Oxide Semiconductor Layer Oxygen Ion Implantation

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Solution Overview

Problem

Current semiconductor devices using oxide semiconductors face challenges in achieving favorable electric characteristics, high on-state current, low power consumption, and reliability, particularly in maintaining data retention when power is stopped, due to issues with oxygen vacancies and crystal damage during oxygen ion implantation.

Innovation Solution

A method involving the formation of an oxide semiconductor layer on a substrate, followed by selective etching, oxygen ion implantation at specific angles, and heat treatment to diffuse oxygen, ensuring efficient oxygen supply without damaging the crystal structure, using a c-axis aligned crystalline oxide semiconductor (CAAC-OS) film with a block layer to prevent oxygen release and enhance oxygen diffusion.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If oxygen ion implantation is performed to reduce oxygen vacancies in oxide semiconductor layer, then electrical characteristics are improved, but crystal structure damage occurs

Engineering Contradiction:
Improveelectrical characteristicsVSAvoidcrystal structure
Core Design Contradiction:
ReliabilityVSStrength

Solution Approach 1:

An insulating layer containing oxygen is formed over the oxide semiconductor layer before oxygen ion implantation. This insulating layer serves as a protective barrier that prevents direct high-energy ion impact on the crystal structure while still allowing oxygen diffusion to occur, thereby reducing crystal damage during the oxygen supplementation process

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The insulating layer acts as an intermediary medium between the oxygen ions and the oxide semiconductor layer. It facilitates oxygen diffusion to fill vacancies while absorbing and distributing the impact energy of incoming ions, preventing direct damage to the crystal structure

Inventive Principle:
Principle #24Intermediary (Mediator)

2Reliability

If high concentration of oxygen is supplied to oxide semiconductor layer, then electrical characteristics improve, but excess oxygen causes degradation

Engineering Contradiction:
Improveelectrical characteristicsVSAvoidoxygen degradation
Core Design Contradiction:
ReliabilityVSObject-generated harmful factors

Solution Approach 1:

Oxygen is supplied locally and selectively to regions where vacancies exist, rather than uniformly throughout the entire oxide semiconductor layer. The insulating layer confines oxygen diffusion to specific areas, ensuring adequate oxygen concentration to improve electrical characteristics while preventing excessive oxygen accumulation that would cause degradation

Inventive Principle:
Principle #3Local quality

3Ease of manufacture

If conventional transistor structures are used, then manufacturing is simple, but power consumption is high and speed is limited

Engineering Contradiction:
Improvemanufacturing simplicityVSAvoidpower consumption
Core Design Contradiction:
Ease of manufactureVSUse of energy by moving object

Solution Approach 1:

The invention changes the material parameter by using oxide semiconductor materials with specific properties (wide bandgap, high mobility potential) and controls the oxygen concentration parameter through controlled implantation and diffusion processes. These parameter changes enable the transistor to achieve low power consumption and high-speed operation while maintaining ease of manufacture through established thin-film fabrication techniques

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach results in semiconductor devices with improved electrical characteristics, high on-state current, low power consumption, and enhanced reliability, while maintaining data retention even when power is stopped, by effectively managing oxygen vacancies and crystal integrity.

Implementation Method 1

implanting an oxygen ion in the oxide semiconductor layer

Methodology Applied
Scientific EffectIon implantation: Ion Implantation

Implementation Method 2

performing heat treatment on the oxide semiconductor layer to diffuse oxygen into the oxide semiconductor layer

Methodology Applied
Scientific EffectDiffusion: Diffusion

Data Source

PatentUS10096489B2Method for manufacturing semiconductor device
Publication Date: 2018.10.09 SEMICON ENERGY LAB CO LTD
  • US10096489B2 patent drawing
  • US10096489B2 patent drawing
  • US10096489B2 patent drawing

AI summary

Provided is a method for manufacturing a semiconductor device with favorable electrical characteristics. The following steps are performed in the following order: forming an oxide semiconductor film over a substrate having a substantially planar surface; selectively etching the oxide semiconductor film to form an oxide semiconductor layer; implanting an oxygen ion on a top surface of the oxide semiconductor layer and a side surface of the oxide semiconductor layer in a cross-section perpendicular to the substantially planar surface in a channel width direction of the oxide semiconductor layer from an angle 0°<θ<90°; forming an insulating layer over the oxide semiconductor layer, and performing heat treatment on the oxide semiconductor layer to diffuse oxygen into the oxide semiconductor layer.