Oxide Semiconductor Layer Deoxidation for Low-Resistance 3D Memory

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Solution Overview

Problem

In three-dimensional nonvolatile semiconductor memory devices, the resistance between memory cells increases due to the expansion of impurity diffusion layers during heat treatment, impairing performance and integration.

Innovation Solution

The implementation of low-resistance areas within oxide semiconductor layers by deoxidizing them with interlayer insulating layers, such as silicon-rich oxide silicon or hydrogen-rich insulating layers, which maintains the structure's integrity and reduces resistance, preventing excessive expansion during thermal treatment.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If doping is performed to form impurity diffusion layers to reduce resistance between memory cells, then resistance is reduced and read/write speed is improved, but the impurity diffusion layers expand during heat treatment which impairs device performance and integration

Engineering Contradiction:
Improveresistance between memory cellsVSAvoidimpurity diffusion layer expansion control
Core Design Contradiction:
ReliabilityVSManufacturing precision

Solution Approach 1:

The patent changes the chemical composition parameter of the channel layer by forming a silicon-rich oxide silicon layer instead of a conventional silicon layer. This compositional change allows the layer to serve as both the channel and impurity diffusion layer, eliminating the need for separate doping processes that cause expansion issues.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent uses a composite silicon-rich oxide silicon layer that combines properties of both channel layer and impurity diffusion layer. This composite material approach allows simultaneous achievement of low resistance and controlled dimensions without the harmful expansion effect of conventional doped silicon layers.

Inventive Principle:
Principle #40Composite materials

2Quantity of substance

If three-dimensional vertical-channel stacked structure is adopted to increase integration density, then capacity and degree of integration are improved, but resistance between memory cells increases and read/write speed decreases

Engineering Contradiction:
Improveintegration densityVSAvoidresistance between memory cells
Core Design Contradiction:
Quantity of substanceVSReliability

Solution Approach 1:

The patent changes the material composition parameter by using silicon-rich oxide silicon instead of conventional silicon. This compositional change enables the material to simultaneously provide the three-dimensional vertical-channel structure for high integration and the impurity diffusion capability for low resistance, resolving the contradiction between integration density and resistance.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach enables high-speed read/write operations and suppresses the short-channel effect, achieving high performance and integration in three-dimensional semiconductor memory devices.

Implementation Method 1

a low-resistance area formed in an oxide semiconductor layer by deoxidizing the oxide semiconductor layer with an interlayer insulating layer

Methodology Applied
Scientific EffectOxygen diffusion: Diffusion

Data Source

PatentUS9502431B2Nonvolatile semiconductor memory device and method of manufacturing the same
Publication Date: 2016.11.22 KIOXIA CORP
  • US9502431B2 patent drawing
  • US9502431B2 patent drawing
  • US9502431B2 patent drawing

AI summary

According to one embodiment, a memory device includes a first stacked layer structure stacked in order of a first insulating layer, a first electrode layer, . . . an n-th insulating layer, an n-th electrode layer, and an (n+1)-th insulating layer in a first direction perpendicular to a surface of a semiconductor substrate, where n is a natural number, an oxide semiconductor layer extending through the first to n-th electrode layers in the first direction, a second stacked layer structure provided between the first to n-th electrode layers and the oxide semiconductor layer, and including a charge storage layer which storages charges, and a area provided in the oxide semiconductor layer.