In Situ Ozone Substrate Treatment for Imprint Lithography Adhesion

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Solution Overview

Problem

In nano-fabrication processes, particularly in imprint lithography, weak adhesion between the substrate and the patterned layer can lead to defects and yield issues due to the separation of the substrate from the patterned layer, necessitating improved adhesion methods.

Innovation Solution

An in situ ozone processing method is employed to enhance adhesion by cleaning and conditioning the substrate surface, followed by the deposition of an adhesion layer using a process chamber that evacuates gases, heats the chamber, and introduces ozone to remove organic contaminants, and then applies adhesion materials, which are reacted onto the substrate to form a strong bond.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional imprint lithography is used without surface treatment, then the process is simple and fast, but adhesion between substrate and patterned layer is weak leading to defects

Engineering Contradiction:
Improveadhesion strengthVSAvoidprocess complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent applies preliminary surface treatment (ozone exposure or plasma treatment) to the substrate before applying the patterned layer. This preliminary action modifies the substrate surface to enhance adhesion properties, preventing separation defects during the imprint lithography process.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The patent changes the surface parameters of the substrate through chemical treatment (ozone or plasma exposure). This modifies surface energy, roughness, or chemical composition to improve adhesion between the substrate and patterned layer without affecting the bulk material properties.

Inventive Principle:
Principle #35Parameter changes

2Reliability

If adhesion layer is deposited through additional processing steps, then adhesion force increases, but manufacturing time and process complexity increase

Engineering Contradiction:
Improveadhesion forceVSAvoidmanufacturing throughput
Core Design Contradiction:
ReliabilityVSProductivity

Solution Approach 1:

The patent combines the surface treatment step with the existing imprint lithography process flow. By integrating ozone exposure or plasma treatment into the manufacturing sequence, the adhesion enhancement is achieved without requiring separate, additional processing equipment or stages.

Inventive Principle:
Principle #5Merging (Combining)

Solution Approach 2:

The substrate surface treats itself through exposure to ozone or plasma in the existing process chamber environment. The substrate undergoes self-modification of its surface properties through chemical reactions with the ozone or plasma, eliminating the need for external adhesion promoters or complex multi-step coating processes.

Inventive Principle:
Principle #25Self-service

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The in situ ozone processing significantly increases the adhesion force between the substrate and the patterned layer, reducing defects and improving yield by ensuring a robust bond during the imprinting process.

Implementation Method 1

introduces ozone to remove organic contaminants

Methodology Applied
Scientific EffectOxidation: Oxidation

Implementation Method 2

a process chamber that evacuates gases

Methodology Applied
Scientific EffectVacuum: Vacuum

Implementation Method 3

heats the chamber

Methodology Applied
Scientific EffectHeating: Heating

Data Source

PatentUS8361546B2Facilitating adhesion between substrate and patterned layer
Publication Date: 2013.01.29 MOLECULAR IMPRINTS INC
  • US8361546B2 patent drawing
  • US8361546B2 patent drawing
  • US8361546B2 patent drawing

AI summary

Systems and methods for adhering a substrate to a patterned layer are described. Included are in situ cleaning and conditioning of the substrate, and the application of an adhesion layer between the substrate and the patterned layer, as well as forming an intermediate layer between adhesion materials and the substrate.