Oxide Superconducting Wire with Metal Stabilization

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Solution Overview

Problem

Oxide superconducting wires face issues such as quenching due to defects, reduced mechanical strength, moisture deterioration, and ineffective current bypassing when thinned or divided into fragments, leading to decreased energy efficiency and magnetic field instability.

Innovation Solution

A laminate structure comprising a base material, an intermediate layer with controlled orientation, and an oxide superconducting layer with non-orientation regions, covered by a metal layer that functions as a current bypass and protects against moisture, enhancing mechanical strength and preventing quenching.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Loss of energy

If the oxide superconducting layer is thinned or divided into fragments, then shielding currents and magnetization losses are reduced, but the wire becomes more susceptible to quenching due to defects and reduced mechanical strength

Engineering Contradiction:
Improvemagnetization lossesVSAvoidquench resistance
Core Design Contradiction:
Loss of energyVSReliability

Solution Approach 1:

The oxide superconducting layer is divided into multiple thin filaments (each 1-10 μm thick) arranged in parallel within the laminate. This segmentation reduces shielding currents and magnetization losses while the distributed structure prevents catastrophic quenching, as defects in one filament do not affect others

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The invention creates a composite structure combining the oxide superconducting layer with metal stabilizing layers (Ag, Au, Cu, or alloys) and dielectric layers. This composite laminate provides both the superconducting functionality and the mechanical strength + quench resistance that thin superconducting layers alone would lack

Inventive Principle:
Principle #40Composite materials

2Loss of energy

If the oxide superconducting layer is thinned or divided, then alternating-current losses are reduced, but the mechanical strength of the wire decreases

Engineering Contradiction:
Improvealternating-current lossesVSAvoidmechanical strength
Core Design Contradiction:
Loss of energyVSStrength

Solution Approach 1:

The superconducting layer is segmented into multiple thin filaments that can flex and deform independently under mechanical stress, reducing stress concentration and improving overall wire flexibility and strength despite individual filament thinning

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

Metal stabilizing layers with high mechanical strength (Ag, Au, Cu, or their alloys) are integrated into the laminate structure to provide mechanical support and reinforcement to the thin superconducting filaments, maintaining overall wire strength while allowing thin superconducting sections

Inventive Principle:
Principle #40Composite materials

3Manufacturing precision

If grooves are formed to divide the oxide superconducting layer, then the layer is successfully fragmented, but the substrate may be damaged and wire strength decreases

Engineering Contradiction:
Improvelayer division precisionVSAvoidwire strength
Core Design Contradiction:
Manufacturing precisionVSStrength

Solution Approach 1:

Grooves are formed in the metal stabilizing layer or substrate before depositing the oxide superconducting layer, so that the superconducting material naturally forms separated sections over the grooves without requiring post-deposition mechanical cutting that would damage the substrate

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The metal stabilizing layer serves as an intermediary that facilitates the division process - grooves are formed in this robust metal layer rather than directly in the brittle oxide superconducting layer or substrate, preventing damage to the substrate while achieving precise filament separation

Inventive Principle:
Principle #24Intermediary (Mediator)

4Loss of energy

If the oxide superconducting layer is thinned, then shielding currents are reduced, but the side surface becomes exposed to moisture causing deterioration

Engineering Contradiction:
Improveshielding currentsVSAvoidmoisture deterioration
Core Design Contradiction:
Loss of energyVSObject-affected harmful factors

Solution Approach 1:

A dielectric layer (such as Al2O3, SiO2, or polymer coatings) is deposited as a protective thin film over the oxide superconducting layer and metal stabilizing layers, sealing the side surfaces and preventing moisture ingress while maintaining the thin-section benefits

Inventive Principle:
Principle #30Flexible shells and thin films

Solution Approach 2:

The laminate structure combines multiple materials including moisture-barrier dielectric layers that protect the thin superconducting sections from environmental degradation, allowing the wire to maintain both thin dimensions and environmental stability

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The metal layer effectively limits the impact of defects, maintains mechanical strength, prevents moisture-induced deterioration, and ensures reliable current bypassing, even when the wire is divided into thin filaments, thereby improving energy efficiency and magnetic field stability.

Implementation Method 1

a metal layer which covers at least a front surface and side surfaces of the oxide superconducting layer in the laminate

Methodology Applied
Scientific EffectPhysical barrier protection:

Implementation Method 2

the oxide superconducting layer having a crystal orientation controlled by the intermediate layer

Methodology Applied
Scientific EffectCrystal orientation control:

Implementation Method 3

RE-123-based oxide superconductors (REBa2Cu3O7-x: RE represents rare earth elements including Y) exhibit superconductivity at the temperature of liquid nitrogen

Methodology Applied
Scientific EffectSuperconductivity: Superconductivity

Implementation Method 4

When a magnetic field component, which varies in a direction perpendicular to the surface over time, is applied to an oxide superconducting wire, loop-like shielding currents flow in the surface of an oxide superconducting layer

Methodology Applied
Scientific EffectElectromagnetic induction: Electromagnetic Induction

Data Source

PatentUS10332656B2Oxide superconducting wire
Publication Date: 2019.06.25 FUJIKURA LTD
  • US10332656B2 patent drawing
  • US10332656B2 patent drawing
  • US10332656B2 patent drawing

AI summary

An oxide superconducting wire, includes a laminate including a base material, an intermediate layer, and an oxide superconducting layer, the intermediate layer being laminated on a main surface of the base material, the intermediate layer being constituted of one or more layers having an orientation, the intermediate layer having one or more first non-orientation regions extending in a longitudinal direction of the base material, the oxide superconducting layer being laminated on the intermediate layer, the oxide superconducting layer having a crystal orientation controlled by the intermediate layer, the oxide superconducting layer having second non-orientation regions located on the first non-orientation regions, and a metal layer which covers at least a front surface and side surfaces of the oxide superconducting layer in the laminate.