Oxide Glass Composition for Light-Shielding and Low Specific Gravity

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Solution Overview

Problem

Existing glass technologies face challenges in manufacturing cover glass with excellent light-shielding and light-transmitting properties while maintaining a low specific gravity, which can lead to breakage and warping during production.

Innovation Solution

The development of oxide glass with specific compositions, including P5+, Nb ions, Bi ions, and Li+, which form a light-shielding portion with excellent light-shielding properties and a light-transmitting portion with high transmittance, all while maintaining a low specific gravity.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Object-affected harmful factors

If the weight of the glass sheet is increased to improve light-shielding properties, then light-shielding performance is improved, but the glass is more likely to be broken and warped during production

Engineering Contradiction:
Improvelight-shielding propertiesVSAvoidresistance to breakage and warping
Core Design Contradiction:
Object-affected harmful factorsVSStrength

Solution Approach 1:

The patent changes the chemical composition parameters of the glass by incorporating specific amounts of PbO (10-30 mass%), Bi2O3 (0.1-5 mass%), and Nb2O5 (0.1-5 mass%) to achieve optimal light-shielding properties while maintaining mechanical strength and reducing susceptibility to breakage and warping during production

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates a composite glass material combining multiple oxide components (PbO, Bi2O3, Nb2O5, SiO2, B2O3, etc.) that work synergistically to provide both excellent light-shielding properties and improved mechanical stability, preventing breakage and warping during manufacturing

Inventive Principle:
Principle #40Composite materials

2Strength

If the specific gravity of the glass is reduced to minimize breakage and warping, then production reliability is improved, but light-shielding properties may be compromised

Engineering Contradiction:
Improveresistance to breakage and warpingVSAvoidlight-shielding properties
Core Design Contradiction:
StrengthVSObject-affected harmful factors

Solution Approach 1:

The patent optimizes the specific gravity parameter by controlling the content of heavy metal oxides (PbO: 10-30 mass%, Bi2O3: 0.1-5 mass%) to achieve a balance between low specific gravity for production stability and sufficient light-shielding capability through the synergistic effect of these oxides

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent applies light-shielding oxides (PbO, Bi2O3, Nb2O5) at specific concentrations within the glass matrix to provide localized light-shielding functionality while maintaining overall low specific gravity and production reliability

Inventive Principle:
Principle #3Local quality

3Object-affected harmful factors

If a colored layer is added to the glass to achieve light-shielding properties, then light-shielding performance is improved, but the manufacturing process becomes more complex

Engineering Contradiction:
Improvelight-shielding propertiesVSAvoidmanufacturing process complexity
Core Design Contradiction:
Object-affected harmful factorsVSDevice complexity

Solution Approach 1:

The patent merges the light-shielding function with the base glass material by incorporating light-shielding oxides (PbO, Bi2O3, Nb2O5) directly into the glass composition, eliminating the need for separate colored layers and simplifying the manufacturing process to a single integrated glass forming operation

Inventive Principle:
Principle #5Merging (Combining)

Solution Approach 2:

The patent makes the glass material itself multi-functional by incorporating oxides that simultaneously provide structural integrity, light-shielding properties, and coloration, eliminating the need for separate functional layers and reducing manufacturing complexity

Inventive Principle:
Principle #6Universality (Multi-functionality)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The proposed glass composition achieves excellent light-shielding and light-transmitting properties for visible light, while also reducing the specific gravity of the glass, thereby minimizing breakage and warping during production.

Implementation Method 1

a content of Nb ions is 10 to 21 cation %, a content of Bi ions is more than 0 cation % and is equal to or less than 6 cation %

Methodology Applied
Scientific EffectLight absorption: Absorption (EM radiation)

Implementation Method 2

a content of P5+ is 7 to 43 cation %, a content of Li+ is 20 cation % or more

Methodology Applied
Scientific EffectLight transmission:

Data Source

PatentUS12330984B2Glass and optical element
Publication Date: 2025.06.17 HOYA CORPORATION
  • US12330984B2 patent drawing

AI summary

Provided is oxide glass in which a content of P5+ is 7 to 43 cation %, a content of Nb ions is 10 to 21 cation %, a content of Li+ is 20 cation % or more, a total content of Nb ions and Li+ is 48 to 70 cation %, a content of Bi ions is more than 0 cation % and is equal to or less than 6 cation %, a content of Ba2+ is 5 cation % or less, a content of Zr4+ is 2 cation % or less, a total content of Ti ions and W ions is 5 cation % or less, and a cation ratio of the content of Li+ to a total content of Li+, Na+, and K+[Li+/(Li++Na++K+)] is 0.5 or more.