Oxynitride Phosphor Pillar Particles Dispersion Fluidity

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Solution Overview

Problem

Current semiconductor light emitting devices face challenges in process properties, particularly in the dispersion and fluidity of phosphor particles, which affect their integration and performance in light emitting devices.

Innovation Solution

Development of an oxynitride-based phosphor with a β-type Si3N4 crystal structure and a compositional formula of Si6−xAlxOxN8−x:Euy, featuring primary particles with pillar shapes that are bonded to form secondary particles with improved fluidity and uniform dispersion, allowing for enhanced processability and light emission characteristics.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Ease of operation

If conventional phosphor particles are used, then light emission function is achieved, but fluidity and dispersion properties are poor

Engineering Contradiction:
ImprovefluidityVSAvoiddispersion uniformity
Core Design Contradiction:
Ease of operationVSReliability

Solution Approach 1:

The phosphor is divided into primary particles with pillar shape and secondary particles formed by bonding multiple primary particles. This segmentation allows the primary particles to maintain good fluidity while the secondary particles ensure uniform dispersion when incorporated into light emitting devices.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The invention creates a composite particle structure where multiple primary particles are bonded together to form secondary particles. This composite structure combines the fluidity advantages of small pillar-shaped particles with the dispersion benefits of larger aggregated structures.

Inventive Principle:
Principle #40Composite materials

2Manufacturing precision

If phosphor processing is performed, then light emitting device performance is improved, but processing time increases

Engineering Contradiction:
Improvedevice performanceVSAvoidprocessing time
Core Design Contradiction:
Manufacturing precisionVSLoss of time

Solution Approach 1:

The phosphor particles are pre-formed with optimal pillar shape and secondary particle structure before incorporation into the light emitting device. This preliminary structuring ensures that no additional processing time is required during device manufacturing, as the particles are already optimized for both fluidity and dispersion.

Inventive Principle:
Principle #10Preliminary action

3Reliability

If phosphor particles are aggregated, then dispersion is improved, but fluidity decreases

Engineering Contradiction:
Improvedispersion uniformityVSAvoidfluidity
Core Design Contradiction:
ReliabilityVSEase of operation

Solution Approach 1:

The aggregation is performed at the secondary particle level rather than creating large random aggregates. By bonding a controlled number of pillar-shaped primary particles into secondary particles, the structure maintains fluidity while achieving uniform dispersion characteristics.

Inventive Principle:
Principle #1Segmentation

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The oxynitride-based phosphor exhibits increased fluidity and uniform dispersion, reducing processing time and improving the performance of light emitting devices by emitting light in the desired wavelength range, specifically green light, and enhancing the overall efficiency of wavelength conversion.

Implementation Method 1

the oxynitride-based phosphor... converting a wavelength of at least a portion of the excitation light into a wavelength of green light

Methodology Applied
Scientific EffectPhotoluminescence: Photoluminescence

Data Source

PatentUS9559271B2Oxynitride-based phosphor and white light emitting device including the same
Publication Date: 2017.01.31 SAMSUNG ELECTRONICS CO LTD
  • US9559271B2 patent drawing
  • US9559271B2 patent drawing
  • US9559271B2 patent drawing

AI summary

There is provided an oxynitride-based phosphor comprising a β-type Si3N4 crystal structure and represented by a compositional formula of Si6−xAlxOxN8−x:Euy (0<x≦0.3, 0.001≦y≦0.03), the oxynitride-based phosphor having a form of a secondary particle comprising a plurality of primary particles bonded to each other, the plurality of primary particles having pillar shapes.