harmful factors

Solution Approach 1:

The patent incorporates antioxidants and stabilizing agents in the dye composition to prevent premature oxidation and degradation of the dye precursors and couplers. These protective components are applied simultaneously with the dye, creating a protective environment that enhances color fastness against washing, light, and perspiration throughout the dyeing process and aftercare.

Inventive Principle:
Principle #10Preliminary action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The composition achieves intense, persistent, and non-selective coloration with improved resistance to external factors, ensuring good coverage and color intensity even after multiple shampooing operations.

Implementation Method 1

These oxidation bases are colourless or weakly coloured compounds, which, when combined with oxidizing products, are able to produce coloured compounds by a process of oxidative condensation.

Methodology Applied
Scientific EffectOxidative condensation: Oxidation

Data Source

PatentEP4262691B1Cosmetic composition comprising a combination of two particular couplers and n,n-dicarboxymethylglutamic acid and/or its salts
Publication Date: 2026.04.08 LOREAL SA
  • EP4262691B1 patent drawing
  • EP4262691B1 patent drawing
  • EP4262691B1 patent drawing

AI summary

A subject of the present invention is a cosmetic composition comprising 6-hydroxybenzomorpholine of formula (II), hydroxyethyl-3,4-methylenedioxyaniline of formula (III), at least one compound chosen from N,N-dicarboxymethylglutamic acid, its salts and mixtures thereof. The present invention also relates to a process for dyeing keratin fibres, such as the hair, wherein the composition as described previously is applied to said fibres. Another subject of the present invention is the use of the composition according to the invention for the cosmetic treatment of keratin fibres such as the hair.