Galvanic Oxygen Sensor Pressure Equalization

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Solution Overview

Problem

Galvanic fuel cell oxygen sensors, such as the Teledyne UFO-130-2, face issues with membrane displacement and rupture due to pressure differences, leading to inaccurate readings and short lifespan, requiring frequent recalibration and being susceptible to 'oxygen shock'.

Innovation Solution

The method involves applying an equal vacuum to both sides of the membrane using a pressure equalization port tube and sealing with Tygon tubing and RTV11 sealant to maintain equal pressures, reducing membrane displacement and enhancing sensor stability.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Speed

If a thin or porous membrane is used to improve oxygen transfer rate, then response time is improved, but membrane strength decreases leading to displacement and rupture

Engineering Contradiction:
Improveresponse timeVSAvoidmembrane strength
Core Design Contradiction:
SpeedVSStrength

Solution Approach 1:

The patent uses a thin PTFE membrane (0.005 to 0.020 inches thick) that is flexible yet sufficiently strong when properly supported. The membrane is stretched tautly across the cathode mesh and secured at the edges, creating a stable configuration that maintains both rapid oxygen transfer and structural integrity during operation.

Inventive Principle:
Principle #30Flexible shells and thin films

2Productivity

If vacuum is applied to draw gas sample through the sensor, then gas flow is improved, but pressure difference causes membrane displacement and rupture

Engineering Contradiction:
Improvegas flowVSAvoidmembrane stability
Core Design Contradiction:
ProductivityVSReliability

Solution Approach 1:

The patent applies vacuum to both the sample gas chamber and the electrolyte chamber simultaneously, creating equal pressure conditions on both sides of the membrane. This eliminates pressure differential that would cause membrane displacement or rupture, while still allowing gas flow through the sensor via the cathode mesh structure.

Inventive Principle:
Principle #12Equipotentiality

3Quantity of substance

If membrane is made porous and thin for rapid oxygen transfer, then oxygen transfer rate is improved, but membrane becomes susceptible to displacement

Engineering Contradiction:
Improveoxygen transfer rateVSAvoidmembrane position stability
Core Design Contradiction:
Quantity of substanceVSStability of the object's composition

Solution Approach 1:

The thin PTFE membrane is stretched tautly across the cathode mesh support and secured at the edges to a flat surface, creating a stable configuration that prevents displacement while maintaining high oxygen transfer rate through its porous structure.

Inventive Principle:
Principle #30Flexible shells and thin films

Solution Approach 2:

By equalizing pressure on both sides of the membrane through simultaneous vacuum application, the patent eliminates pressure-induced membrane displacement, maintaining stable membrane position while preserving rapid oxygen transfer through the porous structure.

Inventive Principle:
Principle #12Equipotentiality

4Measurement precision

If frequent recalibration is performed to maintain accuracy, then measurement precision is maintained, but operational time is reduced

Engineering Contradiction:
Improvereading accuracyVSAvoidoperational time
Core Design Contradiction:
Measurement precisionVSLoss of time

Solution Approach 1:

By eliminating membrane displacement through pressure equalization, the patent ensures consistent oxygen transfer conditions and stable baseline readings, reducing drift and the frequency of recalibration needed to maintain measurement precision.

Inventive Principle:
Principle #12Equipotentiality

Solution Approach 2:

The stable, displacement-free membrane configuration ensures consistent oxygen transfer characteristics over time, maintaining measurement accuracy and reducing the operational interruptions required for recalibration.

Inventive Principle:
Principle #30Flexible shells and thin films

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach extends the sensor's life, improves response time, and maintains accuracy by preventing membrane rupture and displacement, thus reducing false readings and the need for frequent recalibration.

Implementation Method 1

measure oxygen content of a gas or fluid by diffusing oxygen through a semipermeable membrane into an electrolyte layer

Methodology Applied
Scientific EffectDiffusion: Diffusion

Implementation Method 2

applying an equal vacuum to both sides of the membrane using a pressure equalization port tube

Methodology Applied
Scientific EffectPressure equalization: Pascal's Law

Implementation Method 3

The oxygen in the sample contacts the gold cathode and is chemically reduced to hydroxyl ions

Methodology Applied
Scientific EffectElectrochemical reduction: Redox Reactions

Implementation Method 4

The hydroxyl ions then flow toward the silver anode, where an oxidation reaction occurs with the silver

Methodology Applied
Scientific EffectElectrochemical oxidation: Redox Reactions

Data Source

PatentUS8110081B2Oxygen sensor improvement method
Publication Date: 2012.02.07 MEDICAL GRAPHICS CORP A CORP OF MN
  • US8110081B2 patent drawing
  • US8110081B2 patent drawing
  • US8110081B2 patent drawing

AI summary

A method for improving the performance of a galvanic fuel cell type oxygen sensor comprises providing a pressure equalization port leading to the interior of an inner core housing that contains the membrane, the electrolyte and the anode and cathode electrodes and hermetically sealing the sensor housing except for its sample inlet port and its sample outlet port. By connecting the same vacuum source to both the pressure equalization port and the sample outlet port, the device's membrane is less subject to movement or rupture as gas samples are drawn in via the sample inlet port. A technique for ensuring a hermetic seal is also described.