Oxide Semiconductor ALD Process for Low-Variation Transistors

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Solution Overview

Problem

Existing semiconductor devices face challenges with variations in transistor electrical characteristics, reliability, electrical performance, miniaturization, integration, and power consumption, particularly in the use of oxide semiconductors.

Innovation Solution

A method involving the deposition of metal oxides using an Atomic Layer Deposition (ALD) process, including specific precursors and oxidizing gases, with controlled temperature and gas introduction steps to reduce hydrogen concentration and enhance thickness uniformity, is employed to form semiconductor devices.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Use of energy by moving object

If oxide semiconductors are used in transistors, then power consumption is reduced, but variation in electrical characteristics increases

Engineering Contradiction:
Improvepower consumptionVSAvoidvariation in electrical characteristics
Core Design Contradiction:
Use of energy by moving objectVSReliability

Solution Approach 1:

The patent changes the chemical composition parameters of the oxide semiconductor by introducing nitrogen and controlling oxygen content. This modifies the material properties to reduce carrier concentration and improve electrical characteristic uniformity while maintaining low power consumption characteristics

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates a composite oxide semiconductor material containing nitrogen within the oxide structure. This composite approach combines the low power consumption advantage of oxide semiconductors with improved electrical characteristic uniformity through nitrogen incorporation

Inventive Principle:
Principle #40Composite materials

2Productivity

If transistor size is reduced for miniaturization, then integration density increases, but electrical characteristics become more variable

Engineering Contradiction:
Improveintegration densityVSAvoidelectrical characteristics uniformity
Core Design Contradiction:
ProductivityVSReliability

Solution Approach 1:

The patent modifies the oxide semiconductor composition by adding nitrogen and controlling oxygen content to reduce carrier concentration. This parameter change improves the uniformity of electrical characteristics, enabling better performance in miniaturized transistors with higher integration density

Inventive Principle:
Principle #35Parameter changes

3Ease of manufacture

If conventional deposition methods are used, then manufacturing process is simple, but thickness uniformity and hydrogen control are poor

Engineering Contradiction:
Improveprocess simplicityVSAvoidthickness uniformity
Core Design Contradiction:
Ease of manufactureVSManufacturing precision

Solution Approach 1:

The patent employs Atomic Layer Deposition (ALD) which uses periodic alternation of precursor and oxidizing gas introduction. This periodic action enables precise control of film thickness and composition, achieving superior thickness uniformity compared to conventional continuous deposition methods

Inventive Principle:
Principle #19Periodic action

Solution Approach 2:

The patent changes the deposition parameters by using ALD with controlled temperature (210-300°C) and specific gas sequences. This enables precise control of film properties including thickness uniformity and hydrogen concentration reduction

Inventive Principle:
Principle #35Parameter changes

4Ease of manufacture

If hydrogen is present in insulators, then deposition process is easier, but hydrogen transfers to metal oxide causing electrical characteristic degradation

Engineering Contradiction:
Improvedeposition easeVSAvoidelectrical characteristic stability
Core Design Contradiction:
Ease of manufactureVSReliability

Solution Approach 1:

The patent converts the harmful effect of hydrogen by providing dedicated hydrogen absorption sites in the insulator structure. The insulator is designed to capture and retain hydrogen that would otherwise transfer to the metal oxide, thereby protecting electrical characteristics while simplifying deposition processes

Inventive Principle:
Principle #22Blessing in disguise (Convert harm into benefit)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The method results in semiconductor devices with reduced transistor variation, improved reliability, enhanced electrical characteristics, higher on-state current, and lower power consumption, enabling miniaturization and integration.

Implementation Method 1

The metal oxide is deposited by an ALD method

Methodology Applied
Scientific EffectAtomic Layer Deposition: Chemical Vapour Deposition

Implementation Method 2

performing heat treatment, so that hydrogen in the first insulator, the second insulator, and the oxide is transferred and absorbed into the metal oxide

Methodology Applied
Scientific EffectDiffusion: Diffusion

Data Source

PatentUS12575348B2Method for manufacturing semiconductor device
Publication Date: 2026.03.10 SEMICON ENERGY LAB CO LTD
  • US12575348B2 patent drawing
  • US12575348B2 patent drawing
  • US12575348B2 patent drawing

AI summary

A semiconductor device in which variation in electrical characteristics is small is provided. A first insulator is deposited, a metal oxide is device over the first insulator, a second insulator is device over the metal oxide, an oxide film is device over the second insulator, and heat treatment is performed, whereby hydrogen in the first insulator, the second insulator, and the oxide is transferred and absorbed into the metal oxide. The metal oxide is formed by an ALD method.