Oxide Nanosheet Catalyst Layer for High-Density Support

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Solution Overview

Problem

Conventional catalysts used in water electrolysis cells are expensive and have limited surface area, making it difficult to support them at high density, which hampers the efficiency of water electrolysis.

Innovation Solution

A catalyst layer is developed using a nanosheet made of oxides like Ti, Mn, Co, Mo, Ru, W, and Ta as carriers, with a catalyst such as iridium oxide or ruthenium oxide supported on these carriers, allowing for high-density catalyst support and efficient water electrolysis.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Quantity of substance

If conventional oxide carriers are used, then catalyst stability is maintained, but catalyst support density is low

Engineering Contradiction:
Improvecatalyst support densityVSAvoidoxide carrier surface area
Core Design Contradiction:
Quantity of substanceVSArea of stationary object

Solution Approach 1:

The invention changes the physical form of the oxide carrier from conventional bulk or particle structures to a nanosheet structure. This parameter change in morphology dramatically increases the surface area of the oxide carrier, enabling high-density catalyst support while maintaining the stability benefits of oxide materials.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention transitions from zero-dimensional particles or three-dimensional bulk oxides to two-dimensional nanosheet structures. This dimensional change provides extensive surface area for catalyst support, resolving the contradiction between maintaining oxide stability and achieving high catalyst density.

Inventive Principle:
Principle #17Another dimension (Dimensionality change)

2Quantity of substance

If catalyst amount is reduced, then cost is decreased, but water electrolysis efficiency may be compromised

Engineering Contradiction:
Improvecatalyst amountVSAvoidwater electrolysis efficiency
Core Design Contradiction:
Quantity of substanceVSProductivity

Solution Approach 1:

By changing the carrier morphology to nanosheets with dramatically increased surface area, the invention allows the same catalyst amount to provide much higher active site density. This maintains or improves electrolysis efficiency while reducing the total catalyst quantity required, addressing the cost-efficiency contradiction.

Inventive Principle:
Principle #35Parameter changes

3Productivity

If catalyst activity is increased by supporting on stable oxide, then efficiency is improved, but surface area is insufficient for high density support

Engineering Contradiction:
Improvewater electrolysis efficiencyVSAvoidoxide carrier surface area
Core Design Contradiction:
ProductivityVSArea of stationary object

Solution Approach 1:

The transition to two-dimensional nanosheet structures provides extensive surface area while maintaining the stability of oxide carriers. This enables high-density catalyst support that delivers improved water electrolysis efficiency, resolving the contradiction between efficiency improvement and surface area sufficiency.

Inventive Principle:
Principle #17Another dimension (Dimensionality change)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This configuration increases the surface area of the oxide carrier, enabling high catalyst activity and reducing the amount of catalyst needed, thus enhancing the efficiency of water electrolysis while allowing for a larger volume of electrolysis with the same catalyst amount.

Implementation Method 1

using a layered oxide nanosheet as the carrier increases the surface area of the oxide carrier, allowing the catalyst to be supported on a stable oxide at a high density

Methodology Applied
Scientific EffectSurface area effect:

Implementation Method 2

a catalyst layer which is one layer constituting the water electrolysis cell

Methodology Applied
Scientific EffectElectrolysis: Electrolysis

Data Source

PatentUS20230250543A1Catalyst layer, membrane electrode assembly
Publication Date: 2023.08.10 TOYOTA JIDOSHA KK
  • US20230250543A1 patent drawing
  • US20230250543A1 patent drawing

AI summary

To enhance water electrolysis efficiency by supporting a catalyst on an oxide carrier at a high density. A catalyst layer includes a carrier and a catalyst. The carrier is a nanosheet made of an oxide containing at least one element selected from Ti, Mn, Co, Mo, Ru, W, Nb, and Ta. The catalyst is supported on the carrier.