Oxy-combustion Boiler Transition Control via Flue Gas Recycle

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Solution Overview

Problem

Implementing oxy-combustion on a commercial scale is hindered by challenges in adequately oxygenating the flue gas and developing a methodology for starting up and transitioning to oxy-combustion in utility coal boilers, particularly in controlling carbon dioxide emissions and minimizing nitrogen oxide emissions.

Innovation Solution

A boiler structure and methodology that allows for gradual transition between air and oxygen firing modes by controlling flue gas recycle flow, oxygen supply, and fresh air intake to maintain proper combustion conditions, with careful measurement and regulation of gas flow and oxygen levels to achieve full oxygen combustion mode, enabling efficient carbon dioxide processing and storage.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Quantity of substance

If air is replaced with oxygen in combustion, then carbon dioxide concentration in flue gas increases, but system complexity increases due to need for oxygen supply and flue gas recycling systems

Engineering Contradiction:
Improvecarbon dioxide concentrationVSAvoidoxygen supply and flue gas recycling system
Core Design Contradiction:
Quantity of substanceVSDevice complexity

Solution Approach 1:

The combustion system is divided into separate oxygen supply and flue gas recycling subsystems, each independently controlled. This allows the complex oxy-combustion process to be managed through modular components rather than a monolithic system, making the high carbon dioxide concentration achievable while keeping system complexity manageable through structured segmentation.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The system dynamically adjusts oxygen concentration and flue gas recycling ratios as operational parameters to optimize carbon dioxide concentration in the flue gas. By continuously varying these parameters based on load conditions, the system achieves high CO2 concentration without requiring maximum complexity at all operating points.

Inventive Principle:
Principle #35Parameter changes

2Quantity of substance

If flue gas recycling is increased to achieve oxy-combustion, then carbon dioxide concentration improves, but transition control difficulty increases

Engineering Contradiction:
Improvecarbon dioxide concentrationVSAvoidtransition control
Core Design Contradiction:
Quantity of substanceVSDifficulty of detecting and measuring

Solution Approach 1:

The transition control system incorporates feedback mechanisms that monitor oxygen levels, flue gas flow rates, and combustion parameters in real-time. This feedback allows the control system to automatically adjust flue gas recycling ratios and oxygen supply during transition phases, reducing the difficulty of detecting and measuring the optimal transition point while maintaining high carbon dioxide concentration.

Inventive Principle:
Principle #23Feedback

Solution Approach 2:

The system employs dynamic control strategies that adapt flue gas recycling ratios and oxygen injection rates based on real-time combustion conditions. This dynamic approach smooths the transition between air-firing and oxy-combustion modes, making the transition control more manageable while achieving the desired carbon dioxide concentration in the flue gas.

Inventive Principle:
Principle #15Dynamics

3Productivity

If oxygen injection is increased to maintain combustion, then combustion efficiency improves, but energy consumption increases

Engineering Contradiction:
Improvecombustion efficiencyVSAvoidenergy for oxygen supply and gas recycling
Core Design Contradiction:
ProductivityVSUse of energy by moving object

Solution Approach 1:

The system optimizes oxygen injection rates and flue gas recycling ratios as variable parameters based on combustion load and efficiency requirements. By dynamically adjusting these parameters rather than maintaining constant high oxygen levels, the system achieves high combustion efficiency while minimizing the energy required for oxygen supply and gas recycling operations.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The system applies oxygen injection and flue gas recycling at partial levels sufficient to achieve the required combustion efficiency rather than using excessive oxygen throughout. This partial action approach maintains productivity while reducing the energy consumption associated with oxygen production and gas recycling systems.

Inventive Principle:
Principle #16Partial or excessive action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

Enables the production of a flue gas primarily composed of carbon dioxide and water, reducing nitrogen oxide emissions and eliminating the need for additional chemical scrubbing, while maintaining system pressure and equilibrium during transitions, facilitating carbon dioxide storage or industrial uses.

Implementation Method 1

combustion of fuel in a boiler furnace with an oxygenated gas instead of air to produce a flue gas having a high concentration of carbon dioxide

Methodology Applied
Scientific EffectCombustion: Combustion

Implementation Method 2

recycle a portion of the flue gas from the stack back to the burner inlet where it mixes with fresh air and oxygen

Methodology Applied
Scientific EffectGas mixing and recirculation: Convection

Data Source

PatentUS8453585B2Oxy-combustion coal fired boiler and method of transitioning between air and oxygen firing
Publication Date: 2013.06.04 THE BABCOCK & WILCOX CO
  • US8453585B2 patent drawing
  • US8453585B2 patent drawing
  • US8453585B2 patent drawing

AI summary

A new and unique boiler and method of transition between air and Oxy-combustion in a coal fired combustion process wherein near pure oxygen may be introduced to the boiler furnace in several locations including directly into the flame through the burner and/or directly into the furnace as nearly pure oxygen, and/or into the recycle flue gas streams to the burners, including both primary and secondary streams.