Metal Oxide Layered Structure for RDL Adhesion Under Fine Pitch

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Solution Overview

Problem

The semiconductor industry faces challenges in achieving strong adhesion between metallization and dielectric layers in semiconductor devices, which can lead to delamination issues, especially as feature sizes decrease and integration density increases.

Innovation Solution

A metal oxide layered structure with a 1:1 ratio of metal to oxygen atoms is formed on the metallization pattern, either directly or after native oxide formation, to enhance adhesion between the metallization and dielectric layers, with a thickness of at least 50 Å, using processes like oxygen-containing plasma treatment.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If feature size is reduced to increase integration density, then more components can be integrated into a given area, but adhesion between metallization and dielectric layers deteriorates leading to delamination

Engineering Contradiction:
Improveintegration densityVSAvoidadhesion strength
Core Design Contradiction:
ProductivityVSReliability

Solution Approach 1:

A metal oxide intermediate layer is introduced between the metallization layer and the dielectric layer to serve as an adhesion promoter. This intermediate layer chemically bonds to both the metal and the dielectric material, preventing delamination while allowing continued miniaturization of device features to maintain high integration density.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The adhesion problem is resolved by changing the chemical composition and oxidation state of the metallization layer surface. By controlling the oxidation parameters (oxygen exposure, temperature, duration), the metal surface is transformed into a metal oxide layer with enhanced adhesion properties, enabling reliable bonding at reduced feature sizes.

Inventive Principle:
Principle #35Parameter changes

2Reliability

If a metal oxide layer is formed to improve adhesion, then delamination is reduced, but the manufacturing process complexity increases

Engineering Contradiction:
Improveadhesion strengthVSAvoidprocess complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The metal oxide adhesion layer is formed as a preliminary step before dielectric layer deposition. By performing the oxidation treatment on the metallization layer in advance, the adhesion promoter is prepared beforehand, ensuring reliable bonding without requiring additional complex processing steps during subsequent manufacturing operations.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

Oxygen plasma or other strong oxidizing environments are used to rapidly form the metal oxide layer in a controlled manner. This accelerated oxidation process creates the adhesion-promoting metal oxide layer efficiently, reducing processing time and simplifying the overall manufacturing sequence while maintaining high adhesion strength.

Inventive Principle:
Principle #38Strong oxidants (Accelerated oxidation)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach improves adhesion between metallization and dielectric layers, reducing the risk of delamination and supporting the integration of more components in smaller areas, thus enhancing the reliability and performance of semiconductor devices.

Implementation Method 1

using processes like oxygen-containing plasma treatment

Methodology Applied
Scientific EffectPlasma: Plasma

Implementation Method 2

treating the metallization pattern with an oxygen-containing plasma, the treating forming a metal oxide layer

Methodology Applied
Scientific EffectOxidation: Oxidation

Data Source

PatentUS11854826B2Metal oxide layered structure and methods of forming the same
Publication Date: 2023.12.26 TAIWAN SEMICONDUCTOR MANUFACTURING CO LTD
  • US11854826B2 patent drawing
  • US11854826B2 patent drawing
  • US11854826B2 patent drawing

AI summary

Some embodiment structures and methods are described. A structure includes an integrated circuit die at least laterally encapsulated by an encapsulant, and a redistribution structure on the integrated circuit die and encapsulant. The redistribution structure is electrically coupled to the integrated circuit die. The redistribution structure includes a first dielectric layer on at least the encapsulant, a metallization pattern on the first dielectric layer, a metal oxide layered structure on the metallization pattern, and a second dielectric layer on the first dielectric layer and the metallization pattern. The metal oxide layered structure includes a metal oxide layer having a ratio of metal atoms to oxygen atoms that is substantially 1:1, and a thickness of the metal oxide layered structure is at least 50 Å. The second dielectric layer is a photo-sensitive material. The metal oxide layered structure is disposed between the metallization pattern and the second dielectric layer.