Oxide Semiconductor TFT Conductivity Control via Oxygen Plasma

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Solution Overview

Problem

Oxide semiconductor channel layers in microelectronic devices, such as thin film transistors (TFTs), exhibit increased conductivity after photolithographic patterning, making it difficult to turn off the TFTs effectively, which is a challenge in achieving controlled conductivity and on-to-off ratios.

Innovation Solution

Incorporating an oxygen-containing plasma treatment step following photolithographic patterning of the oxide semiconductor channel layer, which reduces conductivity and allows for better control over the turn-on voltage by annealing the device in air at 175°C and exposing it to oxygen plasma, resulting in a channel conductance of effectively zero at turn-on voltage.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Ease of manufacture

If photolithographic patterning is performed on oxide semiconductor channel layer, then device fabrication is enabled, but channel conductivity increases making TFT difficult to turn off

Engineering Contradiction:
Improvephotolithographic patterning capabilityVSAvoidTFT on-to-off ratio
Core Design Contradiction:
Ease of manufactureVSReliability

Solution Approach 1:

The patent applies preliminary action by performing oxygen plasma treatment immediately after photolithographic patterning to prevent the unwanted conductivity increase. The plasma treatment is applied as a corrective step right after the harmful effect occurs, restoring the channel layer's electrical properties before subsequent processing steps.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The patent converts the harmful effect of photolithographic patterning (increased channel conductivity) into a beneficial process by using oxygen plasma treatment. The plasma exposure, which initially causes conductivity increase, is followed by a controlled plasma treatment that restores and even improves the channel layer quality, turning the harmful side effect into an opportunity for enhanced device performance.

Inventive Principle:
Principle #22Blessing in disguise (Convert harm into benefit)

2Reliability

If oxygen plasma treatment is applied to reduce channel conductivity, then TFT on-to-off ratio improves, but additional process steps are required

Engineering Contradiction:
ImproveTFT on-to-off ratioVSAvoidnumber of process steps
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent merges the oxygen plasma treatment step with the existing photolithographic processing sequence, combining two previously separate processes into an integrated workflow. The plasma treatment is performed using the same plasma equipment and process infrastructure already present in the fabrication line, reducing overall process complexity despite adding a treatment step.

Inventive Principle:
Principle #5Merging (Combining)

Solution Approach 2:

The patent utilizes parameter changes by adjusting plasma treatment conditions (power, gas flow, duration) to optimize the conductivity reduction effect. By carefully controlling these parameters, the process achieves the desired electrical properties improvement while minimizing the impact of adding an extra process step to the fabrication sequence.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The oxygen-containing plasma treatment effectively reduces high channel conductivity, enhancing on-to-off ratios and allowing for precise control of the turn-on voltage, achieving a channel sheet resistance greater than or equal to 10^8 Ohms/square and improving device performance by reducing hysteresis and increasing mobility.

Implementation Method 1

exposing it to oxygen plasma

Methodology Applied
Scientific EffectPlasma treatment: Plasma

Implementation Method 2

oxygen-containing plasma treatment

Methodology Applied
Scientific EffectOxidation: Oxidation

Implementation Method 3

annealing the device in air at 175°C

Methodology Applied
Scientific EffectAnnealing: Annealing

Data Source

PatentUS8058096B2Microelectronic device
Publication Date: 2011.11.15 HEWLETT PACKARD DEVELOPMENT COMPANY LP
  • US8058096B2 patent drawing
  • US8058096B2 patent drawing
  • US8058096B2 patent drawing

AI summary

A thin film transistor is manufactured by a process including forming an oxide semiconductor channel, patterning the oxide semiconductor channel with a photolithographic process, and exposing the patterned oxide semiconductor channel to an oxygen containing plasma.