Oxide Semiconductor Side Wall Protection Against Oxygen Deficiency

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Solution Overview

Problem

Oxide semiconductor layers in semiconductor devices suffer from oxygen deficiency when exposed to vacuum conditions during processing, leading to increased leakage current due to defects caused by plasma etching, which affects the reliability and performance of the devices.

Innovation Solution

A method for manufacturing semiconductor devices involves performing heat treatments to cover the side walls of the oxide semiconductor layer with an insulating oxide, preventing exposure to vacuum and reducing oxygen deficiency, thereby minimizing defects and leakage current.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Ease of manufacture

If the side surfaces of the oxide semiconductor layer are exposed to vacuum during processing, then the etching process can be performed, but oxygen is extracted from the side surfaces causing defects (oxygen deficiency) and increased leakage current

Engineering Contradiction:
Improveetching processVSAvoidleakage current
Core Design Contradiction:
Ease of manufactureVSReliability

Solution Approach 1:

An insulating oxide layer is formed on the side surfaces of the oxide semiconductor layer before the etching process. This preliminary protective action prevents oxygen extraction during subsequent vacuum exposure and plasma etching, thereby avoiding oxygen deficiency defects while maintaining etching capability

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The insulating oxide layer acts as an intermediary protective barrier between the oxide semiconductor layer and the vacuum/plasma environment. This intermediate layer allows the etching process to proceed while preventing direct harmful interaction between the vacuum environment and the oxide semiconductor, thus preventing oxygen extraction

Inventive Principle:
Principle #24Intermediary (Mediator)

2Shape

If plasma etching is performed on the oxide semiconductor layer, then the desired shape can be achieved, but metal atoms bond with chlorine or fluorine radicals causing oxygen atoms to be activated and desorbed, creating defects

Engineering Contradiction:
Improveside surface shapeVSAvoidoxygen deficiency defects
Core Design Contradiction:
ShapeVSManufacturing precision

Solution Approach 1:

The insulating oxide is deposited on the side surfaces before plasma etching occurs. This preliminary protective layer prevents direct bonding between metal atoms and chlorine/fluorine radicals during etching, thereby preventing oxygen atom activation and subsequent desorption that would create defects

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The insulating oxide layer serves as an intermediary protective barrier during plasma etching. It allows the etching process to shape the oxide semiconductor layer while preventing harmful chemical reactions between plasma radicals and the oxide semiconductor, thus maintaining manufacturing precision

Inventive Principle:
Principle #24Intermediary (Mediator)

3Productivity

If the oxide semiconductor layer is processed in a vacuum environment, then processing can be completed, but the side surfaces are exposed to vacuum causing oxygen extraction and defects

Engineering Contradiction:
Improveprocessing completionVSAvoidoxygen deficiency
Core Design Contradiction:
ProductivityVSReliability

Solution Approach 1:

The insulating oxide is formed on the side surfaces before vacuum processing begins. This preliminary protective measure enables subsequent vacuum-based processing to be completed while preventing oxygen extraction from the oxide semiconductor layer, thereby maintaining reliability

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The insulating oxide layer acts as an intermediary protective barrier between the oxide semiconductor layer and the vacuum environment. This allows vacuum processing to be completed successfully while preventing direct harmful interaction that would cause oxygen deficiency defects

Inventive Principle:
Principle #24Intermediary (Mediator)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The approach ensures sufficient oxygen presence on the oxide semiconductor layer surfaces, significantly reducing defects and leakage current, enhancing the reliability and performance of semiconductor devices.

Implementation Method 1

side walls of the oxide semiconductor layer are covered with an insulating oxide; in second heat treatment, the side surfaces of the oxide semiconductor layer are prevented from being exposed to a vacuum and defects (oxygen deficiency) in the oxide semiconductor layer can be reduced

Methodology Applied
Scientific EffectDiffusion barrier: Diffusion Barrier

Implementation Method 2

after first heat treatment is performed on an oxide semiconductor film, the oxide semiconductor film is processed to form an oxide semiconductor layer

Methodology Applied
Scientific EffectHeat treatment: Heat Treatment

Data Source

PatentUS10593786B2Manufacturing method of the semiconductor device
Publication Date: 2020.03.17 SEMICON ENERGY LAB CO LTD
  • US10593786B2 patent drawing
  • US10593786B2 patent drawing
  • US10593786B2 patent drawing

AI summary

The semiconductor device is manufactured through the following steps: after first heat treatment is performed on an oxide semiconductor film, the oxide semiconductor film is processed to form an oxide semiconductor layer; immediately after that, side walls of the oxide semiconductor layer are covered with an insulating oxide; and in second heat treatment, the side surfaces of the oxide semiconductor layer are prevented from being exposed to a vacuum and defects (oxygen deficiency) in the oxide semiconductor layer are reduced.