Oxide Semiconductor Schottky Diode for High Breakdown Voltage

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Solution Overview

Problem

Conventional Schottky diodes face challenges in achieving high current-voltage characteristics and mass productivity due to the use of materials like Si, GaAs, and SiC, which require high-temperature processes and are costly, especially when trying to form wide band gap semiconductors for high voltage applications.

Innovation Solution

A Schottky barrier diode element is developed using a silicon substrate with an oxide semiconductor layer having a band gap of 3.0 eV to 5.6 eV, primarily composed of indium (In) and other metals like Ti, Zn, Ga, and Sn, which offers excellent current-voltage characteristics and high dielectric breakdown fields, while being cost-effective and suitable for mass production.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Speed

If Si-based schottky diode is used for high-speed switching, then switching speed is improved, but band gap is limited to 1.1 eV requiring larger element size for high voltage applications

Engineering Contradiction:
Improveswitching speedVSAvoidwithstand voltage
Core Design Contradiction:
SpeedVSReliability

Solution Approach 1:

The patent uses a layered composite structure combining Si substrate with wide band gap compound semiconductor layers (SiC, SiGe, GaN, AlN) to achieve both high-speed switching performance and high withstand voltage capability. The compound semiconductor layer forms the Schottky barrier interface while the Si substrate provides mechanical support and electrical connection.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The invention applies different material properties to different regions: the compound semiconductor layer provides high breakdown field and wide band gap for voltage handling, while the Si substrate provides high carrier mobility for fast switching. This local differentiation of material functions resolves the contradiction between speed and voltage capability.

Inventive Principle:
Principle #3Local quality

2Reliability

If GaAs is used to achieve higher band gap (1.4 eV) and superior withstand voltage, then voltage capability is improved, but epitaxial growth on Si substrate is difficult causing dislocation

Engineering Contradiction:
Improvewithstand voltageVSAvoidcrystal quality
Core Design Contradiction:
ReliabilityVSManufacturing precision

Solution Approach 1:

The patent introduces SiC, SiGe, or GaN as intermediate buffer layers between the GaAs active layer and the Si substrate. These intermediary layers have lattice constants that gradually transition from Si to GaAs, reducing dislocation density and enabling high-quality GaAs growth on Si substrates.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The semiconductor structure is segmented into multiple functional layers: Si substrate, buffer layers (SiC/SiGe/GaN), and GaAs active layer. This segmentation allows each layer to be optimized independently for its specific function while managing the interface between mismatched materials.

Inventive Principle:
Principle #1Segmentation

3Reliability

If SiC is used to achieve wide band gap (3.3 eV) and high dielectric breakdown field, then voltage capability is improved, but high-temperature production process reduces mass productivity

Engineering Contradiction:
Improvedielectric breakdown fieldVSAvoidmass productivity
Core Design Contradiction:
ReliabilityVSProductivity

Solution Approach 1:

The patent utilizes the phase transition property of AlN from solid to liquid at relatively low temperature (1100-1200°C) to enable low-temperature processing. By controlling the melting and solidification of AlN in situ, the invention achieves wide band gap semiconductor formation without requiring high-temperature epitaxial growth, thereby improving mass productivity.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution provides a Schottky barrier diode with improved current-voltage characteristics and high dielectric breakdown fields, enabling the use of wide band gap semiconductors at a lower cost and with enhanced mass productivity, suitable for various electronic and automotive applications.

Implementation Method 1

a schottky barrier diode element having a silicon (Si) substrate, an oxide semiconductor layer and a schottky electrode layer

Methodology Applied
Scientific EffectSchottky barrier:

Implementation Method 2

a diode having rectification function utilizing an electron barrier formed in the interface of a metal and a semiconductor

Methodology Applied
Scientific EffectElectron barrier formation:

Data Source

PatentUS11769840B2Oxide semiconductor substrate and schottky barrier diode
Publication Date: 2023.09.26 IDEMITSU KOSAN CO LTD
  • US11769840B2 patent drawing
  • US11769840B2 patent drawing

AI summary

A schottky barrier diode element having a silicon (Si) substrate, an oxide semiconductor layer and a schottky electrode layer, wherein the oxide semiconductor layer includes a polycrystalline and/or amorphous oxide semiconductor having a band gap of 3.0 eV or more and 5.6 eV or less.