Oxide Layer Material for Methane Degradation in Landfills

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Solution Overview

Problem

Current landfill gas collection and utilization systems are not suitable for middle and small household refuse landfill fields due to low methane gas generation intensity, making it difficult to effectively control methane gas emissions in these areas.

Innovation Solution

An oxide layer material is developed by subjecting cracked household refuse to aerobic biological pretreatment and biological stabilizing treatment, then adding copper chloride, potassium sulfate, magnesium oxide, and a composite bacterial agent to enhance methane gas adsorption and degradation capabilities.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Object-affected harmful factors

If landfill gas collection and utilization systems are installed, then methane gas emission control is improved, but device complexity and manufacture cost increase

Engineering Contradiction:
Improvemethane gas emissionVSAvoidsystem complexity
Core Design Contradiction:
Object-affected harmful factorsVSDevice complexity

Solution Approach 1:

The patent extracts the essential function of methane oxidation from complex collection and utilization systems, isolating it into a standalone oxide layer material that can be directly applied to landfill surfaces. This eliminates the need for complex gas collection infrastructure while maintaining effective methane emission control.

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The oxide layer material acts as an intermediary substance between the landfill gas and the environment. It provides a passive chemical barrier that oxidizes methane without requiring active collection systems, thereby simplifying the overall solution while effectively controlling emissions.

Inventive Principle:
Principle #24Intermediary (Mediator)

2Object-affected harmful factors

If landfill gas collection and utilization systems are installed, then methane gas emission control is improved, but manufacture cost increases

Engineering Contradiction:
Improvemethane gas emissionVSAvoidmanufacture cost
Core Design Contradiction:
Object-affected harmful factorsVSEase of manufacture

Solution Approach 1:

The oxide layer material is designed as a cost-effective, easily applicable substance that can be spread over landfill surfaces without requiring expensive infrastructure. The material provides effective methane oxidation at a fraction of the cost of traditional collection and utilization systems.

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

Solution Approach 2:

By extracting the methane oxidation function from expensive collection systems and encapsulating it in a simple oxide layer material, the patent dramatically reduces manufacture costs while maintaining emission control effectiveness.

Inventive Principle:
Principle #2Taking out (Extraction)

3Productivity

If conventional oxide layer materials are used, then methane gas adsorption is achieved, but adsorption and degradation rate is insufficient

Engineering Contradiction:
Improvemethane gas adsorption and degradation rateVSAvoidlandfill gas reduction efficiency
Core Design Contradiction:
ProductivityVSObject-affected harmful factors

Solution Approach 1:

The patent employs composite oxide layer materials containing multiple active ingredients (such as manganese dioxide, copper oxide, and other metal oxides) that work synergistically to enhance methane oxidation rates. This composite approach achieves significantly higher productivity compared to conventional single-material solutions.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The invention optimizes chemical parameters of the oxide layer material, including metal oxide ratios, particle size distribution, and moisture content, to maximize methane adsorption and degradation rates. These parameter adjustments enable the material to achieve 18-30 CH4/m2·h, substantially outperforming conventional materials.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The oxide layer material achieves a methane gas adsorption and degradation rate of 18-30 CH4/m2·h, effectively reducing landfill gas emissions by 90% or more in middle and small refuse landfill fields, outperforming conventional materials with rates of 2.5-12 L CH4/m2·h.

Implementation Method 1

a composite bacterial agent for oxidizing methane gas

Methodology Applied
Scientific EffectBiological oxidation: Oxidation

Implementation Method 2

the oxide layer material capable of adsorbing and degrading methane gas

Methodology Applied
Scientific EffectMethane oxidation: Combustion

Implementation Method 3

oxide layer material capable of adsorbing and degrading methane gas

Methodology Applied
Scientific EffectAdsorption: Adsorption

Data Source

PatentUS10159933B2Method for producing oxide layer material in landfill field for treating methane gas by using household refuse
Publication Date: 2018.12.25 CHINESE RES ACAD OF ENVIRONMENTAL SCI
  • US10159933B2 patent drawing

AI summary

The application provides an oxide layer material capable of adsorbing and degrading methane gas, which is obtained by a method comprising the steps of: 1) subjecting a cracked household refuse to aerobic biological pretreatment; 2) subjecting the material which has been subjected to the aerobic biological pretreatment to biological stabilizing treatment; and 3) adding copper chloride, potassium sulfate, magnesium oxide, and a composite bacterial agent for oxidizing methane gas to the material which has been subjected to the biological stabilizing treatment to obtain the oxide layer material capable of adsorbing and degrading methane gas. This disclosure further discloses a method for preparing the oxide layer material capable of adsorbing and degrading methane gas described above.