Oxide Semiconductor TFT Channel Crystallization With Low-Temperature Annealing

Resolve Bottlenecks,
Find Innovative Solutions
Generate Solutions

Solution Overview

Problem

Conventional semiconductor devices using crystalline silicon for TFTs in liquid crystal and electroluminescence displays face challenges such as high manufacturing complexity, increased cost, and substrate distortion due to high-temperature processing, while amorphous silicon-based devices have low mobility and high power consumption, and are prone to substrate damage during film formation.

Innovation Solution

The use of oxide semiconductors like zinc oxide (ZnO) with lamp rapid thermal annealing (LRTA) to promote crystallization in the channel region of TFTs, allowing for the production of semiconductor devices with improved mobility and reduced manufacturing costs, while avoiding substrate distortion and damage.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Speed

If crystalline silicon is used for TFT semiconductor film, then mobility is improved (higher by two digits or more), but manufacturing complexity increases and cost increases due to crystallization steps

Engineering Contradiction:
ImprovemobilityVSAvoidmanufacturing complexity
Core Design Contradiction:
SpeedVSDevice complexity

Solution Approach 1:

The patent changes the material parameter from crystalline silicon to oxide semiconductor (such as In-Ga-Zn-O), which inherently provides high mobility without requiring crystallization steps. This material substitution resolves the contradiction by achieving high-speed operation through different physical mechanisms while simplifying the manufacturing process.

Inventive Principle:
Principle #35Parameter changes

2Speed

If crystalline silicon is used for TFT semiconductor film, then mobility is improved, but manufacturing cost increases due to additional crystallization steps

Engineering Contradiction:
ImprovemobilityVSAvoidmanufacturing cost
Core Design Contradiction:
SpeedVSEase of manufacture

Solution Approach 1:

The patent changes the material parameter from crystalline silicon to oxide semiconductor (such as In-Ga-Zn-O), which inherently provides high mobility without requiring crystallization steps. This material substitution resolves the contradiction by achieving high-speed operation through different physical mechanisms while simplifying the manufacturing process.

Inventive Principle:
Principle #35Parameter changes

3Reliability

If high temperature heating (550°C or higher) is applied for crystallization, then crystalline silicon TFT performance is improved, but substrate distortion occurs and resin substrates cannot be used

Engineering Contradiction:
ImproveTFT performanceVSAvoidsubstrate integrity
Core Design Contradiction:
ReliabilityVSStability of the object's composition

Solution Approach 1:

The patent changes the material parameter from crystalline silicon to oxide semiconductor (such as In-Ga-Zn-O), which can be processed at lower temperatures (below 450°C) while maintaining high mobility. This enables the use of resin substrates and prevents substrate distortion while achieving reliable TFT performance.

Inventive Principle:
Principle #35Parameter changes

4Ease of manufacture

If amorphous silicon is used for TFT semiconductor film, then manufacturing cost is reduced and resin substrates can be used, but mobility is low (0.2 to 1.0 cm2/V·s) and power consumption is high

Engineering Contradiction:
Improvemanufacturing costVSAvoidmobility
Core Design Contradiction:
Ease of manufactureVSSpeed

Solution Approach 1:

The patent changes the material parameter from amorphous silicon to oxide semiconductor (such as In-Ga-Zn-O), which provides high mobility (comparable to or exceeding crystalline silicon) while maintaining compatibility with low-cost manufacturing processes and resin substrates. This resolves the contradiction by achieving high performance through different material physics.

Inventive Principle:
Principle #35Parameter changes

5Ease of manufacture

If plasma CVD method is used to form amorphous silicon film, then film formation is achieved, but substrate damage occurs due to high vacuum heating

Engineering Contradiction:
Improvefilm formation capabilityVSAvoidsubstrate damage
Core Design Contradiction:
Ease of manufactureVSObject-affected harmful factors

Solution Approach 1:

The patent changes the material parameter from amorphous silicon to oxide semiconductor (such as In-Ga-Zn-O), which can be deposited using sputtering methods at lower temperatures and with less substrate damage. The oxide semiconductor films can be formed at temperatures below 450°C, preventing substrate damage while achieving high-quality films.

Inventive Principle:
Principle #35Parameter changes

6Ease of manufacture

If sputtering method is used to form amorphous silicon film, then film formation is achieved, but insulating film forms on surface when exposed to atmospheric air

Engineering Contradiction:
Improvefilm formation capabilityVSAvoidfilm quality
Core Design Contradiction:
Ease of manufactureVSManufacturing precision

Solution Approach 1:

The patent changes the material parameter from amorphous silicon to oxide semiconductor (such as In-Ga-Zn-O). Since oxide semiconductors already contain oxygen in their crystal structure, they do not form additional insulating oxide films when exposed to atmospheric air. This eliminates the quality degradation issue while maintaining the advantages of sputtering deposition.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach enables the production of semiconductor devices with enhanced mobility and cost-effectiveness, while maintaining substrate integrity and reducing power consumption, and allows for the use of low-temperature processing, making it suitable for large-area displays.

Implementation Method 1

by heating a gate electrode that is near the compound semiconductor by lamp rapid thermal annealing (LRTA; also simply called lamp heating), crystallization of the compound semiconductor is selectively promoted

Methodology Applied
Scientific EffectRapid thermal annealing: Annealing

Implementation Method 2

crystallization of the compound semiconductor is selectively promoted

Methodology Applied
Scientific EffectCrystallization: Crystallisation

Implementation Method 3

when a substrate is heated to a high temperature during a heat treatment step, a size of the substrate becomes distorted due to warping and shrinking

Methodology Applied
Scientific EffectThermal expansion: Thermal Expansion

Data Source

PatentUS12183832B2Semiconductor device and manufacturing method thereof
Publication Date: 2024.12.31 SEMICON ENERGY LAB CO LTD
  • US12183832B2 patent drawing
  • US12183832B2 patent drawing
  • US12183832B2 patent drawing

AI summary

An object is to provide a semiconductor device of which a manufacturing process is not complicated and by which cost can be suppressed, by forming a thin film transistor using an oxide semiconductor film typified by zinc oxide, and a manufacturing method thereof. For the semiconductor device, a gate electrode is formed over a substrate; a gate insulating film is formed covering the gate electrode; an oxide semiconductor film is formed over the gate insulating film; and a first conductive film and a second conductive film are formed over the oxide semiconductor film. The oxide semiconductor film has at least a crystallized region in a channel region.