Oxide Semiconductor Transistor Structure for Hydrogen Diffusion Control

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Solution Overview

Problem

Current semiconductor devices face challenges in achieving high reliability, excellent electrical characteristics, high on-state current, miniaturization, and low power consumption, particularly due to issues with hydrogen diffusion and impurity concentration in oxide semiconductor transistors.

Innovation Solution

A semiconductor device is designed with a transistor surrounded by an insulator that acts as a hydrogen barrier, using a conductor with nitrogen and metal that extracts hydrogen, maintaining a hydrogen concentration between 2.0×10^19 and 1.0×10^21 atoms/cm^3, and bonding hydrogen to nitrogen atoms, with heat treatment above 350°C and below 700°C to absorb hydrogen in the oxide.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If a conventional transistor structure is used without hydrogen barrier insulator, then manufacturing process is simpler, but hydrogen diffusion into oxide semiconductor causes poor reliability and electrical characteristics

Engineering Contradiction:
Improvetransistor reliabilityVSAvoiddevice structure complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

An insulator with hydrogen barrier property is introduced as an intermediary layer between the oxide semiconductor and the surrounding environment. This barrier insulator prevents hydrogen diffusion into the oxide semiconductor, thereby improving transistor reliability and electrical characteristics without fundamentally changing the transistor structure

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

Hydrogen is extracted from the oxide semiconductor by a conductor containing nitrogen and metal with hydrogen extraction capability. The conductor forms a region with controlled hydrogen concentration where hydrogen atoms bond to nitrogen atoms, removing harmful hydrogen from the channel formation region

Inventive Principle:
Principle #2Taking out (Extraction)

2Power

If hydrogen concentration in oxide semiconductor is increased, then on-state current may improve, but electrical characteristics deteriorate due to hydrogen-induced defects

Engineering Contradiction:
Improveon-state currentVSAvoidelectrical characteristics
Core Design Contradiction:
PowerVSReliability

Solution Approach 1:

The hydrogen concentration in the oxide semiconductor is precisely controlled within the range of 2.0×10^19 to 1.0×10^21 atoms/cm³. This parameter optimization balances the beneficial effects of hydrogen (improved on-state current) while avoiding harmful effects (electrical characteristic deterioration), achieving both high power and reliability

Inventive Principle:
Principle #35Parameter changes

3Productivity

If transistor is miniaturized to increase integration, then device density improves, but hydrogen diffusion effects become more significant causing performance degradation

Engineering Contradiction:
Improveintegration densityVSAvoidtransistor performance
Core Design Contradiction:
ProductivityVSReliability

Solution Approach 1:

The hydrogen barrier insulator acts as a protective intermediary that becomes increasingly important as transistor size decreases. In miniaturized devices, the surface-to-volume ratio increases, making diffusion effects more significant; the barrier insulator effectively blocks hydrogen diffusion paths that would otherwise dominate in small devices

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The conductor is designed with specific local properties (nitrogen content and metal composition) to create a hydrogen extraction region with controlled hydrogen concentration. This local quality enhancement ensures that even in miniaturized transistors, hydrogen is effectively managed in critical regions

Inventive Principle:
Principle #3Local quality

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution provides a semiconductor device with enhanced reliability, electrical characteristics, high on-state current, miniaturization capabilities, and low power consumption by effectively managing hydrogen concentration and impurity levels, thereby stabilizing transistor performance.

Implementation Method 1

an insulator placed so as to surround the transistor, the insulator has a barrier property against hydrogen

Methodology Applied
Scientific EffectDiffusion barrier: Diffusion Barrier

Implementation Method 2

the conductor has a physical property of extracting hydrogen; the conductor includes a region having a hydrogen concentration higher than or equal to 2.0×10^19 atoms/cm³ and lower than or equal to 1.0×10^21 atoms/cm³

Methodology Applied
Scientific EffectHydrogen absorption: Absorption (physical)

Implementation Method 3

at least part of hydrogen atoms included in the region is bonded to a nitrogen atom; the conductor includes nitrogen and a metal

Methodology Applied
Scientific EffectChemical bonding: Chemical Bonding

Implementation Method 4

heat treatment above 350°C and below 700°C to absorb hydrogen in the oxide

Methodology Applied
Scientific EffectThermal diffusion: Diffusion

Data Source

PatentUS11935964B2Semiconductor device and method for manufacturing semiconductor device
Publication Date: 2024.03.19 SEMICON ENERGY LAB CO LTD
  • US11935964B2 patent drawing
  • US11935964B2 patent drawing
  • US11935964B2 patent drawing

AI summary

A semiconductor device having high reliability is provided. The semiconductor device includes a transistor and an insulator placed so as to surround the transistor; the insulator has a barrier property against hydrogen; the transistor includes an oxide and a conductor; the conductor includes nitrogen and a metal; the conductor has a physical property of extracting hydrogen; the conductor includes a region having a hydrogen concentration higher than or equal to 2.0×1019 atoms/cm3 and lower than or equal to 1.0×1021 atoms/cm3; and at least part of hydrogen atoms included in the region is bonded to a nitrogen atom.