Ozone Generator Feedback Control for NOx Exhaust Analysis

Resolve Bottlenecks,
Find Innovative Solutions
Generate Solutions

Solution Overview

Problem

Conventional gas analyzers face challenges in reliably measuring nitrogen oxides in exhaust gases due to incomplete conversion of nitrogen monoxide to nitrogen dioxide and excessive ozone production, leading to unwanted nitrogen oxide compounds and incomplete thermal decomposition.

Innovation Solution

A gas analyzer with a regulating device that controls ozone generation based on measured ozone concentration to maintain a setpoint value, using ultraviolet light sources for ozone production from residual oxygen in the exhaust gas, and employing LED arrays with specific wavelengths for precise measurement of nitrogen dioxide and ozone concentrations.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If ozone is generated with excess to maximize nitrogen monoxide conversion, then conversion efficiency improves, but unwanted nitrogen oxide compounds form and thermal decomposition becomes incomplete

Engineering Contradiction:
Improveconversion efficiencyVSAvoidunwanted nitrogen oxide compounds
Core Design Contradiction:
ReliabilityVSObject-generated harmful factors

Solution Approach 1:

The patent implements a feedback control system where the actual ozone concentration is continuously measured and compared to a target concentration. The ozone generator is regulated based on this feedback to maintain the optimal ozone level for complete nitrogen monoxide conversion without generating excess ozone that would form unwanted compounds like dinitrogen pentoxide.

Inventive Principle:
Principle #23Feedback

Solution Approach 2:

The patent changes the ozone concentration parameter from excessive to precisely controlled levels. By regulating the ozone generator to maintain a specific target concentration rather than using excess ozone, the system achieves complete conversion of nitrogen monoxide to nitrogen dioxide while preventing the formation of unwanted higher nitrogen oxide compounds.

Inventive Principle:
Principle #35Parameter changes

2Adaptability or versatility

If multiple light-emitting diodes with different wavelengths are used for simultaneous measurement, then measurement capability improves, but device complexity increases

Engineering Contradiction:
Improvemeasurement capabilityVSAvoiddevice complexity
Core Design Contradiction:
Adaptability or versatilityVSDevice complexity

Solution Approach 1:

The patent employs multiple light-emitting diodes with different wavelengths (350-500 nm for nitrogen dioxide, 250-265 nm for ozone) that share common optical components including the measuring chamber, detector, and evaluation device. This multi-functional approach enables simultaneous measurement of different gases without requiring separate complete measurement systems, thus improving versatility while controlling complexity.

Inventive Principle:
Principle #6Universality (Multi-functionality)

Solution Approach 2:

The patent merges the measurement paths for nitrogen dioxide and ozone detection by using a single measuring chamber, detector, and evaluation system. Both light-emitting diodes illuminate the same measuring chamber and their signals are processed by the same detector and evaluation device, combining multiple measurement functions into one integrated system.

Inventive Principle:
Principle #5Merging (Combining)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

Ensures almost complete conversion of nitrogen monoxide to nitrogen dioxide, reducing excess ozone production and enabling linear measurement of nitrogen oxides with high accuracy and minimal interference, thus providing reliable continuous monitoring with reduced equipment costs.

Implementation Method 1

ozone is generated from oxygen

Methodology Applied
Scientific EffectPhotodissociation: Photodissociation

Implementation Method 2

exhaust gas is treated with the ozone generated to convert nitrogen monoxide contained in the exhaust gas into nitrogen dioxide

Methodology Applied
Scientific EffectOxidation: Oxidation

Implementation Method 3

a first light-emitting diode that emits with a central wavelength of between 350 nm and 500 nm, a second light-emitting diode that emits with a central wavelength of between 250 nm and 265 nm

Methodology Applied
Scientific EffectLight-emitting diode effect: Light Emitting Diode

Implementation Method 4

the nitrogen dioxide concentration in the treated exhaust gas is measured photometrically using a first light-emitting diode

Methodology Applied
Scientific EffectAbsorption spectroscopy: Absorption Spectroscopy

Data Source

PatentUS11226322B2Optical gas analyzer and method for measuring nitrogen oxides in an exhaust gas
Publication Date: 2022.01.18 SIEMENS AG
  • US11226322B2 patent drawing
  • US11226322B2 patent drawing
  • US11226322B2 patent drawing

AI summary

Gas analyzer and method for measuring nitrogen oxides in an exhaust gas, wherein to measure the nitrogen oxides, ozone is generated from oxygen, the exhaust gas is treated with the ozone generated to convert nitrogen monoxide within the exhaust gas into nitrogen dioxide, the nitrogen dioxide concentration in the treated exhaust gas is measured photometrically using a first light-emitting diode which emits with a central wavelength between 350 nm and 500 nm and output as the nitrogen oxide concentration in the exhaust gas, and the ozone concentration in the treated exhaust gas is measured photometrically using a second light-emitting diode which emits with a central wavelength between 250 nm and 265 nm, where generation of the ozone using the measured ozone concentration as an actual value is regulated to a prespecified setpoint value to enable reliable continuous measurement of nitrogen oxides in exhaust gases with a low outlay on equipment.