Cold-Rolled Packaging Steel with Nitrogen-Driven Isotropy

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Solution Overview

Problem

Existing cold-rolled flat steel products for packaging face challenges in achieving high strength while maintaining formability and isotropy, particularly due to anisotropy issues caused by production processes, which affect their performance in deep drawing and ironing processes.

Innovation Solution

The introduction of nitrogen into cold-rolled flat steel products during annealing in the presence of a nitrogen donor, leading to interstitial storage and solid solution solidification, which enhances both strength and isotropy, is used to create a steel product with improved yield strength and elongation at break, minimizing anisotropy and slab cracking risks.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Loss of substance

If the thickness of cold-rolled packaging steel is reduced to improve resource efficiency and cost reduction, then material stiffness decreases, but strength must be increased to meet cold formability requirements

Engineering Contradiction:
Improvesteel thickness reductionVSAvoidyield strength
Core Design Contradiction:
Loss of substanceVSStrength

Solution Approach 1:

The patent applies parameter changes by precisely controlling chemical composition parameters (carbon content 0.02-0.1%, nitrogen content 0.01-0.05%, silicon content 0.03-0.17%, manganese content 0.17-0.5%) and processing parameters (cold rolling reduction 50-90%, annealing temperature 500-700°C) to achieve the desired balance between strength and formability in thin steel sheets

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates a composite microstructure consisting of multiple phases (ferrite, pearlite, and retained austenite) through controlled rolling and annealing processes, where each phase contributes different properties: ferrite provides ductility, pearlite provides strength, and retained austenite enhances formability through TRIP effect

Inventive Principle:
Principle #40Composite materials

2Strength

If cold working is increased to increase strength, then longitudinal and transverse differences (anisotropy) increase, but ductility decreases disproportionately

Engineering Contradiction:
Improveyield strengthVSAvoidductility and anisotropy
Core Design Contradiction:
StrengthVSEase of operation

Solution Approach 1:

The patent applies preliminary action by performing controlled cold rolling with specific reduction ratios (50-90%) followed by annealing treatment before final forming operations. This preliminary deformation and recrystallization process creates a fine-grained microstructure that pre-establishes both strength and improved anisotropy characteristics, preparing the material for subsequent forming operations

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The patent utilizes phase transitions during the annealing process where the cold-worked microstructure transforms through recrystallization, and controlled cooling produces a multiphase structure (ferrite, pearlite, retained austenite) that simultaneously provides strength and ductility while reducing anisotropy

Inventive Principle:
Principle #36Phase transitions

3Strength

If carbon content is increased to increase strength, then anisotropy in the form of linear pattern increases during processing, but surface quality deteriorates and slab cracking risk increases

Engineering Contradiction:
Improvetensile strengthVSAvoidsurface quality and slab cracking
Core Design Contradiction:
StrengthVSObject-affected harmful factors

Solution Approach 1:

The patent applies parameter changes by strictly limiting carbon content to 0.02-0.1% (much lower than conventional steels) while compensating for strength through controlled nitrogen (0.01-0.05%) and silicon (0.03-0.17%) additions, along with optimized thermomechanical processing parameters to achieve high strength without the harmful effects of high carbon

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent uses nitrogen and silicon as intermediary elements that provide solid solution strengthening without the harmful effects of high carbon. These intermediaries (nitrogen atoms and silicon atoms) dissolve in the ferrite lattice and provide strength through lattice distortion, replacing the need for high carbon content that would otherwise cause anisotropy and surface defects

Inventive Principle:
Principle #24Intermediary (Mediator)

4Strength

If alloying elements (Mn, Si, P) are added to increase strength through solid solution strengthening, then strength increases, but surface quality is impaired

Engineering Contradiction:
Improvetensile strengthVSAvoidsurface quality
Core Design Contradiction:
StrengthVSObject-affected harmful factors

Solution Approach 1:

The patent applies parameter changes by optimizing the content ranges of alloying elements: manganese (0.17-0.5%), silicon (0.03-0.17%), and phosphorus (<0.03%) to achieve the necessary strength while minimizing surface quality deterioration. These controlled parameter changes balance strength enhancement with surface integrity for packaging applications

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach results in a flat steel product with high 0.5% yield strength and good elongation at break, ensuring homogeneous mechanical properties across the sheet plane, suitable for various forming processes with reduced material waste and improved isotropy, thus addressing the contradictory objectives of strength and formability.

Implementation Method 1

The introduction of nitrogen into cold-rolled flat steel products during annealing in the presence of a nitrogen donor, leading to interstitial storage and solid solution solidification

Methodology Applied
Scientific EffectDiffusion: Diffusion

Implementation Method 2

The introduction of nitrogen into cold-rolled flat steel products during annealing in the presence of a nitrogen donor

Methodology Applied
Scientific EffectAnnealing: Annealing

Data Source

PatentEP3875611B1Cold-rolled steel sheet product for packages
Publication Date: 2025.01.22 THYSSENKRUPP RASSELSTEIN
  • EP3875611B1 patent drawingFigure 1
  • EP3875611B1 patent drawingFigure 2a
  • EP3875611B1 patent drawingFigure 2b

AI summary

The invention relates to a cold-rolled steel flat product for packaging with a thickness of less than 0.6 mm, which has been cold-rolled from a steel along one rolling direction (0°) and has excellent isotropy with respect to its mechanical properties.