Oxygen Detector Saccharide Blend Heat Resistance

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Solution Overview

Problem

Conventional oxygen detectors lose their ability to detect oxygen effectively at high temperatures due to browning of reducing saccharides, leading to unclear color changes and slow response times, which is exacerbated by the use of monosaccharides with high reactivity.

Innovation Solution

Incorporating a reducing trisaccharide as a second component alongside a monosaccharide and disaccharide in the oxygen indicator aqueous solution, which stabilizes the reducing saccharides and prevents browning, allowing the oxygen detector to maintain its functionality at room temperature and high temperatures.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If monosaccharides are used as reducing saccharides to maintain redox dye in reduced state, then oxygen detection ability is improved, but browning occurs at high temperature causing unclear color changes

Engineering Contradiction:
Improveoxygen detection abilityVSAvoidbrowning of reducing saccharide
Core Design Contradiction:
ReliabilityVSObject-affected harmful factors

Solution Approach 1:

The patent combines monosaccharides and disaccharides as reducing saccharides in the oxygen detector. This combination allows the system to benefit from the high reducing power of monosaccharides while the disaccharides provide thermal stability and prevent browning at high temperatures, thus resolving the contradiction between detection ability and heat resistance.

Inventive Principle:
Principle #5Merging (Combining)

Solution Approach 2:

The patent uses a composite system of multiple saccharide types (monosaccharides and disaccharides) working together. This composite approach leverages the complementary properties of different saccharides: monosaccharides provide strong reducing capability while disaccharides provide thermal stability, creating a synergistic effect that overcomes the limitations of single-component systems.

Inventive Principle:
Principle #40Composite materials

2Reliability

If monosaccharides are used as reducing saccharides due to high reducing power, then redox dye is effectively reduced, but reactivity increases causing rapid browning at high temperature

Engineering Contradiction:
Improveredox dye reduction efficiencyVSAvoidbrowning reaction speed
Core Design Contradiction:
ReliabilityVSSpeed

Solution Approach 1:

The patent merges monosaccharides and disaccharides in the reducing saccharide component. The monosaccharides provide the necessary reducing power for effective redox dye reduction, while the disaccharides act as thermal stabilizers that slow down browning reactions at high temperatures, thus balancing reduction efficiency with reaction speed control.

Inventive Principle:
Principle #5Merging (Combining)

Solution Approach 2:

The patent changes the compositional parameter of the reducing saccharide system from single-component (monosaccharide) to multi-component (monosaccharide + disaccharide). This parameter change modifies the overall reactivity profile of the system, providing both high reducing power and reduced thermal reactivity through the combined effects of different saccharide types.

Inventive Principle:
Principle #35Parameter changes

3Reliability

If reducing saccharides are stored at low temperature to prevent browning, then detection ability is maintained, but storage cost increases

Engineering Contradiction:
Improvedetection abilityVSAvoidstorage temperature
Core Design Contradiction:
ReliabilityVSTemperature

Solution Approach 1:

The patent combines monosaccharides and disaccharides to create a reducing saccharide system that is stable at room temperature. This combination eliminates the need for low-temperature storage while maintaining detection ability, as the disaccharide component prevents browning even at elevated temperatures, thus resolving the contradiction between maintaining reliability and storage temperature requirements.

Inventive Principle:
Principle #5Merging (Combining)

4Reliability

If reducing saccharide reacts with basic substance to form chain structure, then redox dye is reduced, but decomposition occurs at high temperature reducing detection ability

Engineering Contradiction:
Improveredox dye reductionVSAvoidreducing saccharide structure stability
Core Design Contradiction:
ReliabilityVSStability of the object's composition

Solution Approach 1:

The patent merges monosaccharides and disaccharides in the reducing saccharide component. The monosaccharides form the necessary chain structures with basic substances to reduce redox dye, while the disaccharides provide structural stability that prevents decomposition at high temperatures, thus resolving the contradiction between redox dye reduction and structural stability.

Inventive Principle:
Principle #5Merging (Combining)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The oxygen detector exhibits high heat resistance, maintaining clear and quick color changes in response to oxygen levels, reducing storage costs and ensuring effective oxygen detection across varying temperatures.

Implementation Method 1

The reducing saccharide is ring-opened in the oxygen indicator aqueous solution adjusted to be basic by the basic substance and forms a chain structure having a reducing group (an aldehyde group or a ketone group), which reduces the redox dye

Methodology Applied
Scientific EffectReduction: Reduction

Implementation Method 2

When the redox dye maintained in the reduced state is oxidized by oxygen in the atmosphere, the redox dye changes the color

Methodology Applied
Scientific EffectOxidation: Oxidation

Implementation Method 3

The reducing saccharide is ring-opened in the oxygen indicator aqueous solution adjusted to be basic by the basic substance

Methodology Applied
Scientific EffectpH adjustment:

Data Source

PatentUS8415167B2Oxygen detector and method for manufacturing oxygen detector
Publication Date: 2013.04.09 POWDERTECH CO LTD

AI summary

It is an object of the present invention to provide: an oxygen indicator aqueous solution for an oxygen detector that has high heat resistance, can be stored at room temperature, and can maintain an excellent ability to detect oxygen, regardless of the atmospheric temperature; an oxygen detector; and a method for manufacturing an oxygen detector.In order to achieve this object, there is provided an oxygen indicator aqueous solution for an oxygen detector that is an aqueous solution comprising reducing saccharides, a basic substance, and a redox dye reduced by the reducing saccharides, the aqueous solution comprising, as the reducing saccharides, a monosaccharide as a first component and a reducing trisaccharide as a second component. In addition, there is provided a manufacturing method preferred for the manufacturing of the oxygen detector.