Semiconductor Oxide Layer Refinement via Vacuum Thermal Treatment

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Solution Overview

Problem

Conventional semiconductor device passivation methods result in oxide layers with high defect densities and often require high processing temperatures, which can deteriorate semiconductor substrates and structures.

Innovation Solution

A method involving refining a semiconductor structure with a semiconductor layer and an oxide layer in a vacuum chamber, maintaining a refinement temperature between 20°C and 800°C and a total pressure below 1×10−3 mbar for at least 25 seconds, to reduce defect states and enhance oxide layer crystallinity.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional methods are used to form oxide layers for passivation, then the oxide layer can be formed, but the oxide layer will have high defect densities that deteriorate semiconductor device performance

Engineering Contradiction:
Improvesemiconductor device performanceVSAvoidoxide layer defect density
Core Design Contradiction:
ReliabilityVSManufacturing precision

Solution Approach 1:

The patent applies parameter changes by modifying the physical and chemical conditions during oxide layer formation and treatment. Specifically, it uses low-pressure oxygen environment (1-100 mbar) combined with controlled temperature ranges (200-800°C) and extended treatment times (1-60 minutes) to transform the oxide layer structure, reduce defect densities, and improve crystallinity, thereby resolving the contradiction between forming oxide layers and achieving low defect densities

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent employs an inert oxygen atmosphere at controlled low pressures (1-100 mbar) during the oxide layer treatment process. This controlled atmospheric environment prevents additional defect formation while enabling the refinement of existing oxide structures, addressing the contradiction by providing a clean environment that maintains oxide layer integrity while reducing defects

Inventive Principle:
Principle #39Inert atmosphere (Inert environment)

2Manufacturing precision

If high processing temperatures are used to form oxide layers, then oxide formation can be achieved, but the semiconductor substrates and structures will deteriorate

Engineering Contradiction:
Improveoxide layer formation qualityVSAvoidsubstrate and structure deterioration
Core Design Contradiction:
Manufacturing precisionVSObject-affected harmful factors

Solution Approach 1:

The patent resolves this contradiction by changing the temperature parameter from conventional high-temperature rapid oxidation to a controlled range of 200-800°C with extended treatment times. This parameter transformation allows sufficient oxide layer refinement and defect reduction while preventing substrate damage that would occur at higher temperatures

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent applies periodic action through extended treatment durations (1-60 minutes) at moderate temperatures. This prolonged exposure to controlled oxygen pressure and temperature conditions enables gradual oxide layer improvement without the thermal shock and damage associated with rapid high-temperature processing, thus resolving the contradiction between oxide quality and substrate integrity

Inventive Principle:
Principle #19Periodic action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach effectively lowers defect densities at the semiconductor-oxide interface and increases the degree of crystallinity of the oxide layer, improving semiconductor device performance.

Implementation Method 1

maintaining total pressure (ptot) in the vacuum chamber below a maximum total pressure (ptotmax) of 1×10−3 millibars (mbar)

Methodology Applied
Scientific EffectVacuum: Vacuum

Implementation Method 2

maintaining temperature (T) of the semiconductor structure within a refinement temperature range (ΔT) extending from 20 degrees Celsius (° C.) to 800° C.

Methodology Applied
Scientific EffectHeating: Heating

Implementation Method 3

refining the oxide layer by maintaining temperature (T) of the semiconductor structure within a refinement temperature range (ΔT)

Methodology Applied
Scientific EffectDiffusion: Diffusion

Data Source

PatentUS20230223252A1Method, semiconductor structure, and vacuum processing system
Publication Date: 2023.07.13 UNIVERSITY OF TURKU
  • US20230223252A1 patent drawing
  • US20230223252A1 patent drawing

AI summary

This disclosure relates to a method (100) for passivating a semiconductor structure, comprising a semiconductor layer and an oxide layer on the semiconductor layer; a semiconductor structure; and a vacuum processing system. The method (100) comprises providing the semiconductor structure (110) in a vacuum chamber (310) and, while keeping the semiconductor structure in the vacuum chamber (120) throughout a refinement period with a duration of at least 25 s refining the oxide layer (130) by maintaining temperature (131) of the semiconductor structure within a refinement temperature range extending from 20° C., to 800° C., and maintaining total pressure (132) in the vacuum chamber below a maximum total pressure, of 1×10−3 mbar.