Reactive PAE Creping Adhesive Cross-Linking Control

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Solution Overview

Problem

The existing creping adhesive technologies, particularly thermosetting polyamide-epichlorohydrin polymers, face challenges in controlling adhesion and rewetability, leading to issues such as adhesive build-up and reduced sheet quality due to limited control over cross-linking, which affects the creping process and tissue product quality.

Innovation Solution

A creping adhesive composition based on a reactive, lightly crosslinked polyamidoamine-epihalohydrin polymer, optionally combined with a reactive modifier, is used to control adhesion properties by varying the crosslinking density, allowing for optimized adhesion and release from the Yankee dryer surface under different moisture conditions.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If thermosetting polyamide-epichlorohydrin polymers are used as creping adhesive, then adhesion control is improved, but adhesive build-up and streaking occur due to limited control over cross-linking

Engineering Contradiction:
Improveadhesion controlVSAvoidadhesive build-up
Core Design Contradiction:
ReliabilityVSObject-generated harmful factors

Solution Approach 1:

The patent changes the cross-linking parameter by using a reactive modifier that controls the degree of cross-linking in the thermosetting adhesive. This allows the adhesive to maintain reliable adhesion while preventing excessive build-up and streaking by optimizing the cross-linking density to an appropriate level.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates a composite adhesive system by combining the thermosetting polyamide-epichlorohydrin polymer with a reactive modifier. This composite approach enables the adhesive to achieve both strong adhesion and controlled release properties, preventing the harmful build-up and streaking effects.

Inventive Principle:
Principle #40Composite materials

2Strength

If cross-linking density is increased to improve adhesion, then adhesion strength is improved, but rewetability control is reduced

Engineering Contradiction:
Improveadhesion strengthVSAvoidrewetability control
Core Design Contradiction:
StrengthVSAdaptability or versatility

Solution Approach 1:

The reactive modifier enables independent control of cross-linking density and rewetability. By adjusting the amount and type of reactive modifier, the adhesive can achieve high adhesion strength through controlled cross-linking while maintaining appropriate rewetability for different moisture conditions.

Inventive Principle:
Principle #35Parameter changes

3Manufacturing precision

If adhesive build-up is reduced to improve creping quality, then creping performance is improved, but adhesion control becomes insufficient

Engineering Contradiction:
Improvecreping qualityVSAvoidadhesion control
Core Design Contradiction:
Manufacturing precisionVSReliability

Solution Approach 1:

The composite adhesive system with reactive modifier provides balanced performance by achieving both high creping quality and reliable adhesion control. The controlled cross-linking density prevents excessive build-up that would interfere with creping, while maintaining sufficient adhesion for proper web transfer.

Inventive Principle:
Principle #40Composite materials

4Duration of action of stationary object

If thermosetting adhesives are used to provide durability, then adhesive durability is improved, but doctor blade chatter increases

Engineering Contradiction:
Improveadhesive durabilityVSAvoiddoctor blade chatter
Core Design Contradiction:
Duration of action of stationary objectVSObject-affected harmful factors

Solution Approach 1:

The reactive modifier optimizes the cross-linking parameter to achieve appropriate adhesive durability without excessive build-up. This balanced cross-linking density provides durable adhesive performance while reducing the stiffness and build-up that cause doctor blade chatter.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach provides improved control over adhesion and rewetability, leading to enhanced creping performance and tissue product quality across a wide range of operating conditions, including high drum temperatures and low moisture content, while maintaining adhesive durability and reducing doctor blade chatter.

Implementation Method 1

A creping adhesive composition based on a reactive, lightly crosslinked polyamidoamine-epihalohydrin polymer, optionally combined with a reactive modifier, is used to control adhesion properties by varying the crosslinking density

Methodology Applied
Scientific EffectCross-linking: Chemical Bonding

Implementation Method 2

thermosetting creping adhesive with reactive modifiers

Methodology Applied
Scientific EffectThermosetting: Chemical Bonding

Data Source

PatentUS8246781B2Thermosetting creping adhesive with reactive modifiers
Publication Date: 2012.08.21 ECOLAB USA INC
  • US8246781B2 patent drawing
  • US8246781B2 patent drawing
  • US8246781B2 patent drawing

AI summary

A creping adhesive comprising a PAE composition comprising a reactive, light crosslinked polyamidoamine-epichlorohydrin polymer (PAE-type polymer) optionally in combination with a reactive modifier and the corresponding method for of creping cellulosic fiber webs with the adhesive.