Oxygen-Doped Silver Mirror for Low Contact Resistance in LED Chips

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Solution Overview

Problem

Optoelectronic semiconductor chips, such as light emitting diodes, face challenges in achieving low contact resistance and maintaining high reflectivity for efficient radiation emission, particularly in the blue spectral range, due to the use of materials like platinum or nickel which reduce reflectivity despite lowering contact resistance.

Innovation Solution

Incorporating a silver mirror with a controlled amount of oxygen, typically between 10^-5 and 10% by weight, to reduce contact resistance without significantly affecting reflectivity, and using a silver mirror composed of silver and oxygen with minimal impurities to enhance energy-efficient radiation emission.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If materials like platinum or nickel are used to reduce contact resistance, then contact resistance decreases, but reflectivity decreases

Engineering Contradiction:
Improvecontact resistanceVSAvoidreflectivity
Core Design Contradiction:
ReliabilityVSUse of energy by moving object

Solution Approach 1:

The patent changes the chemical composition parameter of the silver mirror by introducing oxygen at controlled concentrations (10^-5 to 10% by weight). This parameter change allows the silver mirror to simultaneously achieve low contact resistance with the semiconductor layer and maintain high reflectivity for blue light, resolving the contradiction between electrical contact quality and optical performance

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates a composite material system where oxygen is incorporated into the silver mirror structure. This composite silver-oxygen material exhibits both low contact resistance properties and high reflectivity properties, combining the beneficial characteristics that were previously mutually exclusive when using pure metals like platinum or nickel

Inventive Principle:
Principle #40Composite materials

2Use of energy by moving object

If a silver mirror is used to maintain high reflectivity, then reflectivity increases, but contact resistance increases

Engineering Contradiction:
ImprovereflectivityVSAvoidcontact resistance
Core Design Contradiction:
Use of energy by moving objectVSReliability

Solution Approach 1:

By adjusting the oxygen concentration parameter in the silver mirror to specific ranges (particularly 10^-4 to 10^-2% by weight), the patent optimizes both electrical and optical properties. This parameter optimization allows pure silver to maintain its high reflectivity while the introduced oxygen reduces contact resistance, reversing the traditional trade-off

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The silver mirror with oxygen content achieves low contact resistance and maintains high reflectivity, leading to efficient radiation emission, particularly in the blue spectral range, thereby improving the energy efficiency of the semiconductor chip.

Implementation Method 1

The silver mirror is arranged at the semiconductor layer sequence and designed to reflect the radiation generated in the active layer, in particular in a direction toward a radiation exit area of the semiconductor chip

Methodology Applied
Scientific EffectReflection: Reflection

Implementation Method 2

In order to reduce the contact resistance it is possible to fit an intermediate layer between a mirror and the semiconductor layer sequence... a comparatively small amount of oxygen in the silver mirror

Methodology Applied
Scientific EffectElectrical Resistance reduction through oxygen doping: Electrical Resistance

Data Source

PatentUS8816373B2Optoelectronic semiconductor chip and method for producing an optoelectronic semiconductor chip
Publication Date: 2014.08.26 OSRAM OLED
  • US8816373B2 patent drawing
  • US8816373B2 patent drawing
  • US8816373B2 patent drawing

AI summary

In at least one embodiment, the optoelectronic semiconductor chip comprises a semiconductor layer sequence for generating an electromagnetic radiation, and also a silver mirror. The silver mirror is arranged at the semiconductor layer sequence. Oxygen is admixed with the silver of the silver mirror. A proportion by weight of the oxygen in the silver mirror is preferably at least 10−5 and furthermore preferably at most 10%.