Oxide Semiconductor TFT Purification for Stable Electric Characteristics

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Solution Overview

Problem

Existing semiconductor devices with oxide semiconductor thin film transistors face instability due to impurities such as moisture, which affect the reliability and electric characteristics of the transistors.

Innovation Solution

A manufacturing method involving heat treatment in an oxygen atmosphere to dehydrate and dehydrogenate the oxide semiconductor layer, followed by slow cooling and the formation of an oxide insulating layer to reduce impurities and improve the transistor's reliability.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If heat treatment is performed in an oxygen atmosphere to remove impurities, then the purity and reliability of the oxide semiconductor layer is improved, but the manufacturing process complexity and time are increased

Engineering Contradiction:
Improvetransistor reliabilityVSAvoidmanufacturing process complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

Heat treatment for dehydration and dehydrogenation is performed on the oxide semiconductor layer before forming the source and drain electrodes. This preliminary purification action removes impurities such as water and hydrogen in advance, ensuring high transistor reliability and stable electrical characteristics before subsequent manufacturing steps are completed.

Inventive Principle:
Principle #10Preliminary action

2Stability of the object's composition

If heat treatment is performed to dehydrate and dehydrogenate the oxide semiconductor layer, then the electric characteristics stability is improved, but the manufacturing time and energy consumption are increased

Engineering Contradiction:
Improveelectric characteristics stabilityVSAvoidmanufacturing time
Core Design Contradiction:
Stability of the object's compositionVSLoss of time

Solution Approach 1:

The oxide semiconductor layer undergoes heat treatment for dehydration and dehydrogenation before electrode formation. This preliminary stabilization ensures that the layer achieves desired electrical characteristics and compositional stability prior to subsequent manufacturing steps, preventing later adjustments and reducing total manufacturing time.

Inventive Principle:
Principle #10Preliminary action

3Manufacturing precision

If slow cooling is performed after heat treatment, then the crystal structure and purity are improved, but the manufacturing cycle time is extended

Engineering Contradiction:
Improvecrystal structure precisionVSAvoidcooling time
Core Design Contradiction:
Manufacturing precisionVSLoss of time

Solution Approach 1:

The oxide semiconductor layer undergoes controlled phase transition during slow cooling after heat treatment. This controlled cooling process allows proper crystallization and structural stabilization, improving manufacturing precision and electrical characteristics while managing the necessary time investment for quality outcomes.

Inventive Principle:
Principle #36Phase transitions

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The method enhances the stability and reliability of thin film transistors by reducing moisture and hydrogen impurities, leading to improved electric characteristics and increased durability.

Implementation Method 1

heat treatment which reduces impurities such as moisture to improve the purity of the oxide semiconductor layer (heat treatment for dehydration or dehydrogenation) is performed in an oxygen atmosphere

Methodology Applied
Scientific EffectHeat treatment: Heat Treatment

Implementation Method 2

heat treatment for dehydration or dehydrogenation is performed in an oxygen atmosphere

Methodology Applied
Scientific EffectDehydration:

Implementation Method 3

heat treatment for dehydration or dehydrogenation is performed in an oxygen atmosphere

Methodology Applied
Scientific EffectDehydrogenation:

Implementation Method 4

the heat treatment can oxidize the oxide semiconductor layer

Methodology Applied
Scientific EffectOxidation: Oxidation

Implementation Method 5

After the heat treatment, it is preferable that the oxide semiconductor layer be slowly cooled in the/an oxygen atmosphere or an inert gas atmosphere of nitrogen or a rare gas

Methodology Applied
Scientific EffectSlow cooling:

Data Source

PatentUS11855194B2Method for manufacturing semiconductor device
Publication Date: 2023.12.26 SEMICON ENERGY LAB CO LTD
  • US11855194B2 patent drawing
  • US11855194B2 patent drawing
  • US11855194B2 patent drawing

AI summary

A highly reliable semiconductor device which includes a thin film transistor having stable electric characteristics, and a manufacturing method thereof. In the manufacturing method of the semiconductor device which includes a thin film transistor where a semiconductor layer including a channel formation region is an oxide semiconductor layer, heat treatment which reduces impurities such as moisture to improve the purity of the oxide semiconductor layer and oxidize the oxide semiconductor layer (heat treatment for dehydration or dehydrogenation) is performed. Not only impurities such as moisture in the oxide semiconductor layer but also those existing in a gate insulating layer are reduced, and impurities such as moisture existing in interfaces between the oxide semiconductor layer and films provided over and under and in contact with the oxide semiconductor layer are reduced.