Oxide Semiconductor Electrode Structure for Threshold Voltage Stability

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Solution Overview

Problem

Oxide semiconductor transistors used in memory cells face challenges with heat treatment, leading to fluctuating threshold voltages and reduced heat resistance due to oxygen deficiency and absorption issues during the manufacturing process.

Innovation Solution

The semiconductor device incorporates a specific electrode structure with regions of indium, zinc, and oxygen, along with metal elements like titanium, tantalum, and tungsten, where the third and fourth regions have higher oxygen concentrations, preventing oxygen absorption and maintaining high resistance, thus stabilizing the threshold voltage and enhancing heat resistance.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If oxide semiconductor transistor undergoes heat treatment during memory cell and wiring formation, then memory cell structure is formed, but threshold voltage fluctuates and heat resistance decreases due to oxygen deficiency and absorption

Engineering Contradiction:
Improveheat resistanceVSAvoidthreshold voltage stability
Core Design Contradiction:
ReliabilityVSStability of the object's composition

Solution Approach 1:

The patent applies preliminary action by forming a protective oxide layer on the oxide semiconductor layer before heat treatment. This protective layer prevents oxygen deficiency and absorption during subsequent heat treatment processes, thereby maintaining threshold voltage stability and heat resistance. The protective structure is prepared in advance to counteract the harmful effects of heat treatment.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The patent introduces an intermediary protective oxide layer between the oxide semiconductor layer and the external environment during heat treatment. This intermediary layer acts as a barrier that prevents oxygen loss from and absorption into the oxide semiconductor layer, thus maintaining its electrical characteristics and preventing threshold voltage fluctuations.

Inventive Principle:
Principle #24Intermediary (Mediator)

2Reliability

If oxide semiconductor transistor is used in memory cell switching transistor, then excellent off-operation characteristics are achieved, but heat treatment causes oxygen issues leading to performance degradation

Engineering Contradiction:
Improveoff-operation characteristicsVSAvoidoxygen deficiency and absorption during heat treatment
Core Design Contradiction:
ReliabilityVSObject-affected harmful factors

Solution Approach 1:

The patent converts the harmful effect of heat treatment into a beneficial outcome by using the heat treatment process to form a protective oxide layer on the oxide semiconductor layer. This protective layer, which would normally be considered an additional complexity, actually protects the oxide semiconductor from oxygen deficiency and absorption, thereby maintaining the excellent off-operation characteristics.

Inventive Principle:
Principle #22Blessing in disguise (Convert harm into benefit)

Solution Approach 2:

The patent creates an inert protective environment by forming an oxide layer on the oxide semiconductor layer before heat treatment. This protective layer acts as an inert barrier that isolates the oxide semiconductor from oxygen-related harmful effects during heat treatment, preserving its electrical characteristics.

Inventive Principle:
Principle #39Inert atmosphere (Inert environment)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This configuration effectively suppresses threshold voltage fluctuations and improves the heat resistance of oxide semiconductor transistors, ensuring reliable operation even after heat treatment.

Implementation Method 1

the third region having an atomic concentration of oxygen (O) higher than an atomic concentration of oxygen (O) of the second region, and the fourth region having an atomic concentration of oxygen (O) higher than an atomic concentration of oxygen (O) of the second region

Methodology Applied
Scientific EffectOxygen concentration gradient:

Data Source

PatentUS11978807B2Semiconductor device and semiconductor memory device
Publication Date: 2024.05.07 KIOXIA CORP
  • US11978807B2 patent drawing
  • US11978807B2 patent drawing
  • US11978807B2 patent drawing

AI summary

Provided is a semiconductor device of the embodiment including: an oxide semiconductor layer; a gate electrode; a first electrode electrically connected to one portion of the oxide semiconductor layer, the first electrode including a first region, second region, a third region, and a fourth region, the first region disposed between the first portion and the second region, the first region disposed between the third region and the fourth region, the first region containing at least one element of In, Zn, Sn or Cd, and oxygen, the second region containing at least one metal element of Ti, Ta, W, or Ru, the third region and the fourth region containing the at least one metal element and oxygen, the third region and the fourth region having an atomic concentration of oxygen higher than that of the second region; and a second electrode electrically connected to another portion of the oxide semiconductor layer.