Mixed Oxy-Sulfide Solid Electrolytes for Stable High-Conductivity Batteries

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Solution Overview

Problem

All-oxide solid electrolytes have low ionic conductivity and are chemically unstable, while high-conductivity all-sulfide electrolytes are expensive and chemically unstable, posing challenges for battery design and manufacturing.

Innovation Solution

Development of mixed oxy-sulfide solid electrolytes with nitrogen-doped mixed network former glasses, which combine high conductivity, chemical stability, and low-cost production, enabling the creation of stable and efficient solid-state batteries.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Stability of the object's composition

If all-oxide solid electrolytes are used, then chemical stability is improved, but ionic conductivity deteriorates

Engineering Contradiction:
Improvechemical stabilityVSAvoidionic conductivity
Core Design Contradiction:
Stability of the object's compositionVSReliability

Solution Approach 1:

The patent applies composite materials by creating oxy-sulfide solid electrolytes that combine oxide and sulfide components. This composite approach allows the material to achieve both chemical stability from the oxide portion and high ionic conductivity from the sulfide portion, resolving the contradiction between these two properties that plague pure all-oxide or pure all-sulfide systems.

Inventive Principle:
Principle #40Composite materials

2Reliability

If all-sulfide solid electrolytes are used, then ionic conductivity is improved, but chemical stability deteriorates

Engineering Contradiction:
Improveionic conductivityVSAvoidchemical stability
Core Design Contradiction:
ReliabilityVSStability of the object's composition

Solution Approach 1:

The patent creates a composite oxy-sulfide system where sulfide components provide the high ionic conductivity while oxide components provide chemical stability. This composite structure allows both properties to coexist, overcoming the limitation of pure all-sulfide electrolytes that are highly conducting but chemically unstable and expensive to manufacture.

Inventive Principle:
Principle #40Composite materials

3Reliability

If high-conductivity all-sulfide electrolytes are used, then manufacturing cost deteriorates, but ionic conductivity is improved

Engineering Contradiction:
Improveionic conductivityVSAvoidmanufacturing cost
Core Design Contradiction:
ReliabilityVSEase of manufacture

Solution Approach 1:

The patent employs cheaper oxide components in the composite oxy-sulfide electrolyte to replace expensive all-sulfide materials while maintaining acceptable performance. The oxide-sulfide composite approach allows use of more economical materials without sacrificing the high ionic conductivity needed for practical battery applications.

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The mixed oxy-sulfide electrolytes achieve high ionic conductivity, chemical stability, and mechanical strength, facilitating the production of low-cost, high-capacity solid-state batteries with improved energy and power densities.

Implementation Method 1

nitrogen-doped mixed network former glasses

Methodology Applied
Scientific EffectNitrogen doping: Dopants

Implementation Method 2

mixed network former glasses

Methodology Applied
Scientific EffectGlass formation: Vitrification

Implementation Method 3

ion conductive mixed oxy-sulfide-nitride solid electrolytes

Methodology Applied
Scientific EffectIonic conductivity: Fast Ion Conductor

Data Source

PatentUS10804563B2Oxy-thio-nitride mixed network former solid electrolytes
Publication Date: 2020.10.13 IOWA STATE UNIV RES FOUND INC
  • US10804563B2 patent drawing

AI summary

An ion conductivity mixed chalcogenide (e.g. oxy-sulfide), mixed network former solid electrolyte is provided for use in solid state batteries.