Oxygen Scavenger Materials for Polymer Stabilization and Recycling

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Solution Overview

Problem

Current recycling methods face challenges in processing mixed materials due to compatibility issues caused by additives and pigments, leading to significant costs and environmental pollution, with recyclable materials often being rejected due to embedded plastics, colors, and other contaminants, and there is a need for effective methods to extend the shelf-life of packaged contents and recycle plastics efficiently.

Innovation Solution

The use of oxygen scavenger materials and radical scavengers to stabilize polymers, extend the shelf-life of packaged goods, and improve recycling efficiency by removing oxygen from packaging systems and converting it into stable structures that do not disrupt the recycling process, while also producing value-added products from recycled materials.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If traditional recycling methods are used to process mixed materials, then recycling operations can be performed, but compatibility issues caused by additives and pigments lead to significant costs and environmental pollution

Engineering Contradiction:
Improverecycling efficiencyVSAvoidenvironmental pollution
Core Design Contradiction:
ProductivityVSObject-generated harmful factors

Solution Approach 1:

The patent converts harmful oxygen that causes polymer degradation during recycling into a beneficial byproduct stream. By introducing oxygen scavenger materials that react with oxygen to form stable products, the system transforms oxygen from a harmful contaminant into a controlled reaction component, enabling recycling of materials that would otherwise be rejected due to oxidation damage.

Inventive Principle:
Principle #22Blessing in disguise (Convert harm into benefit)

Solution Approach 2:

The patent introduces oxygen scavenger materials as intermediary substances that mediate between oxygen and polymers. These scavengers act as buffers that consume oxygen through controlled reactions, preventing direct oxidative damage to polymers while allowing the recycling process to proceed. The scavengers are selected to be compatible with recycling streams and can be removed or transformed into acceptable byproducts.

Inventive Principle:
Principle #24Intermediary (Mediator)

2Reliability

If additives and pigments are present in recyclable materials, then material functionality is maintained, but compatibility issues arise导致 materials being rejected at recycling facilities

Engineering Contradiction:
Improvematerial functionalityVSAvoidrecycling compatibility
Core Design Contradiction:
ReliabilityVSAdaptability or versatility

Solution Approach 1:

The patent applies local quality by positioning oxygen scavenger materials at specific locations within the packaging system - either as coatings on container surfaces, as layers within multi-layer packaging structures, or as embedded additives within the polymer matrix itself. This localized application ensures that scavengers are positioned where oxygen contact with polymers is most problematic, providing targeted protection while minimizing interference with recycling processes.

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The patent changes chemical parameters by selecting oxygen scavengers with specific reactivity characteristics, molecular weights, and functional groups that optimize both protection efficiency and recyclability. By adjusting parameters such as scavenger concentration, reaction kinetics, and chemical stability, the system achieves adequate polymer protection while ensuring that scavenger residues do not interfere with recycling compatibility requirements.

Inventive Principle:
Principle #35Parameter changes

3Ease of operation

If oxygen is present in packaging systems, then normal atmospheric conditions are maintained, but polymer degradation occurs reducing shelf-life

Engineering Contradiction:
Improvepackaging simplicityVSAvoidshelf-life
Core Design Contradiction:
Ease of operationVSDuration of action of moving object

Solution Approach 1:

The patent implements preliminary action by incorporating oxygen scavenger materials into the packaging system before product placement and sealing. The scavengers are pre-positioned to immediately begin consuming oxygen upon package closure, creating a protective atmosphere before oxidative degradation can significantly affect the product. This proactive approach extends shelf-life without requiring complex active atmosphere control systems during storage.

Inventive Principle:
Principle #10Preliminary action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach effectively extends the shelf-life of packaged contents, reduces plastic degradation, and enhances recycling efficiency by stabilizing polymers and producing value-added materials, thereby addressing the challenges of material compatibility and environmental pollution.

Implementation Method 1

oxygen scavenger materials to stabilize polymers, OS capable of extending shelf-lives of packaged contents... removing oxygen from packaging systems and converting it into stable structures

Methodology Applied
Scientific EffectOxygen scavenging: Absorption (physical)

Implementation Method 2

radical scavengers capable of stabilizing polymers... reduce plastics degradations thereby extending their useful lives

Methodology Applied
Scientific EffectRadical scavenging: Oxidation

Data Source

PatentUS20220025119A1Waste mitigation methods and materials
Publication Date: 2022.01.27 LI SHENSHEN
  • US20220025119A1 patent drawing
  • US20220025119A1 patent drawing
  • US20220025119A1 patent drawing

AI summary

A compound, comprising a segment having the formula (AA) or (BB):wherein C31 and C32 are carbons (C),wherein R32 and R33 are both hydrogens or collectively forms a carbonyl with C31,wherein R34 and R35 are both hydrogens or collectively forms a carbonyl with C32,wherein X is oxygen (O) or nitrogen attached to an organic residue,wherein R31 is a hydrogen, a hydroxymethyl, a halogen-substituted methyl, or an unsubstituted methylene —CH2— group covalently and directly bonded to X,wherein dashed lines (---) represent optional covalent bonds to satisfy valence.