Oxide Semiconductor Device Oxygen Supply Barrier

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Solution Overview

Problem

Transistors using oxide semiconductors face reliability issues due to sensitivity to impurities and oxygen vacancies, leading to unstable electrical characteristics and low reliability.

Innovation Solution

The semiconductor device reduces impurity concentration and oxygen vacancies by supplying excess oxygen to the oxide semiconductor from an oxide insulator, and uses a barrier insulator to prevent hydrogen and water from entering, while also employing dehydration and dehydrogenation treatments to enhance the barrier properties against impurities.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If oxide semiconductor is used as active layer, then device functionality is achieved, but electrical characteristics become unstable due to impurities and oxygen vacancies

Engineering Contradiction:
Improveelectrical characteristics stabilityVSAvoidimpurity sensitivity
Core Design Contradiction:
ReliabilityVSObject-affected harmful factors

Solution Approach 1:

The oxide insulator is pre-formed with excess oxygen content before the oxide semiconductor is introduced. This preliminary preparation of the insulator creates a reservoir of oxygen that will later diffuse to fill vacancies in the semiconductor, preventing instability before it occurs.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The oxide insulator acts as an intermediary medium between the external environment and the oxide semiconductor. It serves as both a barrier to impurities and a source of oxygen, mediating the interaction between the semiconductor and its surroundings to maintain electrical stability.

Inventive Principle:
Principle #24Intermediary (Mediator)

2Productivity

If oxide semiconductor transistor is manufactured, then device integration is achieved, but threshold voltage changes after bias temperature stress test

Engineering Contradiction:
Improvedevice integration capabilityVSAvoidthreshold voltage stability
Core Design Contradiction:
ProductivityVSReliability

Solution Approach 1:

The oxide insulator is prepared in advance with excess oxygen through specific formation conditions (such as using In-Ga-Zn-O target with oxygen-rich composition). This preliminary oxygen enrichment ensures that when the device undergoes bias temperature stress testing, oxygen can diffuse from the insulator to maintain threshold voltage stability.

Inventive Principle:
Principle #10Preliminary action

3Ease of manufacture

If conventional oxide semiconductor structure is used, then manufacturing simplicity is maintained, but impurity concentration remains high

Engineering Contradiction:
Improvemanufacturing simplicityVSAvoidimpurity concentration control
Core Design Contradiction:
Ease of manufactureVSManufacturing precision

Solution Approach 1:

The invention uses a composite structure combining oxide semiconductor with oxide insulator having specific barrier properties. This composite approach allows the insulator to provide impurity blocking and oxygen supply functions while maintaining compatibility with conventional manufacturing processes like sputtering.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The insulator is formed with specific parameters (thickness of 50-200 nm, oxygen-rich composition, specific dielectric constant range) that optimize its ability to block impurities while supplying oxygen. These parameter changes enable precise control of impurity concentration without complicating the overall manufacturing process.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach results in improved reliability, stable electrical characteristics, reduced power consumption, and the ability to miniaturize or highly integrate semiconductor devices with increased producibility.

Implementation Method 1

supplying excess oxygen to the oxide semiconductor from an oxide insulator in the vicinity of the oxide semiconductor

Methodology Applied
Scientific EffectDiffusion: Diffusion

Implementation Method 2

dehydration and dehydrogenation by heat treatment or the like to prevent impurities such as water or hydrogen from entering an oxide semiconductor

Methodology Applied
Scientific EffectHeat treatment: Heat Treatment

Data Source

PatentUS10886412B2Semiconductor device and manufacturing method thereof
Publication Date: 2021.01.05 SEMICON ENERGY LAB CO LTD
  • US10886412B2 patent drawing
  • US10886412B2 patent drawing
  • US10886412B2 patent drawing

AI summary

A highly reliable semiconductor device includes a first insulator, a second insulator, a first conductor, a third insulator, an oxide semiconductor, second and third conductors, a fourth insulator, a fourth conductor overlapping with a region between the second and third conductors, a fifth insulator, and a sixth insulator in this order. The fourth insulator is in contact with top and side surfaces of the oxide semiconductor, and a top surface of the third insulator. The fifth insulator is in contact with the side surface of the oxide semiconductor and the top surface of the third insulator so as to cover the oxide semiconductor, the second to fourth conductors, and the fourth insulator. The first, second, fifth, and sixth insulators have low permeability for hydrogen, water, and oxygen. The first and sixth insulators have a thinner thickness than the second and sixth insulators, respectively.