Oxide Semiconductor Purification for Low-Leakage Power Transistors

Resolve Bottlenecks,
Find Innovative Solutions
Generate Solutions

Solution Overview

Problem

The challenge is to develop a semiconductor device with high reliability and low power consumption that can handle high power applications, as existing semiconductor materials like silicon have reached theoretical limits, and compound semiconductors like silicon carbide and gallium nitride require high process temperatures, limiting their use on glass substrates and reducing mass productivity.

Innovation Solution

A method involving the use of oxide semiconductors, specifically an In--Ga--Zn--O-based oxide semiconductor film, which undergoes heat treatments in a reduced-pressure atmosphere with inert gases to reduce impurities like hydrogen and water, followed by oxygen addition via ion implantation to achieve high purification, resulting in a transistor with low off-state current and high withstand voltage.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If compound semiconductors like silicon carbide or gallium nitride are used to improve withstand voltage and reduce power loss, then high power application performance is improved, but process temperature becomes too high for glass substrates

Engineering Contradiction:
Improvewithstand voltageVSAvoidprocess temperature
Core Design Contradiction:
ReliabilityVSTemperature

Solution Approach 1:

The invention changes the material parameter from compound semiconductors (silicon carbide, gallium nitride) to oxide semiconductors (In-Ga-Zn-O-based), which have lower processing temperatures while maintaining high withstand voltage characteristics. This material substitution resolves the contradiction between high power performance and glass substrate compatibility.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention uses a composite structure combining oxide semiconductor films with specific metal elements (In, Ga, Zn) to achieve both low processing temperature and high withstand voltage. The composite material approach allows optimization of both thermal and electrical properties simultaneously.

Inventive Principle:
Principle #40Composite materials

2Ease of manufacture

If oxide semiconductor films are formed by sputtering, then film deposition is achieved, but hydrogen and water impurities are incorporated causing time degradation

Engineering Contradiction:
Improvefilm depositionVSAvoidthreshold voltage stability
Core Design Contradiction:
Ease of manufactureVSReliability

Solution Approach 1:

The invention applies preliminary heat treatment to the oxide semiconductor film to remove hydrogen and water impurities before the transistor is fully assembled and before time degradation can occur. This preventive action eliminates the source of threshold voltage drift.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The invention uses oxygen plasma treatment to accelerate oxidation and remove hydrogen impurities from the oxide semiconductor film. The oxygen plasma acts as a strong oxidizing environment that effectively eliminates harmful impurities while maintaining film integrity.

Inventive Principle:
Principle #38Strong oxidants (Accelerated oxidation)

3Reliability

If heat treatment is applied to remove impurities from oxide semiconductor films, then reliability is improved, but process temperature increases

Engineering Contradiction:
Improveimpurity removalVSAvoidheat treatment temperature
Core Design Contradiction:
ReliabilityVSTemperature

Solution Approach 1:

The invention replaces thermal heat treatment with oxygen plasma treatment to remove impurities. This substitution uses chemical/physical plasma processes instead of thermal processes, achieving impurity removal without significant temperature increase that would conflict with glass substrate limitations.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

4Temperature

If amorphous silicon is used as active layer, then low temperature processing is achieved, but mobility is limited compared to polysilicon

Engineering Contradiction:
Improveprocessing temperatureVSAvoidcarrier mobility
Core Design Contradiction:
TemperatureVSSpeed

Solution Approach 1:

The invention uses oxide semiconductors with specific metal compositions (In-Ga-Zn-O) that provide both low processing temperature capability and high carrier mobility. The composite material structure achieves performance characteristics of both amorphous silicon (low temperature) and polysilicon (high mobility).

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The invention changes the material composition parameters by incorporating specific metal elements (In, Ga, Zn) in optimized ratios within the oxide semiconductor structure. This compositional optimization enables simultaneous achievement of low processing temperature and high mobility characteristics.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The approach results in a semiconductor device with significantly reduced off-state current, improved reliability, and high withstand voltage, enabling efficient high-power applications while maintaining low power consumption and allowing for mass production on glass substrates.

Implementation Method 1

heat treatments in a reduced-pressure atmosphere with inert gases to reduce impurities like hydrogen and water

Methodology Applied
Scientific EffectThermal desorption: Desorption

Implementation Method 2

oxygen addition via ion implantation to achieve high purification

Methodology Applied
Scientific EffectIon implantation: Ion Implantation

Data Source

PatentUS11923204B2Manufacturing method of semiconductor device comprising oxide semiconductor
Publication Date: 2024.03.05 SEMICON ENERGY LAB CO LTD
  • US11923204B2 patent drawing
  • US11923204B2 patent drawing
  • US11923204B2 patent drawing

AI summary

A semiconductor device for high power application in which a novel semiconductor material having high mass productivity is provided. An oxide semiconductor film is formed, and then, first heat treatment is performed on the exposed oxide semiconductor film in order to reduce impurities such as moisture or hydrogen in the oxide semiconductor film. Next, in order to further reduce impurities such as moisture or hydrogen in the oxide semiconductor film, oxygen is added to the oxide semiconductor film by an ion implantation method, an ion doping method, or the like, and after that, second heat treatment is performed on the exposed oxide semiconductor film.