Palladium Carbon Composite Gas Sensor Sensitivity Power Trade-off

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Solution Overview

Problem

Existing reducing gas detection sensors lack sensitivity and have high power consumption, with long response times, making them inadequate for effective safety management in detecting gases like hydrogen, formaldehyde, and ethylene.

Innovation Solution

A reducing gas detection material composed of a palladium compound and a carbon compound, which undergoes a reversible reaction with reducing gases, changing electrical conductivity and allowing for a sensor with improved sensitivity and reduced power consumption, featuring a short response time.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Measurement precision

If a palladium oxide reactive layer is used to detect reducing gas through electrical conductivity change, then the sensor can detect reducing gas, but the sensitivity is insufficient and power consumption is high

Engineering Contradiction:
Improvedetection sensitivityVSAvoidpower consumption
Core Design Contradiction:
Measurement precisionVSUse of energy by moving object

Solution Approach 1:

The patent combines palladium oxide with specific carbon compounds (graphene, carbon nanotubes, or fullerenes) to create a composite reactive layer. This composite structure leverages the high electrical conductivity and large surface area of carbon materials to enhance the sensitivity of reducing gas detection while reducing the baseline electrical conductivity, thereby lowering power consumption. The carbon compounds provide efficient electron transport pathways that amplify the conductivity change signal upon reducing gas exposure.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The carbon compounds used in the reactive layer possess porous structures with high surface area-to-volume ratios. This porosity increases the contact area between the reactive layer and reducing gas molecules, enhancing detection sensitivity. The porous structure also allows for faster gas diffusion and reaction, improving response time while maintaining low baseline conductivity for reduced power consumption.

Inventive Principle:
Principle #31Porous materials

2Measurement precision

If the sensitivity of the sensor is increased to improve detection capability, then the detection accuracy improves, but the power consumption increases

Engineering Contradiction:
Improvedetection sensitivityVSAvoidpower consumption
Core Design Contradiction:
Measurement precisionVSUse of energy by stationary object

Solution Approach 1:

The patent optimizes the electrical conductivity parameter of the reactive layer by incorporating carbon compounds with controlled concentrations and structures. This parameter adjustment achieves high sensitivity to reducing gas-induced conductivity changes while maintaining a low baseline conductivity state, thereby decoupling sensitivity improvement from power consumption increase.

Inventive Principle:
Principle #35Parameter changes

3Volume of moving object

If the sensor size is reduced for portability, then the device becomes more compact, but the detection sensitivity decreases

Engineering Contradiction:
Improvesensor sizeVSAvoiddetection sensitivity
Core Design Contradiction:
Volume of moving objectVSMeasurement precision

Solution Approach 1:

The patent employs thin-film deposition techniques to create the palladium oxide and carbon compound reactive layer on a substrate. This thin-film structure reduces the sensor's volume and thickness while maintaining a large effective surface area for gas interaction through the high surface area-to-volume ratio of the carbon compounds, thereby preserving detection sensitivity in a compact form factor.

Inventive Principle:
Principle #30Flexible shells and thin films

Solution Approach 2:

The carbon compounds (graphene, carbon nanotubes, fullerenes) provide a two-dimensional or nanostructured surface that effectively 'copies' and amplifies the interaction area between the reactive layer and reducing gas molecules, allowing compact sensor design with enhanced sensitivity through increased effective contact area without proportionally increasing physical size.

Inventive Principle:
Principle #26Copying

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The sensor achieves high sensitivity and low power consumption, enabling rapid detection of reducing gases with a significantly increased conductivity change, suitable for use in various applications including fuel-cell vehicles.

Implementation Method 1

a reducing gas detection material including a palladium compound and a carbon compound, and having reactivity with a reducing gas

Methodology Applied
Scientific EffectRedox reactions: Redox Reactions

Data Source

PatentUS11686698B2Reducing gas detection material and reducing gas detection sensor
Publication Date: 2023.06.27 CANON KK
  • US11686698B2 patent drawing
  • US11686698B2 patent drawing
  • US11686698B2 patent drawing

AI summary

Provided is a reducing gas detection sensor which has sensitivity improved as compared to that of the related art, and in which power consumption is decreased. The reducing gas detection sensor includes: a reducing gas detection material including a palladium compound and a carbon compound, and having reactivity with a reducing gas; and a unit configured to measure a conductivity of the reducing gas detection material.