Oxime Carbamate Liquid Soluble Concentrate Stability

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Solution Overview

Problem

The stability of oxime carbamates, such as oxamyl, in liquid formulations is low, leading to reduced effectiveness and the need for higher application rates, as they decompose in soil and water, which affects their efficacy in treating pest infestations.

Innovation Solution

A liquid soluble concentrate formulation comprising an oxime carbamate and a solvent system of alcohol, carbonate ester, and water, which enhances the stability and solubility of the active ingredient, allowing for higher concentrations and reduced volume requirements for application.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Ease of operation

If oxime carbamates are used in liquid formulations, then they can be applied conveniently and dissolved in water, but their stability is low and they decompose in soil and water

Engineering Contradiction:
Improveconvenience of applicationVSAvoidstability of oxime carbamate
Core Design Contradiction:
Ease of operationVSStability of the object's composition

Solution Approach 1:

The patent introduces a stabilizing agent as an intermediary substance that mediates between the oxime carbamate active ingredient and the aqueous environment. This stabilizing agent prevents decomposition of the oxime carbamate in water and soil while maintaining the liquid formulation's applicability. The stabilizer acts as a protective intermediary that extends the half-life of the active ingredient without compromising ease of application.

Inventive Principle:
Principle #24Intermediary (Mediator)

2Reliability

If higher application rates are used to compensate for decomposition, then pest control effectiveness is maintained, but the volume of formulation required increases

Engineering Contradiction:
Improvepest control effectivenessVSAvoidvolume of formulation
Core Design Contradiction:
ReliabilityVSQuantity of substance

Solution Approach 1:

The patent changes the chemical parameters of the formulation by introducing stabilizing agents and adjusting pH levels. These parameter changes increase the stability and half-life of the oxime carbamate, allowing lower application rates to achieve the same pest control effectiveness. By modifying the formulation's chemical environment, the active ingredient remains effective longer, reducing the quantity needed per application.

Inventive Principle:
Principle #35Parameter changes

3Ease of manufacture

If conventional solvent systems are used, then the formulation can be prepared simply, but the solubility and stability of oxime carbamates are limited

Engineering Contradiction:
Improvesimplicity of formulation preparationVSAvoidsolubility of oxime carbamate
Core Design Contradiction:
Ease of manufactureVSQuantity of substance

Solution Approach 1:

The patent creates a composite liquid formulation system combining multiple components: oxime carbamate active ingredient, stabilizing agents, pH adjusters, and conventional solvents. This composite approach enhances solubility and stability beyond what conventional single-component systems achieve, while maintaining relative simplicity in preparation. The synergistic interaction between components improves overall formulation performance.

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The formulation maintains high stability and effectiveness, enabling efficient treatment of pest infestations with reduced application rates and increased solubility of oxime carbamates, thereby improving pest control efficacy.

Implementation Method 1

a liquid carrier, the liquid carrier comprising a solvent system comprising an alcohol, a carbonate ester and water

Methodology Applied
Scientific EffectSolubility enhancement: Solvation

Implementation Method 2

The stability of oxime carbamates, such as oxamyl, in liquid formulations is low, leading to reduced effectiveness and the need for higher application rates, as they decompose in soil and water

Methodology Applied
Scientific EffectChemical stability:

Data Source

PatentUS11523612B2Pesticidal composition comprising oxime carbamate and use thereof
Publication Date: 2022.12.13 JIANGSU ROTAM CHEM CO LTD
  • US11523612B2 patent drawing
  • US11523612B2 patent drawing

AI summary

A liquid soluble concentrate (SL) composition is provided, the composition comprising: i) an oxime carbamate; and ii) a liquid carrier, the liquid carrier comprising a solvent system comprising an alcohol, a carbonate ester and water. A method of treating pests using the composition is also provided.