Solid Electrolyte Oxygen Sensor Leak Detection and Control

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Solution Overview

Problem

Conventional solid electrolyte oxygen sensors face challenges with leakage and operation in low oxygen partial pressure environments, leading to potential oscillatory states and sensor polarization, due to manufacturability issues and aggressive measurement conditions.

Innovation Solution

A diagnostic leak check function is implemented, using a steady state current to empty the internal reference chamber, with dynamic adjustment of pumping current based on oxygen partial pressures and voltage measurements to prevent over-pumping and leakage, and a method to scale down pumping current according to calibration gas partial pressures to avoid over-pumping at low pressures.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Quantity of substance

If pumping current is applied to empty the internal reference chamber, then oxygen partial pressure in the chamber is reduced, but the sensor may enter oscillatory states or become polarized in low oxygen environments

Engineering Contradiction:
Improveoxygen partial pressure in reference chamberVSAvoidsensor stability
Core Design Contradiction:
Quantity of substanceVSReliability

Solution Approach 1:

The control circuit continuously monitors the sensor voltage output and uses this feedback to dynamically adjust the pumping current magnitude. When the sensor approaches the null point or exhibits oscillatory behavior, the feedback mechanism reduces or stops the pumping current, preventing over-pumping and polarization while maintaining stable operation in low oxygen environments

Inventive Principle:
Principle #23Feedback

Solution Approach 2:

The pumping current is applied dynamically in pulsed mode rather than continuously. The control circuit adjusts the current magnitude and duration based on real-time sensor conditions, allowing the system to adapt to changing oxygen partial pressures and avoid entering oscillatory states or becoming polarized

Inventive Principle:
Principle #15Dynamics

2Quantity of substance

If pumping current is applied to transfer oxygen into the reference chamber, then oxygen partial pressure is increased, but the sensor may become polarized or exhibit oscillatory behavior

Engineering Contradiction:
Improveoxygen partial pressure in reference chamberVSAvoidsensor stability
Core Design Contradiction:
Quantity of substanceVSReliability

Solution Approach 1:

The control circuit uses feedback from the sensor voltage to dynamically adjust the pumping current. When the reference chamber approaches the null point or shows signs of oscillation, the feedback mechanism automatically reduces or stops the pumping current, preventing polarization and maintaining sensor stability

Inventive Principle:
Principle #23Feedback

Solution Approach 2:

The pumping current is applied in periodic pulsed mode rather than continuously. The control circuit implements measurement intervals during which no pumping current is applied, allowing the sensor to stabilize and preventing continuous pumping that could lead to polarization or oscillatory behavior

Inventive Principle:
Principle #19Periodic action

3Reliability

If steady state current is applied to empty the reference chamber for leak detection, then gross leaks can be detected, but fine leaks may not be detected without additional measurement time

Engineering Contradiction:
Improveleak detection capabilityVSAvoidmeasurement time
Core Design Contradiction:
ReliabilityVSLoss of time

Solution Approach 1:

The leak detection process is segmented into two distinct phases: a rapid gross leak detection phase using steady state current, and a more precise fine leak detection phase using pulsed current with voltage monitoring. This segmentation allows the system to quickly identify obvious leaks while having the capability to detect subtler leakage issues without excessive measurement time

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The system performs preliminary gross leak detection using steady state current before proceeding to more time-consuming fine leak detection. This preliminary action filters out obvious leakage issues quickly, allowing the system to allocate measurement time more efficiently to cases that require more detailed investigation

Inventive Principle:
Principle #10Preliminary action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution effectively detects gross and fine physical leaks, maintains balance in low oxygen environments, and prevents sensor polarization, ensuring accurate oxygen partial pressure measurement by dynamically controlling pumping current and pulse duration.

Implementation Method 1

oxygen ions can be made to flow though the temperature activated solid electrolyte in response to the application of a pumping current to the porous platinum electrodes

Methodology Applied
Scientific EffectIonic conduction: Conduction (electrical)

Implementation Method 2

The relationship of the voltage output of the sensor to an imbalance in the two oxygen partial pressures is defined by the Nernst equation

Methodology Applied
Scientific EffectNernst effect: Nernst Effect

Data Source

PatentUS7338592B2Diagnostic and control methods for internally calibrated oxygen sensor
Publication Date: 2008.03.04 BAKER HUGHES CO
  • US7338592B2 patent drawing
  • US7338592B2 patent drawing
  • US7338592B2 patent drawing

AI summary

A set of methods controls the pumping action of and provides leak checking of a solid electrolyte oxygen sensor having internal and external electrodes. A first method performs a leak check on the sensor by forcing the sensor internal reference chamber to an evacuated state while seeking a minimum pumping current able to maintain this state. Further pumping control methods apply current pulses to the sensor electrodes to achieve a balanced state between an external oxygen partial pressure and an internal reference oxygen partial pressure. Reduction expressions modify the pulse parameters as a function of the sensor voltage output. A further expression modifies the pulse magnitude as a function of the internal reference chamber oxygen partial pressure. A further expression modifies the initial value of the pulse magnitude as a function of the oxygen partial pressure in a calibration gas during a calibration process.